Poly(aryl ether sulfone) composition, and method of making

1. A method for preparing the poly(aryl ether sulfone),

comprising

reacting at least one bishydroxy aromatic compound with an aqueous mixture of alkali metal hydroxide, thereby forming bis salt of the bishydroxy aromatic compound;

drying the bis salt of the bishydroxy aromatic compound, thereby forming a dry bis salt of the bishydroxy aromatic compound;

reacting the dry bis salt of the bishydroxy aromatic compound with at least one dihalodiaryl sulfone in the presence of an organic solvent, an alkali metal carbonate, and a phase transfer catalyst at a temperature of 125-185° C. thereby forming the poly(aryl ether sulfone) wherein the organic solvent comprises ortho-dichlorobenzene, para-dichlorobenzene, dichlorotoluene, 1,2,4-trichlorobenzene, phenetole, anisole, veratrole, and mixtures thereof;

wherein a monofunctional phenoxide is added during the method in a sufficient amount to result in a poly(aryl ether sulfone) having a halogen content less than 3000 parts per million, based on the poly(aryl ether sulfone) weight.

2. The method of claim 1 , wherein the monofunctional phenoxide is added in situ when the at least one bishydroxy aromatic compound reacts with the aqueous mixture of alkali metal hydroxide, prior to the formation of the bis salt of the bishydroxy aromatic compound.

3. The method of claim 1 , wherein the bis salt of the bishydroxy aromatic compound is dried before the phase transfer catalyst is added.

4. The method of claim 1 , wherein the monofunctional phenoxide is added after the poly(aryl ether sulfone) forms.

5. The method of claim 1 , wherein the wherein the monofunctional phenoxide is selected from the group consisting of phenol, p-t-butyl-phenol, m-t-butyl-phenol, 4-hydroxybenzamide, 4-phenoxyphenol, 4-hydroxy-N,N-dimethylbenzamide, 4-ethynylphenol, 4-tert-butyl-2-methylphenol, 4-(2-phenylpropan-2-yl)phenol, (4-hydroxyphenyl)(phenyl)methanone, methyl 4-hydroxybenzoate, 4-(2,4-dimethylheptan-3-yl)phenol, para cumyl phenol, 4-phenyl phenol, para methyl phenol, para nonylphenols, o-t-butyl phenol, hydroxy benzoic acid esters, and combinations thereof.

6. The method of claim 1 , wherein the monofunctional phenoxide is selected from the group consisting of phenol, para cumyl phenol, 4-phenyl phenol, and combinations thereof.

7. The method of claim 1 , wherein the dry bis salt of the bishydroxy aromatic compound reacts with at least one dihalodiaryl sulfone in the presence of an organic solvent under conditions where the solvent-polymer mixture has a % solids is greater than 0 and less than 25 weight %, based on the total weight of the polymer and solvent mixture, and the reaction occurs at a temperature of 170 to 185° C.

8. The method of claim 1 , wherein the poly(aryl ether sulfone) comprises units of formula (I):

wherein Ar 1 is a divalent C 6 -C 15 aromatic group, Ar 2 is a divalent C 6 -C 15 aromatic group, Ar 3 is a divalent C 6 -C 15 aromatic group, and n is greater than 1;

and a terminal group of formula (II) derived from a monofunctional phenoxide

wherein X is a hydrogen atom or an organic substituent having from 1 to 20 carbon atoms and wherein the polymer is methoxy free and the polymer has an OH content greater than 0 and less than 50 ppm, based on polymer weight, a glass transition temperature of 180 to 290° C., a molecular weight of 20,000 to 100,000, and a halogen content of more than 0 and less than 3000 ppm.