Poly(arylene ether)—polyolefin composition and its use in wire and cable insulation and sheathing
View Patent ↗A composition includes specific amounts of a poly(arylene ether), an unfunctionalized hydrogenated triblock copolymer, an unfunctionalized polyolefin, and magnesium dihydroxide. The composition is useful for forming insulation and sheath layers of wire and cable.
1. An insulated conductor, comprising:
a conductor;
an insulating layer surrounding the conductor;
wherein the insulating layer comprises an insulating layer composition comprising
about 10 to about 35 weight percent of a poly(arylene ether);
about 8 to about 16 weight percent of an unfunctionalized hydrogenated triblock copolymer of an alkenyl aromatic compound and a conjugated diene; wherein the unfunctionalized hydrogenated triblock copolymer has a weight average molecular weight less than or equal to 200,000 atomic mass units;
about 15 to about 30 weight percent of an unfunctionalized polyolefin comprising about 14 to about 30 weight percent of an unfunctionalized ethylene-octene copolymer; and
43 to 60 weight percent of a magnesium dihydroxide;
wherein the ma nesiu dihydroxide la er composition m osition comprises a stearic acid-treated magnesium dihydroxide;
wherein all weight percents are based on the total weight of the insulating layer composition; and
a sheath layer surrounding the insulating layer;
wherein the sheath layer comprises a sheath layer composition comprising about 10 to about 35 weight percent of a poly(arylene ether);
about 8 to about 16 weight percent of an unfunctionalized hydrogenated triblock copolymer of an alkenyl aromatic compound and a conjugated diene; wherein the unfunctionalized hydrogenated triblock copolymer has a weight average molecular weight less than or equal to 200,000 atomic mass units;
about 15 to about 30 weight percent of an unfunctionalized polyolefin comprising about 14 to about 30 weight percent of an unfunctionalized ethylene-octene copolymer; and
about 20 to about 40 weight percent of a magnesium dihydroxide;
wherein the magnesium dihydroxide of the sheath layer composition comprises an amino magnesium dihydroxide;
wherein all weight percents are based on the total weight of the sheath layer composition.
2. The insulated conductor of claim 1 , wherein the insulating layer composition further comprises about 2 to about 8 weight percent of an acid-functionalized polyolefin, an acid-functionalized hydrogenated block copolymer of an alkenyl aromatic compound and a conjugated diene, or a combination thereof.
3. The insulated conductor of claim 1 , wherein the sheath layer composition further comprises about 2 to about 8 weight percent of an acid-functionalized polyolefin, an acid-functionalized hydrogenated block copolymer of an alkenyl aromatic compound and a conjugated diene, or a combination thereof.
4. The insulated conductor of claim 1 , wherein the insulating layer composition comprises
about 10 to about 20 weight percent of the poly(arylene ether);
about 8 to about 13 weight percent of the unfunctionalized hydrogenated triblock copolymer;
about 15 to about 25 weight percent of the unfunctionalized polyolefin; wherein the unfunctionalized polyolefin comprises about 14 to about 21 weight percent of the unfunctionalized ethylene-octene copolymer; and
43 to 56 weight percent of the magnesium dihydroxide.
5. The insulated conductor of claim 4 , wherein the unfunctionalized polyolefin of the insulating layer composition further comprises about 1.5 to about 4.5 weight percent of a linear low density polyethylene.
6. The insulated conductor of claim 4 , wherein the insulating layer composition further comprises about 3 to about 7 weight percent of an acid-functionalized polyolefin; wherein the acid-functionalized polyolefin comprises a maleic anhydride-functionalized ethylene-octene copolymer.
7. The insulated conductor of claim 1 ,
wherein the sheath layer composition comprises
about 20 to about 30 weight percent of the poly(arylene ether);
about 9 to about 15 weight percent of the unfunctionalized hydrogenated triblock copolymer; wherein the unfunctionalized hydrogenated triblock copolymer has a weight average molecular weight less than or equal to 200,000 atomic mass units;
about 22 to about 30 weight percent of the unfunctionalized polyolefin;
wherein the unfunctionalized polyolefin comprises about 15 to about 22 weight percent of an unfunctionalized ethylene-octene copolymer; and
about 25 to about 35 weight percent of the magnesium dihydroxide.
8. The insulated conductor of claim 7 , wherein the unfunctionalized polyolefin of the sheath layer composition further comprises about 3 to about 7 weight percent of a polybutene and about 1.5 to about 4.5 weight percent of a linear low density polyethylene.
9. The insulated conductor of claim 7 , wherein the sheath layer composition further comprises about 3 to about 7 weight percent of an acid-functionalized polyolefin; wherein the acid-functionalized polyolefin comprises a maleic anhydride-functionalized ethylene-octene copolymer.
10. The insulated conductor of claim 1 ,
wherein the insulating layer composition comprises
about 10 to about 20 weight percent of the poly(arylene ether);
about 8 to about 13 weight percent of the unfunctionalized hydrogenated triblock copolymer;
about 15 to about 25 weight percent of the unfunctionalized polyolefin;
wherein the unfunctionalized polyolefin comprises about 14 to about 21 weight percent of the unfunctionalized ethylene-octene copolymer; and
43 to 56 weight percent of the magnesium dihydroxide; and
wherein the sheath layer composition comprises
about 20 to about 30 weight percent of the poly(arylene ether);
about 9 to about 15 weight percent of the unfunctionalized hydrogenated triblock copolymer; wherein the unfunctionalized hydrogenated triblock copolymer has a weight average molecular weight less than or equal to 200,000 atomic mass units;
about 22 to about 30 weight percent of an unfunctionalized polyolefin;
wherein the unfunctionalized polyolefin comprises about 15 to about 22 weight percent of an unfunctionalized ethylene-octene copolymer; and
about 25 to about 35 weight percent of the magnesium dihydroxide.
11. The insulated conductor of claim 10 , wherein the unfunctionalized polyolefin of the insulating layer composition further comprises about 1.5 to about 4.5 weight percent of a linear low density polyethylene.
12. The insulated conductor of claim 10 , wherein the insulating layer composition further comprises about 3 to about 7 weight percent of an acid-functionalized polyolefin comprising a maleic anhydride-functionalized ethylene-octene copolymer.
13. The insulated conductor of claim 10 , wherein the unfunctionalized polyolefin of the sheath layer composition further comprises about 3 to about 7 weight percent of a polybutene and about 1.5 to about 4.5 weight percent of a linear low density polyethylene.
14. The insulated conductor of claim 10 , wherein the sheath layer composition further comprises about 3 to about 7 weight percent of an acid-functionalized polyolefin; wherein the acid-functionalized polyolefin comprises a maleic anhydride-functionalized ethylene-octene copolymer.