Catalyzed SCR filter and emission treatment system
View Patent ↗Provided is an emission treatment system and method for simultaneously remediating the nitrogen oxides (NOx), particulate matter, and gaseous hydrocarbons present in diesel engine exhaust streams. The emission treatment system has an oxidation catalyst upstream of a soot filter coated with a material effective in the Selective Catalytic Reduction (SCR) of NOx by a reductant, e.g., ammonia. Also provided is a method for disposing an SCR catalyst composition on a wall flow monolith that provides adequate catalyst loading, but does not result in unsuitable back pressures in the exhaust.
1. An emission treatment system for treatment of an exhaust stream comprising NOx and particulate matter, the emission treatment system comprising: a) an oxidation catalyst; b) an injector in fluid communication with and downstream of the oxidation catalyst, wherein the injector periodically meters ammonia or an ammonia precursor into the exhaust stream; and c) an SCR catalyst article consisting essentially of a wall flow monolith and catalytic material, the wall flow monolith in fluid communication with and downstream of the injector, wherein the wall flow monolith has a plurality of longitudinally extending passages formed by longitudinally extending walls bounding and defining said passages, wherein the passages comprise inlet passages having an open inlet end and a closed outlet end, and outlet passages having a closed inlet end and an open outlet end, the wall flow monolith having a porosity of from 50% to 60% and an average pore size of from 10 to 25 microns, and the wall flow monolith contains the catalytic material comprising an SCR catalyst composition including a slurry-loaded washcoat of a zeolite and base metal selected from one or more of a copper and iron component, the washcoat permeating the walls at a loading up to 2.4 g/in 3 , the wall flow monolith having integrated, NOx and particulate removal efficiency in which presence of the catalytic material in the wall flow monolith catalyzes the oxidation of soot.
2. The emission treatment system of claim 1 , wherein the SCR catalyst composition is effective to catalyze the reduction of NOx at a temperature below about 600° C. and is able to aid in regeneration of the filter by lowering the temperature at which soot captured by the filter is combusted.
3. The emission treatment system of claim 1 , wherein the SCR catalyst composition promotes the oxidation of excess NH 3 with O 2 .
4. The emission treatment system of claim 1 , wherein the base metal component is a copper component and the zeolite of the SCR catalyst composition has a silica to alumina ratio of at least about 10.
5. The emission treatment system of claim 1 , wherein the zeolite of the SCR catalyst composition is selected from beta zeolite, USY and ZSM-20.
6. The emission treatment system of claim 1 , wherein the zeolite of the SCR catalyst composition is a beta zeolite.
7. The emission treatment system of claim 1 , wherein the zeolite of the SCR catalyst composition has pores with a pore diameter of at least about 7 Angstroms and are connected in three dimensions.
8. The emission treatment system of claim 1 , wherein the SCR catalyst composition contains one or both of an iron and a copper promoter present in an amount of from about 0.1 to 30 percent by weight of the total weight of promoter plus zeolite.
9. The emission treatment system of claim 1 , wherein the SCR catalyst composition contains one or both of an iron and a copper promoter present in an amount of from about 1 to 5 percent by weight of the total weight of promoter plus zeolite.
10. The emission treatment system of claim 1 , wherein the wall flow monolith has a wall porosity of from 55% to 60% with an average pore size of from 10 to 25 microns.
11. The emission treatment system of claim 1 , wherein the longitudinally extending walls have an inlet side and an opposing outlet side and SCR catalyst is coated on both the inlet and outlet sides of the walls.
12. The emission treatment system of claim 1 , wherein the SCR catalyst composition permeates the walls of the monolith at a concentration of at least 1.3 g/in 3 .
13. The emission treatment system of claim 12 , wherein there is from 1.6 to 2.4 g/in 3 of SCR catalyst composition disposed on the wall flow monolith.
14. The emission treatment system of claim 1 , wherein the SCR catalyst composition has a thermal resistance to degradation at temperatures greater than 650° C.
15. The emission treatment system of claim 14 , wherein the SCR catalyst composition is effective to resist degradation upon exposure to sulfur components.
16. An emission treatment system for treatment of an exhaust stream comprising NOx and particulate matter, the emission treatment system comprising: a) an oxidation catalyst; b) an injector in fluid communication with and downstream of the oxidation catalyst, wherein the injector periodically meters ammonia or an ammonia precursor into the exhaust stream; and c) an SCR catalyst article consisting essentially of a wall flow monolith and catalytic material, the wall flow monolith in fluid communication with and downstream of the injector, wherein the wall flow monolith has a plurality of longitudinally extending passages formed by longitudinally extending walls bounding and defining said passages, wherein the passages comprise inlet passages having an open inlet end and a closed outlet end, and outlet passages having a closed inlet end and an open outlet end, wherein the wall flow monolith contains the catalytic material comprising an SCR catalyst composition including a slurry-loaded washcoat of a zeolite and base metal selected from one or more of a copper and iron component, the washcoat permeating the walls at a concentration of at least 1.3 g/in 3 ; wherein the wall flow monolith has a wall porosity of from 50% to 60% with an average pore size of from 10 to 25 microns, the wall flow monolith having integrated, NOx and particulate removal efficiency, in which presence of the catalytic material in the wall flow monolith catalyzes the oxidation of soot.
17. The emission treatment system of claim 16 , wherein there is from 1.6 to 2.4 g/in 3 of SCR catalyst composition disposed on the wall flow monolith.
18. The emission treatment system of claim 16 , wherein the SCR catalyst composition contains one or both of an iron and a copper promoter present in an amount of from about 0.1 to 30 percent by weight of the total weight of promoter plus zeolite.
19. The emission treatment system of claim 16 , wherein the SCR catalyst composition promotes the oxidation of excess NH 3 with O 2 .
20. The emission treatment system of claim 16 , wherein the SCR catalyst composition has a thermal resistance to degradation at temperatures greater than 650° C.
21. The emission treatment system of claim 16 , wherein the SCR catalyst composition in effective to resist degradation upon exposure to sulfur components.
22. An emission treatment system for treatment of an exhaust stream comprising NOx and particulate matter, the emission treatment system comprising: a) an oxidation catalyst; b) an injector in fluid communication with and downstream of the oxidation catalyst, wherein the injector periodically meters ammonia or an ammonia precursor into the exhaust stream; and
c) an SCR catalyst article consisting essentially of a wall flow monolith and catalytic material, the wall flow monolith in fluid communication with and downstream of the injector, wherein the wall flow monolith has a plurality of longitudinally extending passages formed by longitudinally extending walls bounding and defining said passages, wherein the passages comprise inlet passages having an open inlet end and a closed outlet end, and outlet passages having a closed inlet end and an open outlet end, and the wall flow monolith contains the catalytic material comprising an SCR catalyst composition including a slurry-loaded washcoat of a zeolite and base metal, the washcoat permeating the walls, wherein the wall flow monolith has a wall porosity of from 50% to 55% with an average pore size of from 10 to 25 microns, the wall flow monolith having integrated, NOx and particulate removal efficiency, in which presence of the catalytic material in the wall flow monolith catalyzes the oxidation of soot.
23. The emission treatment system of claim 22 , wherein the SCR catalyst composition has a thermal resistance to degradation at temperatures greater than 650° C.
24. The emission treatment system of claim 23 , wherein the SCR catalyst composition is effective to resist degradation upon exposure to sulfur components.
25. The emission treatment system of claim 22 , wherein the SCR catalyst composition promotes the oxidation of excess NH 3 with O 2 .
26. The emission treatment system of claim 22 , wherein the SCR catalyst composition contains one or both of an iron and a copper promoter present in an amount of from about 0.1 to 30 percent by weight of the total weight of promoter plus zeolite.
27. The emission treatment system of claim 22 , wherein the filter is effective to remove soot by deposition of particulate matter on the filter and the catalytic material contains a component to promote combustion of the soot in the absence of a fine pore path layer on the wall of the filter.