Stainless steel for oil well, stainless steel pipe for oil well, and method of manufacturing stainless steel for oil well
View Patent ↗The chemical composition of a stainless steel in accordance with the present invention consists of C: not more than 0.05%, Si: not more than 0.5%, Mn: 0.01 to 0.5%, P: not more than 0.04%, S: not more than 0.01%, Cr: more than 16.0 and not more than 18.0%, Ni: more than 4.0 and not more than 5.6%, Mo: 1.6 to 4.0%, Cu: 1.5 to 3.0%, Al: 0.001 to 0.10%, and N: not more than 0.050%, the balance being Fe and impurities, and satisfies Formulas (1) and (2). Also, the micro-structure thereof contains a martensitic phase and a ferritic phase having a volume ratio of 10 to 40%, and the ferritic phase distribution ratio is higher than 85%. Cr+Cu+Ni+Mo≧25.5 (1) −8≦30(C+N)+0.5Mn+Ni+Cu/2+8.2−1.1(Cr+Mo)≦−4 (2)
1. A stainless steel for oil well, comprising:
a chemical composition comprising, by mass percent, C: not more than 0.05%, Si: not more than 0.5%, Mn: 0.01 to 0.13%, P: not more than 0.04%, S: not more than 0.01%, Cr: more than 16.0 and not more than 18.0%, Ni: more than 4.0and not more than 5.6%, Mo: 1.6 to 4.0%, Cu: 1.5 to 3.0%, Al: 0.001 to 0.10%, and N: not more than 0.050%, the balance being Fe and impurities, and satisfying Formulas (1) and (2):
Cr+Cu+Ni+Mo≧25.5 (1)
−8≦30(C+N)+0.5Mn+Ni+Cu/2+8.2−1.1(Cr+Mo)≦−4 (2)
where the content (percent by mass) of element is substituted for the symbol of element in Formulas (1) and (2);
a micro-structure containing a martensitic phase, a ferritic phase having a volume ratio of 10 to 40%, and a retained austenite phase having a volume ratio of 0to 10%, and being such that when a plurality of imaginary line segments, which each have a length of 50 μm in the thickness direction from the surface of the stainless steel and are arranged in a row at intervals of 10 μm over the range of 200 μm, are placed on a cross section of the stainless steel, the ratio of the number of imaginary line segments crossing the ferritic phase to the total number of imaginary line segments is higher than 85%; and
a 0.2% offset yield stress not lower than 758 MPa.
2. The stainless steel for oil well according to claim 1 , wherein the chemical composition further contains, in place of some of Fe, at least one kind selected from the group consisting of V: not more than 0.25%, Nb: not more than 0.25%, Ti: not more than 0.25%, and Zr: not more than 0.25%.
3. The stainless steel for oil well according to claim 1 , wherein the chemical composition further contains, in place of some of Fe, at least one kind selected from the group consisting of Ca: not more than 0.005%, Mg: not more than 0.005%, La: not more than 0.005%, and Ce: not more than 0.005%.
4. A stainless steel pipe comprising the stainless steel described in claim 1 .
5. The stainless steel for oil well according to claim 2 , wherein the chemical composition further contains, in place of some of Fe, at least one kind selected from the group consisting of Ca: not more than 0.005%, Mg: not more than 0.005%, La: not more than 0.005%, and Ce: not more than 0.005%.
6. A stainless steel pipe comprising the stainless steel described in claim 2 .
7. A stainless steel pipe comprising the stainless steel described in claim 3 .
8. A stainless steel pipe comprising the stainless steel described in claim 5 .