Liquid crystal composition and liquid crystal display device
View Patent ↗The invention provides a liquid crystal composition that satisfies at least one of characteristics such as a high maximum temperature of a nematic phase, a low minimum temperature of a nematic phase, a small viscosity, a large optical anisotropy, a large dielectric anisotropy, a large specific resistance, a high stability to ultraviolet light and a high stability to heat, or that is suitably balanced between at least two of the characteristics. The liquid crystal composition has a nematic phase, and includes a specific optically active compound as a first component and may optionally include a specific compound having a high maximum temperature or a small viscosity as a second component, and a specific compound having a large positive dielectric anisotropy as a third component, and the liquid crystal display device contains this composition.
1. A liquid crystal composition having a nematic phase and including at least one optically active compound selected from the group of compounds represented by formula (1) as a first component, and including at least one compound selected from the group of compounds represented by formula (2) as a second component:
wherein R 1 is alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons, or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine; R 2 and R 3 are different each other, and are alkyl having 1 to 12 carbons or alkenyl having 2 to 12 carbons; R 4 and R 5 are independently alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons, or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine; and ring A is 1,4-cyclohexylene or 1,4-phenylene; ring B and ring C are independently 1,4-cyclohexylene or 1,4-phenylene; Z 1 is independently a single bond, ethylene or carbonyloxy; and p is 1 or 2.
2. The liquid crystal composition according to claim 1 , wherein in formula (1), the sum of the carbons in R 2 and R 3 in the range of 3 to 10.
3. The liquid crystal composition according to claim 2 , wherein the first component is at least one compound selected from the group of compounds represented by formula (1-1) and formula (1-2):
wherein R 1 is alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons, or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine.
4. The liquid crystal composition according to claim 1 , wherein the ratio of the first component is in the range of 0.01 part by weight to 5 parts by weight based on 100 parts by weight of the liquid crystal composition excluding the first component.
5. The liquid crystal composition according to claim 1 , wherein the second component is at least one compound selected from the group of compounds represented by formula (2-1) to formula (2-6):
wherein R 4 and R 5 are independently alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons, or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine.
6. The liquid crystal composition according to claim 5 , wherein the second component is at least one compound selected from the group of compounds represented by formula (2-1).
7. The liquid crystal composition according to claim 5 , wherein the second component is a mixture of at least one compound selected from the group of compounds represented by formula (2-1) and at least one compound selected from the group of compounds represented by formula (2-5).
8. The liquid crystal composition according to claim 1 , wherein the ratio of the second component is in the range of 35% by weight to 95% by weight based on the weight of the liquid crystal composition excluding the first component.
9. The liquid crystal composition according to claim 1 , further including at least one compound selected from the group of compounds represented by formula (3) as a third component:
wherein R 6 is alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons, or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine; ring D is independently 1,4-cyclohexylene, 1,3-dioxane-2,5-diyl, 1,4-phenylene, 2-fluoro-1,4-phenylene, 3-fluoro-1,4-phenylene, 3,5-difluoro-1,4-phenylene or 2,5-pyrimidine; Z 2 is independently a single bond, ethylene, carbonyloxy or difluoromethyleneoxy; X 1 and X 2 are independently hydrogen or fluorine; Y 1 is fluorine, chlorine or trifluoromethoxy; and k is 1, 2, 3 or 4.
10. The liquid crystal composition according to claim 9 , wherein the third component is at least one compound selected from the group of compounds represented by formula (3-1) to formula (3-23):
wherein R 6 is alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons, or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine; X 1 , X 2 , X 3 , X 4 , X 5 , X 6 , X 7 , X 8 and X 9 are independently hydrogen or fluorine; and Y 1 is fluorine, chlorine or trifluoromethoxy.
11. The liquid crystal composition according to claim 9 , wherein the ratio of the third component is in the range of 5% by weight to 60% by weight based on the weight of the liquid crystal composition excluding the first component.
12. The liquid crystal composition according to claim 1 , wherein the maximum temperature of a nematic phase is 70° C. or higher, the optical anisotropy (25° C.) at a wavelength of 589 nanometers is 0.08 or more, and the dielectric anisotropy (25° C.) at a frequency of 1 kHz is 2 or more.
13. A liquid crystal display device containing the liquid crystal composition according to claim 1 .
14. The liquid crystal display device according to claim 13 , wherein the operating mode of the liquid crystal display device is a TN mode, an OCB mode, an IPS mode or a PSA mode, and the driving mode of the liquid crystal display device is an active matrix mode.