Organic light-emitting element, organic light-emitting device, organic display panel, organic display device, and method of manufacturing an organic light-emitting element
View Patent ↗An organic light-emitting element includes a reflective anode, a first functional layer, an organic light-emitting layer that emits blue light, a second functional layer, a transparent cathode, and a coating layer. An optical thickness of the first functional layer is greater than 0 nm but not greater than 316 nm. A difference in refractive index between the transparent cathode and either a layer adjacent to the transparent cathode within the second functional layer or a layer adjacent to the transparent cathode within the coating layer is from 0.1 to 0.7 inclusive. The transparent cathode has a physical thickness greater than 0 nm but not greater than 70 nm, a refractive index from 2.0 to 2.4 inclusive, and an optical thickness greater than 0 nm but not greater than 168 nm.
1. An organic light-emitting element, comprising:
a first electrode that reflects incident light;
a second electrode, disposed to face the first electrode, that transmits incident light;
an organic light-emitting layer, disposed between the first electrode and the second electrode, that emits blue light;
a first functional layer disposed between the first electrode and the organic light-emitting layer and composed of one or more layers; and
a second functional layer disposed between the organic light-emitting layer and the second electrode and composed of one or more layers; and
a coating layer disposed to coat the second electrode and composed of one or more layers, wherein
a portion of the blue light emitted from the organic light-emitting layer travels a first optical path by passing through the first functional layer, striking and being reflected by the first electrode, and then being emitted externally after passing through the first functional layer, the organic light-emitting layer, the second functional layer, the second electrode, and the coating layer,
a remaining portion of the blue light emitted from the organic light-emitting layer travels a second optical path by travelling through the second functional layer towards the second electrode, instead of towards the first electrode, and being emitted externally after passing through the second electrode and the coating layer,
an optical thickness of the first functional layer is at most equal to 316 nm,
a difference in refractive index between the second electrode and a layer adjacent to the second electrode among the one or more layers composing the second functional layer is from 0.1 to 0.7 inclusive,
the second electrode has a physical thickness at most equal to 70 nm, a refractive index from 2.0 to 2.4 inclusive, and an optical thickness at most equal to 168 nm, and
a difference in refractive index between the second electrode and a layer adjacent to the second electrode among the one or more layers composing the coating layer is from 0.1 to 0.7 inclusive.
2. The organic light-emitting element according to claim 1 , wherein the following holds:
X 3 =Rx cos θ cos φ− Ry sin θ sin φ+ X 0
Y 3 =Rx cos θ sin φ+ Ry sin θ cos φ+ Y 0
−φ≦θ≦π−φ
X 0=31 , Y 0=35 , Rx =5.2 , Ry =27, φ=0.15( rad )
X 3 being the physical thickness of the first functional layer and Y 3 being the physical thickness of the second electrode.
3. The organic light-emitting element according to claim 1 , wherein the following holds:
X 3 =Rx cos θ cos φ− Ry sin θ sin φ+ X 0
Y 3 =Rx cos θ sin φ+ Ry sin θ cos φ+ Y 0
−φ≦θ≦π−φ
X 0=130, Y 0=35, Rx= 8, Ry =15, φ=0.20( rad )
X 3 being the physical thickness of the first functional layer and Y 3 being the physical thickness of the second electrode.
4. The organic light-emitting element according to claim 1 , wherein
a refractive index of the layer adjacent to the second electrode among the one or more layers composing the second functional layer is from 1.7 to 2.1 inclusive, and
a refractive index of the layer adjacent to the second electrode among the one or more layers composing the coating layer is from 1.7 to 2.1 inclusive.
5. The organic light-emitting element according to claim 1 , wherein
the physical thickness of the second electrode is from 30 nm to 60 nm inclusive, and the optical thickness of the second electrode is from 60 nm to 144 nm inclusive.
6. The organic light-emitting element according to claim 1 , wherein
the physical thickness of the second electrode is from 30 nm to 70 nm inclusive, and the optical thickness of the second electrode is from 60 nm to 168 nm inclusive.
7. The organic light-emitting element according to claim 1 , wherein
the second functional layer includes an electron transport layer that transports electrons to the organic light-emitting layer,
the second electrode is a cathode, and
the coating layer includes a first passivation layer formed on the cathode and a second passivation layer formed on the first passivation layer.
8. The organic light-emitting element according to claim 7 , wherein
the electron transport layer has a physical thickness from 31.5 nm to 38.5 nm inclusive and a refractive index from 1.7 to 2.1 inclusive,
the cathode has a physical thickness from 31.5 nm to 38.5 nm inclusive, a refractive index from 2.0 to 2.4 inclusive, and an optical thickness from 63 nm to 92.4 nm inclusive,
the first passivation layer has a physical thickness from 558 nm to 682 nm inclusive and a refractive index from 1.7 to 2.1 inclusive, and
the second passivation layer has a physical thickness from 5400 nm to 6600 nm inclusive and a refractive index from 1.3 to 1.7 inclusive.
9. The organic light-emitting element according to claim 1 , wherein
the first electrode is an anode, and
the first functional layer includes a transparent conductive layer formed on the anode, a hole injection layer formed on the transparent conductive layer, and a hole transport layer formed on the hole injection layer.
10. The organic light-emitting element according to claim 7 , wherein
the first electrode is an anode, and
the first functional layer includes a transparent conductive layer formed on the anode, a hole injection layer formed on the transparent conductive layer, and a hole transport layer formed on the hole injection layer.
11. The organic light-emitting element according to claim 9 , wherein
the transparent conductive layer has a physical thickness from 14.4 nm to 17.6 nm inclusive and a refractive index from 1.9 to 2.3 inclusive,
the hole injection layer has a physical thickness from 4.5 nm to 5.5 nm inclusive and a refractive index from 1.8 to 2.2 inclusive, and
the hole transport layer has a physical thickness from 9 nm to 11 nm inclusive and a refractive index from 1.5 to 1.9 inclusive.
12. The organic light-emitting element according to claim 9 , wherein
the transparent conductive layer has a physical thickness from 63 nm to 77 nm inclusive and a refractive index from 1.9 to 2.3 inclusive,
the hole injection layer has a physical thickness from 36 nm to 44 nm inclusive and a refractive index from 1.8 to 2.2 inclusive, and
the hole transport layer has a physical thickness from 18 nm to 22 nm inclusive and a refractive index from 1.5 to 1.9 inclusive.
13. The organic light-emitting element according to claim 10 , wherein
the transparent conductive layer has a physical thickness from 14.4 nm to 17.6 nm inclusive and a refractive index from 1.9 to 2.3 inclusive,
the hole injection layer has a physical thickness from 4.5 nm to 5.5 nm inclusive and a refractive index from 1.8 to 2.2 inclusive, and
the hole transport layer has a physical thickness from 9 nm to 11 nm inclusive and a refractive index from 1.5 to 1.9 inclusive.
14. The organic light-emitting element according to claim 10 , wherein
the transparent conductive layer has a physical thickness from 63 nm to 77 nm inclusive and a refractive index from 1.9 to 2.3 inclusive,
the hole injection layer has a physical thickness from 36 nm to 44 nm inclusive and a refractive index from 1.8 to 2.2 inclusive, and
the hole transport layer has a physical thickness from 18 nm to 22 nm inclusive and a refractive index from 1.5 to 1.9 inclusive.
15. The organic light-emitting element according to claim 1 , wherein
the optical thickness of the first functional layer is from 49.0 nm to 73.5 nm inclusive, and
the optical thickness of the second electrode is from 63 nm to 92.4 nm inclusive.
16. The organic light-emitting element according to claim 1 , wherein
the optical thickness of the first functional layer is from 212 nm to 316 nm inclusive, and
the optical thickness of the second electrode is from 63 nm to 92.4 nm inclusive.
17. An organic light-emitting device including the organic light-emitting element according to claim 1 .
18. An organic display panel including the organic light-emitting element according to claim 1 .
19. An organic display device including the organic light-emitting element according to claim 1 .
20. A method of manufacturing an organic light-emitting element, the organic light-emitting element including:
a first electrode that reflects incident light;
a second electrode, disposed to face the first electrode, that transmits incident light;
an organic light-emitting layer, disposed between the first electrode and the second electrode, that emits blue light;
a first functional layer disposed between the first electrode and the organic light-emitting layer and composed of one or more layers; and
a second functional layer disposed between the organic light-emitting layer and the second electrode and composed of one or more layers; and
a coating layer disposed to coat the second electrode and composed of one or more layers,
the organic light-emitting element being configured such that a portion of the blue light emitted from the organic light-emitting layer travels a first optical path by passing through the first functional layer, striking and being reflected by the first electrode, and then being emitted externally after passing through the first functional layer, the organic light-emitting layer, the second functional layer, the second electrode, and the coating layer,
the organic light-emitting element being further configured such that a remaining portion of the blue light emitted from the organic light-emitting layer travels a second optical path by travelling through the second functional layer towards the second electrode, instead of towards the first electrode, and being emitted externally after passing through the second electrode and the coating layer,
the method of manufacturing the organic light-emitting element comprising:
preparing the first electrode that reflects the incident light;
forming, on the first electrode, the first functional layer composed of the one or more layers;
forming, on the first functional layer, the organic light-emitting layer that emits the blue light;
forming, on the organic light-emitting layer, the second functional layer composed of the one or more layers that differ from the first functional layer;
forming, on the second functional layer, the second electrode that transmits the incident light; and
coating the second electrode with the coating layer composed of the one or more layers, wherein
the first functional layer is formed to have an optical thickness at most equal to 316 nm,
material used to form the second functional layer is such that a difference in refractive index between the second electrode and a layer adjacent to the second electrode among the one or more layers composing the second functional layer is from 0.1 to 0.7 inclusive,
the second electrode is formed to have a physical thickness at most equal to 70 nm, a refractive index from 2.0 to 2.4 inclusive, and an optical thickness at most equal to 168 nm, and
material used to form the coating layer is such that a difference in refractive index between the second electrode and a layer adjacent to the second electrode among the one or more layers composing the coating layer is from 0.1 to 0.7 inclusive.
21. The method of manufacturing an organic light-emitting element of claim 20 , wherein
the first functional layer and the second electrode are formed so that the following holds:
X 3 =Rx cos θ cos φ− Ry sin θ sin φ+ X 0
Y 3 =Rx cos θ sin φ+ Ry sin θ cos φ+ Y 0
−φ≦θ≦π−φ
X 0=31 , Y 0=35 , Rx =5.2 , Ry =27, φ=0.15( rad )
X 3 being the physical thickness of the first functional layer and Y 3 being the physical thickness of the second electrode.
22. The method of manufacturing an organic light-emitting element of claim 20 , wherein
the first functional layer and the second electrode are formed so that the following holds:
X 3 =Rx cos θ cos φ− Ry sin θ sin φ+ X 0
Y 3 =Rx cos θ sin φ+ Ry sin θ cos φ+ Y 0
−φ≦θ≦π−φ
X 0=130, Y 0=35, Rx= 8, Ry =15, φ=0.20( rad )
X 3 being the physical thickness of the first functional layer and Y 3 being the physical thickness of the second electrode.
23. The method of manufacturing an organic light-emitting element of claim 20 , wherein
material having a refractive index from 1.7 to 2.1 inclusive is used to form the layer adjacent to the second electrode among the one or more layers composing the second functional layer, and
material used to form the coating layer is such that a refractive index of the layer adjacent to the second electrode among the one or more layers composing the coating layer is from 1.7 to 2.1 inclusive.
24. The method of manufacturing an organic light-emitting element of claim 20 , wherein
an anode is formed as the first electrode,
as the first functional layer, a transparent conductive layer is formed on the anode, a hole injection layer is formed on the transparent conductive layer, and a hole transport layer is formed on the hole injection layer,
the transparent conductive layer is formed from material having a refractive index from 1.9 to 2.3 inclusive and is formed to have a physical thickness from 14.4 nm to 17.6 nm inclusive,
the hole injection layer is formed from material having a refractive index from 1.8 to 2.2 inclusive and is formed to have a physical thickness from 4.5 nm to 5.5 nm inclusive,
the hole transport layer is formed from material having a refractive index from 1.5 to 1.9 inclusive and is formed to have a physical thickness from 9 nm to 11 nm inclusive,
the organic light-emitting layer is formed from material having a refractive index from 1.6 to 2.0 inclusive and is formed to have a physical thickness from 36 nm to 44 nm inclusive,
as the second functional layer, an electron transport layer that transports electrons to the organic light-emitting layer is formed from material having a refractive index from 1.7 to 2.1 inclusive and is formed to have a physical thickness from 31.5 nm to 38.5 nm inclusive,
as the second electrode, a cathode is formed on the electron transport layer from material having a refractive index from 2.0 to 2.4 inclusive, is formed to have a physical thickness from 31.5 nm to 38.5 nm inclusive, and is formed to have an optical thickness from 63 nm to 92.4 nm inclusive,
as the coating layer, a first passivation layer is formed on the cathode and a second passivation layer is formed on the first passivation layer,
the first passivation layer is formed from material having a refractive index from 1.7 to 2.1 inclusive and is formed to have a physical thickness from 558 nm to 682 nm inclusive, and
the second passivation layer is formed from material having a refractive index from 1.3 to 1.7 inclusive and is formed to have a physical thickness from 5400 nm to 6600 nm inclusive.
25. The method of manufacturing an organic light-emitting element of claim 20 , wherein
an anode is formed as the first electrode,
as the first functional layer, a transparent conductive layer is formed on the anode, a hole injection layer is formed on the transparent conductive layer, and a hole transport layer is formed on the hole injection layer,
the transparent conductive layer is formed from material having a refractive index from 1.9 to 2.3 inclusive and is formed to have a physical thickness from 63 nm to 77 nm inclusive,
the hole injection layer is formed from material having a refractive index from 1.8 to 2.2 inclusive and is formed to have a physical thickness from 36 nm to 44 nm inclusive,
the hole transport layer is formed from material having a refractive index from 1.5 to 1.9 inclusive and is formed to have a physical thickness from 18 nm to 22 nm inclusive,
the organic light-emitting layer is formed from material having a refractive index from 1.6 to 2.0 inclusive and is formed to have a physical thickness from 36 nm to 44 nm inclusive,
as the second functional layer, an electron transport layer that transports electrons to the organic light-emitting layer is formed from material having a refractive index from 1.7 to 2.1 inclusive and is formed to have a physical thickness from 31.5 nm to 38.5 nm inclusive,
as the second electrode, a cathode is formed on the electron transport layer from material having a refractive index from 2.0 to 2.4 inclusive, is formed to have a physical thickness from 31.5 nm to 38.5 nm inclusive, and is formed to have an optical thickness from 63 nm to 92.4 nm inclusive,
as the coating layer, a first passivation layer is formed on the cathode and a second passivation layer is formed on the first passivation layer,
the first passivation layer is formed from material having a refractive index from 1.7 to 2.1 inclusive and is formed to have a physical thickness from 558 nm to 682 nm inclusive, and
the second passivation layer is formed from material having a refractive index from 1.3 to 1.7 inclusive and is formed to have a physical thickness from 5400 nm to 6600 nm inclusive.
26. The organic light-emitting element according to claim 1 , the portion of blue light emitted from the organic light-emitting layer along the first optical path and the remaining portion of the blue light emitted from the organic light-emitting layer along the second optical path strengthen each other through an interference effect.
27. The organic light-emitting element according to claim 1 , wherein a portion of the blue light emitted from the second electrode, which travels a third optical path by being directly emitted through the second electrode, and a remaining portion of the blue light emitted from the second electrode, which travels a fourth optical path by being emitted after multiple reflections in the second electrode at the boundary surfaces with the second functional layer and with the coating layer, strengthen each other through an interference effect.
28. The method of manufacturing an organic light-emitting element of claim 20 , the portion of blue light emitted from the organic light-emitting layer along the first optical path and the remaining portion of the blue light emitted from the organic light-emitting layer along the second optical path strengthen each other through an interference effect.
29. The method of manufacturing an organic light-emitting element of claim 20 , wherein the organic light-emitting element is further configured such that a portion of the blue light emitted from the second electrode, which travels a third optical path by being directly emitted through the second electrode, and a remaining portion of the blue light emitted from the second electrode, which travels a fourth optical path by being emitted after multiple reflections in the second electrode at the boundary surfaces with the second functional layer and with the coating layer, strengthen each other through an interference effect.