IP Library Granted Patent US 8,969,871
Granted Patent B2
US 8,969,871 · App. 13/269,205 · Granted Mar 3, 2015

Field-effect transistor, processes for producing the same, and electronic device using the same

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Quick Facts
Patent No.
US 8,969,871
App. No.
13/269,205
Granted
Mar 3, 2015
Kind
B2
Abstract

Provided is a field-effect transistor which has a high mobility and a low variation of mobility. A field-effect transistor at least comprising a substrate, a semiconductor layer, a source electrode, and a drain electrode is produced by forming the source electrode and/or the drain electrode so that the source electrode and/or the drain electrode has a taper shape in a cross-section which is parallel with a channel length direction and perpendicular to the substrate, and forming the semiconductor layer through coating process.

Claims (25)

1. A field-effect transistor which at least comprises a substrate, a semiconductor layer formed through coating process, a source electrode, and a drain electrode, wherein, in a cross-section which is parallel with a channel length direction and perpendicular to the substrate, the source electrode and/or the drain electrode has a taper shape and the taper shape forms an angle of 30° or less with the substrate.

2. The field-effect transistor according to claim 1 , wherein the semiconductor is an organic semiconductor having an annulene structure.

3. The field-effect transistor according to claim 1 , which has a variation of mobility of ±30% or less.

4. A process for producing a field-effect transistor at least comprising a substrate, a semiconductor layer, a source electrode, and a drain electrode, the process comprising; forming the source electrode and/or the drain electrode so that the source electrode and/or the drain electrode has a taper shape in a cross-section which is parallel with a channel length direction and perpendicular to the substrate; and coating a coating solution that contains a semiconductor,

wherein said taper shape forms an angle of 30° or less with the substrate.

5. A process for producing a field-effect transistor at least comprising a substrate, a semiconductor layer, a source electrode, and a drain electrode, the process comprising: forming the source electrode and/or the drain electrode so that the source electrode and/or the drain electrode has a taper shape in a cross-section which is parallel with a channel length direction and perpendicular to the substrate; coating a coating solution that contains a precursor for a semiconductor; and converting the precursor to a semiconductor by heating and/or light irradiation,

wherein said taper shape forms an angle of 30° or less with the substrate.

6. A process for producing a field-effect transistor, at least comprising a substrate, a semiconductor layer, a source electrode, and a drain electrode, the process comprising; forming the source electrode and/or the drain electrode so that the source electrode and/or the drain electrode has a taper shape in a cross-section which is parallel with a channel length direction and perpendicular to the substrate; and coating a coating solution that contains a semiconductor,

wherein said taper shape forms an angle of 30° or less with the substrate, and

wherein the source electrode and/or drain electrode which has a taper shape is formed by forming two resist layers, exposing an photoresist layer to light, removing the uncured portions, forming a metal layer, and then removing unnecessary portions of the metal layer by a lift-off method.

7. A field-effect transistor produced by the process according to claim 4 or 5 .

8. A method for improving a mobility of a field-effect transistor at least comprising a substrate, a semiconductor layer formed through coating process, a source electrode, and a drain electrode, wherein when the field-effect transistor is produced, the source electrode and/or the drain electrode is formed so that the source electrode and/or the drain electrode has a taper shape in a cross-section which is parallel with a channel length direction and perpendicular to the substrate, thereby improving the mobility,

wherein said taper shape forms an angle of 30° or less with the substrate.

9. An electronic device comprising the field-effect transistor according to claim 1 .

10. The field-effect transistor according to claim 1 , wherein said taper shape forms an angle of less than 30° with the substrate.

11. The field-effect transistor according to claim 4 , wherein said taper shape forms an angle of less than 30° with the substrate.

12. The field-effect transistor according to claim 5 , wherein said taper shape forms an angle of less than 30° with the substrate.

13. The field-effect transistor according to claim 8 , wherein said taper shape forms an angle of less than 30° with the substrate.

14. The field-effect transistor according to claim 1 , wherein a semiconductor layer formed through a coating process is formed by a method in which a coating solution comprising a precursor for a semiconductor is applied and said precursor is thereafter converted to said semiconductor.

15. The field-effect transistor according to claim 14 , wherein said precursor is converted by a reverse Diels-Alder reaction.

16. An electronic device comprising the field-effect transistor according to claim 7 .

17. A process for producing a field-effect transistor at least comprising a substrate, a semiconductor layer, a source electrode, and a drain electrode, the process comprising; forming the source electrode and/or the drain electrode so that the source electrode and/or the drain electrode has a taper shape in a cross-section which is parallel with a channel length direction and perpendicular to the substrate; and coating a coating solution that contains a semiconductor,

wherein said taper shape forms an angle of 30° or less with the substrate; and

wherein the source electrode and/or drain electrode which has a taper shape is formed by forming two resist layers, and forming a shape in which an upper photoresist layer overhangs, and forming a metal layer, and then removing unnecessary portions of said metal layer.

18. The process for forming a field-effect transistor according to claim 17 , wherein said forming a shape in which said upper photoresist layer overhangs is formed by forming a film of a photoresist on a lower resist layer which is not photosensitive, exposing said photoresist to light and then developing said layers while regulating the developing time.

Assignments (3)
CHANGE OF NAME Recorded Sep 5, 2017
From: MITSUBISHI RAYON CO., LTD.
To: MITSUBISHI CHEMICAL CORPORATION
Reel/Frame 043750/0834 →
MERGER Recorded Sep 4, 2017
From: MITSUBISHI CHEMICAL CORPORATION
To: MITSUBISHI RAYON CO., LTD.
Reel/Frame 043750/0207 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 27, 2011
From: OSEKI, YOSUKE; SAKAI, YOSHIMASA; OHNO, AKIRA
To: MITSUBISHI CHEMICAL CORPORATION
Reel/Frame 027446/0112 →