Polymer coatings with improved heat stability
View Patent ↗The present invention relates to coatings comprising electrically conductive polymers and esters of gallic acid and sugars, their production and use, and dispersions for the production of such coatings.
1. A dispersion comprising: an electrically conductive polymer, a counter-ion, a dispersing agent, and an ester of gallic acid and a sugar.
2. The dispersion according to claim 1 , wherein the electrically conductive polymer comprises a polymer selected from the group consisting of optionally substituted polythiophenes, optionally substituted polyanilines, optionally substituted polypyrroles and mixtures thereof.
3. The dispersion according to claim 1 , wherein the electrically conductive polymer comprises a polyalkylenedioxythiophene having repeating units of the general formula (I)
wherein A represents an optionally substituted C 1 -C 5 -alkylene radical; each R independently represents a linear or branched, optionally substituted C 1 -C 18 -alkyl radical, an optionally substituted C 5 -C 12 -cycloalkyl radical, an optionally substituted C 6 -C 14 -aryl radical, an optionally substituted C 7 -C 18 -aralkyl radical, an optionally substituted C 1 -C 4 -hydroxyalkyl radical or a hydroxyl radical; and x represents an integer of 0 to 8.
4. The dispersion according to claim 1 , wherein the electrically conductive polymer comprises poly(3,4-ethylenedioxythiophene).
5. The dispersion according to claim 1 , wherein the counter-ion comprises a monomeric or polymeric anion.
6. The dispersion according to claim 1 , wherein the counter-ion comprises a polymeric anion selected from the group consisting of polymeric carboxylic acids and sulphonic acids.
7. The dispersion according to claim 3 , wherein the counter-ion comprises a polymeric anion selected from the group consisting of polymeric carboxylic acids and sulphonic acids.
8. The dispersion according to claim 1 , wherein the counter-ion comprises polystyrenesulphonic acid.
9. The dispersion according to claim 4 , wherein the counter-ion comprises polystyrenesulphonic acid.
10. The dispersion according to claim 1 , wherein the ester of gallic acid and a sugar corresponds to the formula
11. The dispersion according to claim 7 , wherein the ester of gallic acid and a sugar corresponds to the formula
12. The dispersion according to claim 1 , wherein the ester of gallic acid and a sugar is present in an amount of 1 to 100 wt. %, based on the solids content of electrically conductive polymer in the dispersion.
13. The dispersion according to claim 1 , further comprising a polymeric organic binder.
14. The dispersion according to claim 1 , wherein the dispersing agent comprises one or more components selected from the group consisting of water, aliphatic alcohols, aliphatic ketones, aliphatic carboxylic acid esters, aromatic hydrocarbons, aliphatic hydrocarbons, chlorohydrocarbons, aliphatic nitriles, aliphatic sulphoxides and sulphones, aliphatic carboxylic acid amides, aliphatic and araliphatic ethers, and mixtures thereof.
15. A method of preparing an electrically conductive or antistatic coating, the method comprising: (a) providing a dispersion comprising an electrically conductive polymer, a counter-ion, a dispersing agent, and an ester of gallic acid and a sugar; (b) applying the dispersion to a substrate; and (c) drying the applied dispersion.
16. An electrically conductive or antistatic coating comprising a dried dispersion comprising an electrically conductive polymer, a counter-ion, a dispersing agent, and an ester of gallic acid and a sugar.