Microchannel chip and method for gas-liquid phase separation using same

1. A microchannel chip, which comprises a microchannel formed in a substrate and a gas-liquid phase separation microchannel whose upper part is covered with a porous film, said gas-liquid phase separation microchannel being connected to the downstream end of said microchannel, wherein

a depth of the microchannel is 150 μm to 200 μm,

a depth of the gas-liquid phase separation microchannel is 10 μm to 100 μm, and

said porous film is a polytetrafluoroethylene film having an average pore size of 0.1 μm to 2.0 μm and a porosity of 70% to 80%.

2. The microchannel chip according to claim 1 , wherein the depth of said gas-liquid phase separation microchannel is smaller than that of said microchannel.

3. The microchannel chip according to claim 1 , wherein said porous film is made of a hydrophobic material.

4. The microchannel chip according to claim 1 , wherein said microchannel has a width of 10 μm to 600 μm and a depth of 5 μm to 300 μm.

5. The microchannel chip according to claim 1 , wherein said gas-liquid phase separation microchannel has a length of 0.5 cm to 5 cm.

6. A gas-liquid phase separation method for separating a liquid-phase flow from a two-phase flow flowing through a microchannel by removing a gas phase, said two-phase flow being composed of said gas phase and liquid phase, which liquid phase flows in the periphery of said microchannel and which gas phase flows interiorly of said liquid-phase flow, said gas-liquid separation method comprising:

allowing said two-phase flow to flow through said microchannel in the microchannel chip according to claim 1 ; and

leading said two-phase flow to said gas-liquid phase separation microchannel to allow said two-phase flow to flow through this region, thereby discharging said gas-phase flow to the outside from said gas-liquid phase separation microchannel via said porous film.

7. A microchannel chip for measuring a gaseous test substance, which comprises:

a sample gas introduction microchannel from which a sample gas containing a gaseous test substance soluble to a collection solution is introduced;

a collection solution introduction microchannel from which said collection solution is introduced;

a gas extraction microchannel arranged in the downstream of the junction between said sample gas introduction microchannel and said collection solution introduction microchannel, through which gas extraction microchannel a two-phase flow composed of a liquid-phase flow flowing in the periphery of said gas extraction microchannel and a gas-phase flow flowing interiorly of said liquid-phase flow flows;

a gas-liquid phase separation microchannel whose upper part is covered with a porous film, said gas-liquid phase separation microchannel being connected to the downstream end of said gas extraction microchannel; and

a test substance-measuring microchannel connected to the downstream of said gas-liquid phase separation microchannel, in which test substance-measuring microchannel said liquid-phase flow remaining after said two-phase flow passes through said gas-liquid phase separation microchannel and said gas-phase flow is discharged via said porous film flows; and said test substance contained in said liquid-phase flow is measured, wherein

a depth of the gas extraction microchannel is 150 μm to 200 μm,

a depth of the gas-liquid phase separation microchannel is 10 μm to 100 μm, and

said porous film is a polytetrafluoroethylene film has having an average pore size of 0.1 μm to 2.0 μm and a porosity of 70% to 80%.

8. The microchannel chip according to claim 7 , which further comprises at least one reagent introduction microchannel merging with any of said microchannels, said reagent introduction microchannel being used for supplying a reagent required for measuring said test substance.

9. A method of measuring a gaseous test substance, which comprises the steps of:

introducing said sample gas at a rate of 50 mL/min. to 150 mL/min. to said sample gas introduction microchannel of the microchannel chip according to claim 7 ;

introducing said collection solution at a rate of 1 μL/min. to 5 μL/min. to said collection solution introduction microchannel;

collecting said test substance contained in said sample gas into said collection solution by allowing said two-phase flow composed of said sample gas and said collection solution to flow through said gas extraction microchannel;

converting said two-phase flow to a liquid-phase flow by allowing said two-phase flow to flow through said gas-liquid phase separation microchannel to discharge gas-phase flow to the outside via said porous film; and

measuring said test substance contained in the thus obtained liquid-phase flow.

10. The method according to claim 9 , wherein said gaseous test substance is ammonia.

11. The method according to claim 10 , wherein said microchannel chip further comprises two said reagent introduction microchannels, from one of which a coloring solution is introduced and from the other of which an oxidizing solution is introduced.

12. The method according to claim 11 , wherein ammonia is measured using a thermal lens microscope.

13. A method of measuring a gaseous test substance, which comprises the steps of:

introducing said sample gas at a rate of 50 mL/min. to 150 mL/min. to said sample gas introduction microchannel of the microchannel chip according to claim 10 ;

introducing said collection solution at a rate of 1 μL/min. to 5 μL/min. to said collection solution introduction microchannel;

collecting said test substance contained in said sample gas into said collection solution by allowing said two-phase flow composed of said sample gas and said collection solution to flow through said gas extraction microchannel;

converting said two-phase flow to a liquid-phase flow by allowing said two-phase flow to flow through said gas-liquid phase separation microchannel to discharge gas-phase flow to the outside via said porous film; and

measuring said test substance contained in the thus obtained liquid-phase flow.

14. The method according to claim 13 , wherein said gaseous test substance is ammonia.