Phosphorus compound, method of preparing the same and flame retardant thermoplastic resin composition including the same
Disclosed herein is a phosphorus compound represented by Formula 1: wherein each R is the same or different and is independently hydrogen, C 1 -C 6 alkyl or C 6 -C 12 aryl.
1. A phosphorus compound represented by Formula 1:
wherein each R is hydrogen.
2. The phosphorus compound of claim 1 , wherein the difference in the acid value of a 75% solution of the phosphorus compound in water before and after stirring at 93° C. for 48 hours is less than about 0.5 mg KOH/g, and the difference in the acid value of the phosphorus compound before and after standing at 280° C. for 1 hour is less than about 0.1 mg KOH/g.
3. The phosphorus compound of claim 1 , wherein said phosphorus compound has a weight loss of about 5.5% or less, as determined by thermogravimetric analysis at 350° C.
4. A method of preparing a phosphorus compound represented by Formula 1:
wherein each R is hydrogen, the method comprising
reacting phosphorus oxychloride with a compound represented by Formula 2:
wherein R is hydrogen, and
reacting the reaction product with hydroquinone.
5. A flame retardant thermoplastic resin composition comprising the phosphorus compound of claim 1 .
6. The flame retardant thermoplastic resin composition of claim 5 , wherein said thermoplastic resin composition comprises about 100 parts by weight of a thermoplastic resin and about 0.1 to about 50 parts by weight of the phosphorus compound.
7. The flame retardant thermoplastic resin composition of claim 5 , wherein said thermoplastic resin comprises polystyrene (PS) resin, acrylonitrile-butadiene-styrene (ABS) copolymer resin, rubber modified polystyrene (HIPS) resin, acrylonitrile-styrene-acrylate (ASA) copolymer resin, acrylonitrile-styrene (SAN) copolymer resin, methyl methacrylate-butadiene-styrene (MBS) copolymer resin, acrylonitrile-ethyl acrylate-styrene (AES) copolymer resin, polycarbonate (PC) resin, polyphenylene ether (PPE) resin, polyphenylene sulfide (PPS) resin, polyethylene (PE) resin, polypropylene (PP) resin, polyethylene terephthalate (PET) resin, polybutylene terephthalate (PBT) resin, poly(meth)acrylic resin, polyamide (PA) resin, or a combination thereof.
8. The flame retardant thermoplastic resin composition of claim 5 , wherein the thermoplastic resin is polycarbonate resin and wherein said phosphorus compound is present in an amount of about 1 to about 10 parts by weight, based on about 100 parts by weight of the polycarbonate resin.
9. The flame retardant thermoplastic resin composition of claim 5 , wherein the thermoplastic resin is a blend of a polycarbonate resin and a rubber modified aromatic vinyl polymer resin, and wherein the phosphorus compound is present in an amount of about 10 to about 25 parts by weight, based on about 100 parts by weight of the blend of the polycarbonate resin and the rubber modified aromatic vinyl polymer resin.
10. The flame retardant thermoplastic resin composition of claim 5 , further comprising an additive selected from the group consisting of flame retardants, flame retardant assistants, lubricants, plasticizers, heat stabilizers, anti-drip agents, antioxidants, compatibilizers, light stabilizers, pigments, dyes, inorganic additives, and combinations thereof.