Glass fiber-reinforced polyoxymethylene
View Patent ↗The present invention relates to a molding composition, a process for the manufacturing of said molding composition, molded parts obtainable therefrom as well as the use of the molding composition for the manufacturing of molded parts used in the automotive industry, for housings, latches, window winding systems, wiper systems, sun roof systems, seat adjustments, levers, gears, claws, pivot housing or wiper arms.
1. A molding composition comprising:
a) at least one polyoxymethylene (A), wherein at least 25% of the terminal groups are hydroxyl groups,
b) at least one coupling agent (B), which is a polyisocyanate compound selected from the group consisting of an aliphatic polyisocyanate, a cycloaliphatic polyisocyanate, an aromatic polyisocyanate, and mixtures thereof,
c) at least one reinforcing fiber (C),
d) at least one formaldehyde scavenger (D) and
e) 0.1 to 3 wt.-% of stabilizer and processing auxiliaries, wherein the weight is based on the total weight of the composition,
wherein the polyisocyanate compound provides a direct linkage between the at least one polyoxymethylene and the at least one reinforcing fiber or a sizing material coated on the at least one reinforcing fiber.
2. A molding composition according to claim 1 , wherein the polyoxymethylene (A) comprises at least 50 mol-% of —CH 2 O— repeat units.
3. A molding composition according to claim 1 , wherein polyoxymethylene (A) is present in an amount up to 95 wt.-%, wherein the weight is based on the total weight of the molding composition.
4. A molding composition according to claim 1 , wherein the composition additionally comprises an ultrahigh molecular weight polyethylene.
5. A molding composition according to claim 1 , wherein the coupling agent (B) is present in an amount ranging from 0.1 to 5 wt.-%, wherein the weight is based on the total weight of the composition.
6. A molding composition according to claim 1 , wherein the formaldehyde scavenger (D) is an aromatic compound.
7. A molding composition according to claim 1 , wherein the formaldehyde scavenger (D) has a melting point higher than 235° C.
8. A molding composition according to claim 1 , wherein the formaldehyde scavenger (D) has a pKa value ranging from 4.5 to 10.
9. A molding composition according to claim 1 , wherein the formaldehyde scavenger (D) has a melting point which is at least 10° C. higher than the melting point of the polyoxymethylene (A).
10. A molding composition according to claim 1 , wherein the formaldehyde scavenger (D) is melamine.
11. A molding composition according to claim 1 , wherein the formaldehyde scavenger (D) is present in the composition in an amount up to 2 wt.-%, wherein the weight is based on the total weight of the composition.
12. A molded part produced by molding a molding composition synthesized according to claim 1 .
13. A method for manufacturing a molding composition, the method comprising:
a) melt mixing a composition comprising
at least one polyoxymethylene (A), wherein at least 25% of the terminal groups are hydroxyl groups,
at least one coupling agent (B), which is a polyisocyanate compound selected from the group consisting of an aliphatic polyisocyanate, a cycloaliphatic polyisocyanate, an aromatic polyisocyanate, and mixtures thereof,
at least one reinforcing fiber (C),
at least one formaldehyde scavenger (D) and
0.1 to 3 wt.-% of stabilizer and processing auxiliaries,
wherein the polyisocyanate compound provides a direct linkage between the at least one polyoxymethylene and the at least one reinforcing fiber or a sizing material coated on the at least one reinforcing fiber;
at a temperature ranging from 120° C. to 260° C.,
wherein the melting point of the formaldehyde scavenger is at least 10° C. higher than the melt mixing temperature.
14. A molding composition according to claim 1 , wherein the stabilizer and processing auxiliaries comprise a UV stabilizer.
15. A molding composition according to claim 1 , wherein the stabilizer and processing auxiliaries comprise a heat stabilizer.