Polyester polyols from terephthalic acid and oligoalkylene oxides
View Patent ↗Polyester polyols are produced by reacting terephthalic acid with a glycol corresponding to the formula H—(OCH 2 CH 2 ) n —OH and an aliphatic dicarboxylic acid. These polyester polyols are particularly useful for the production of polyurethane) (PUR) and polyurethane/polyisocyanurate (PUR/PIR) foams for use in insulation applications.
1. A polyester polyol having a concentration of ether groups of from 9.0 mol/kg polyester polyol to 16 mol/kg polyester polyol, which is produced by reacting a mixture comprising
(A) terephthalic acid,
(B) an oligoethylene glycol of the formula H—(OCH 2 CH 2 ) n —OH with a number-average number of oxyethylene groups n of from 3.0 to 9.0, and
(C) at least one aliphatic dicarboxylic acid selected from the group consisting of succinic acid, glutaric acid, adipic acid, sebacic acid, suberic acid, azelaic acid, decane dicarboxylic acid, dodecane dicarboxylic acid and omega-hydroxycaproic acid.
2. The polyester polyol of claim 1 in which component (A) is present in an amount of from 10 to 40 wt. %, relative to the total weight of the mixture.
3. The polyester polyol of claim 1 in which component (B) is present in an amount of from 90 to 60 wt. %, relative to the total weight of the mixture.
4. The polyester polyol of claim 1 in which component (C) is present in an amount of from 2 to 20 wt. %, relative to the total weight of the mixture.
5. The polyester polyol of claim 1 in which the polyester polyol has a hydroxyl value of from 100 mg KOH/g to 400 mg KOH/g.
6. The polyester polyol of claim 1 in which the polyester polyol has a viscosity measured in accordance with DIN 53109 of from 800 mPas to 4500 mPas at 25° C.
7. The polyester polyol of claim 1 in which the oligoethylene glycol (B) has a number-average number of oxyethylene groups n in the range between 3.1 and 9.
8. The polyester polyol of claim 1 to in which the polyester polyol has a melting point between −40° C. and 25° C.
9. A process for producing the polyester polyol of claim 1 in which components (A), (B) and (C) are reacted in the presence of a catalyst selected from the group consisting of tin(II) salts and titanium tetraalkoxylates at a temperature from 160° C. to 240° C. and under a pressure of from 1 to 1013 mbar for from 7 to 100 hours.
10. A PUR or PUR/PIR foam produced by reacting the polyester polyol of claim 1 with a polyisocyanate.
11. A process for producing a PUR or PUR/PIR foam comprising reacting:
a) the polyester polyol of claim 1 with
b) at least one polyisocyanate-containing component,
c) at least one blowing agent,
d) at least one catalysts,
e) optionally at least one flame retardant, auxiliary substance or additive, and
f) optionally at least one compound having at least two isocyanate-reactive groups.
12. The PUR or PUR/PIR foam produced by the process of claim 11 .
13. An insulated pipe produced with the PUR or PUR/PIR foam of claim 12 .
14. A sandwich element produced with the PUR or PUR/PIR foam of claim 12 .
15. An insulating sheet produced with the PUR or PUR/PIR foam of claim 12 .
16. A refrigerator produced with the PUR or PUR/PIR foam of claim 12 .