Method for producing silica particles
View Patent ↗A method for producing silica particles, includes preparing a silica particle dispersion containing silica particles, and a solvent containing an alcohol and water, and bringing supercritical carbon dioxide into contact with the silica particle dispersion to remove the solvent.
1. A method for producing silica particles, comprising:
preparing a silica particle dispersion containing silica particles, and a solvent containing an alcohol and water, and
bringing supercritical carbon dioxide into contact with the silica particle dispersion to remove the solvent,
wherein supercritical carbon dioxide is brought into contact with the silica particle dispersion to remove the solvent, in which y represented by Formula (1) satisfies a range of Formula (2-1):
y =((mass of water in silica particle dispersion/mass of alcohol in silica particle dispersion)/temperature (° C.) during removal of the solvent) Formula (1):
0.0003≦y≦0.0012 Formula (2-1).
2. The method for producing silica particles according to claim 1 , wherein in the preparation of the silica particle dispersion, the mass ratio of water to the alcohol in the silica particle dispersion is from about 0.03 to about 0.3.
3. The method for producing silica particles according to claim 1 , wherein in the preparation of the silica particle dispersion, the mass ratio of water to the silica particles in the silica particle dispersion is from about 0.02 to about 3.
4. The method for producing silica particles according to claim 1 , wherein the silica particles are obtained by reaction of a silane compound in the presence of an alkaline catalyst.
5. The method for producing silica particles according to claim 1 , wherein the mass ratio of water to the silica particles in the silica dispersion is from about 0.05 to about 1.
6. The method for producing silica particles according to claim 1 , wherein in the preparation of the silica particle dispersion, the mass ratio of water to the alcohol in the silica particle dispersion is from about 0.05 to about 0.2.
7. The method for producing silica particles according to claim 1 , wherein in the removal of the solvent, the temperature of supercritical carbon dioxide is in the range which is from about 31° C. to about 350° C.
8. The method for producing silica particles according to claim 1 , wherein in the removal of the solvent, the pressure of supercritical carbon dioxide is in the range which is from about 7.38 MPa to about 40 MPa.
9. The method for producing silica particles according to claim 1 , wherein a hydrophobization treatment is further included after removal of the solvent.
10. The method for producing silica particles according to claim 4 , wherein the silane compound is tetraalkoxysilane.
11. The method for producing silica particles according to claim 10 , wherein the tetraalkoxysilane is selected from tetramethoxysilane, tetraethoxysilane, tetrapropoxysilane, and tetrabutoxysilane.
12. The method for producing silica particles according to claim 10 , wherein the amount of tetraalkoxysilane to be supplied is from about 0.001 mol/(mol·min) to about 0.01 mol/(mol·min) with respect to the moles of alcohol in the alkaline catalyst solution.
13. The method for producing silica particles according to claim 12 , wherein the alkaline catalyst is a basic catalyst.
14. The method for producing silica particles according to claim 13 , wherein the alkaline catalyst is selected from ammonia, urea, a monoamine, and a quaternary ammonium salt.