Polycrystalline diamond compacts and related products
View Patent ↗Embodiments relate to polycrystalline diamond compacts (“PDCs”) and methods of manufacturing such PDCs in which an at least partially leached polycrystalline diamond (“PCD”) table is infiltrated with a low viscosity cobalt-based alloy infiltrant. In an embodiment, a method includes forming a PCD table in the presence of a metal-solvent catalyst in a first high-pressure/high-temperature (“HPHT”) process. The method includes at least partially leaching the PCD table to remove at least a portion of the metal-solvent catalyst therefrom to form an at least partially leached PCD table. The method includes subjecting the at least partially leached PCD table and a substrate to a second HPHT process effective to at least partially infiltrate the at least partially leached PCD table with a cobalt-based alloy infiltrant having a composition at or near a eutectic composition of the cobalt-based alloy infiltrant.
1. A polycrystalline diamond compact, comprising:
a cemented carbide substrate including a plurality of carbide grains cemented with a cementing constituent, wherein the cementing constituent includes a cobalt-based alloy having at least one eutectic forming alloying element in an amount at or near a eutectic composition for an alloy system of cobalt and the at least one eutectic forming alloying element; and
a preformed polycrystalline diamond table including a plurality of bonded diamond grains defining a plurality of interstitial regions, at least a portion of the plurality of interstitial regions including the cobalt-based alloy of the substrate disposed therein, wherein the cobalt-based alloy bonds the preformed polycrystalline diamond table to the substrate.
2. The polycrystalline diamond compact of claim 1 wherein the at least one eutectic forming alloying element is selected from the group consisting of carbon, silicon, boron, phosphorus, tantalum, tantalum carbide, niobium, molybdenum, antimony, and tin.
3. The polycrystalline diamond compact of claim 1 wherein the at least one eutectic forming alloying element is selected from the group consisting of silicon, boron, phosphorus, tantalum, and tantalum carbide.
4. The polycrystalline diamond compact of claim 1 wherein the total amount of the at least one eutectic forming alloying element of the cobalt-based alloy in the preformed polycrystalline diamond table is not above the eutectic composition point of the cobalt-based alloy.
5. The polycrystalline diamond compact of claim 1 wherein the composition of the cobalt-based alloy is 0.4 to 1.5 times the eutectic composition.
6. The polycrystalline diamond compact of claim 1 wherein the composition of the cobalt-based alloy is 0.9 to 1.1 times the eutectic composition.
7. The polycrystalline diamond compact of claim 1 wherein the at least one eutectic forming alloying element is silicon, and the silicon is present in the preformed polycrystalline diamond table in an amount less than 12.5% by weight of the cobalt-based alloy.
8. The polycrystalline diamond compact of claim 1 wherein the at least one eutectic forming alloying element is carbon, and the carbon is present in the preformed polycrystalline diamond table in an amount less than about 2.9% by weight cobalt-based alloy.
9. The polycrystalline diamond compact of claim 1 wherein the at least one eutectic forming alloying element is boron, and the boron is present in the preformed polycrystalline diamond table in an amount less than 5.5% by weight cobalt-based alloy.
10. The polycrystalline diamond compact of claim 1 wherein the at least one eutectic forming alloying element is phosphorus, and the phosphorus is present in the preformed polycrystalline diamond table in an amount less than 11.5% by weight cobalt-based alloy.
11. The polycrystalline diamond compact of claim 1 wherein the at least one eutectic forming alloying element is tantalum, and the tantalum is present in the preformed polycrystalline diamond table in an amount less than 32.4% by weight cobalt-based alloy.
12. The polycrystalline diamond compact of claim 1 wherein the cemented carbide substrate comprises a first substrate portion that includes the cobalt-based alloy and is bonded to the preformed polycrystalline diamond table, and a second substrate portion that receives the first substrate portion.
13. The polycrystalline diamond compact of claim 1 wherein the cobalt-based alloy comprises a cobalt solid solution phase and at least one additional phase including the at least one eutectic forming alloying element.
14. The polycrystalline diamond compact of claim 1 wherein the at least one eutectic forming alloying element is selected from the group consisting of carbon, phosphorus, tantalum carbide, antimony, and tin.
15. A rotary drill bit, comprising:
a bit body configured to engage a subterranean formation, the bit body including a plurality of blades; and
a plurality of polycrystalline diamond cutting elements attached to the plurality of blades, at least one of the plurality of polycrystalline diamond cutting elements including:
a cemented carbide substrate including a plurality of carbide grains cemented with a cementing constituent, wherein the cementing constituent includes a cobalt-based alloy having at least one eutectic forming alloying element in an amount at or near a eutectic composition for an alloy system of cobalt and the at least one eutectic forming alloying element; and
a preformed polycrystalline diamond table including a plurality of bonded diamond grains defining a plurality of interstitial regions, at least a portion of the plurality of interstitial regions including the cobalt-based alloy of the substrate disposed therein, wherein cobalt-based alloy bonds the preformed polycrystalline diamond table to the substrate.
16. A polycrystalline diamond compact, comprising:
a cemented carbide substrate including a plurality of carbide grains cemented with a cementing constituent, wherein the cementing constituent includes a cobalt-based alloy having at least one eutectic forming alloying element in an amount at or near a eutectic composition for an alloy system of cobalt and the at least one eutectic forming alloying element; and
a preformed polycrystalline diamond table attached to the substrate that includes a first region adjacent to the substrate and a second region remote from the substrate, the preformed polycrystalline diamond table including a plurality of bonded diamond grains defining a plurality of interstitial regions, at least a portion of the plurality of interstitial regions of the first region includes the cobalt-based alloy of the substrate disposed therein while the plurality of interstitial regions of the second region are substantially free of the cobalt-based alloy.
17. A polycrystalline diamond compact, comprising:
a cemented carbide substrate; and
a preformed polycrystalline diamond table attached to the substrate, the preformed polycrystalline diamond table including a plurality of bonded diamond grains defining a plurality of interstitial regions, at least a portion of the plurality of interstitial regions including a cobalt-based alloy disposed therein, wherein the cobalt-based alloy includes at least one eutectic forming alloying element in an amount at or near a eutectic composition for an alloy system of cobalt and the at least one eutectic forming alloying element, wherein the at least one eutectic forming alloying element is selected from the group consisting of carbon, phosphorus, antimony, and tin.
18. The polycrystalline diamond compact of claim 17 wherein the at least one eutectic forming alloying element is phosphorus.