Palladium-containing catalyst, method for producing same, and method for producing α, β-unsaturated carboxylic acid
View Patent ↗Disclosed is a palladium-containing catalyst which enables to produce an α,β-unsaturated carboxylic acid in high selectivity from an olefin or an α,β-unsaturated aldehyde. Also disclosed are a method for producing such a catalyst and a method for producing an α,β-unsaturated carboxylic acid using such a catalyst. Specifically disclosed is a palladium-containing catalyst containing 0.001 to 0.25 mole of antimony element to 1 mole of palladium element or a palladium-containing catalyst containing palladium element which composes a metal, tellurium element, and bismuth element.
1. A method for producing an α,β-unsaturated carboxylic acid, comprising:
oxidizing at least one of an olefin and an α,β-unsaturated aldehyde with molecular oxygen, wherein the oxidizing is carried out in the liquid phase with a reduced palladium-containing catalyst, and
wherein the reduced palladium-containing catalyst comprises palladium, tellurium and bismuth,
wherein the molar ratio of the bismuth element to the palladium element, Bi/Pd, in the palladium-containing catalyst is from 0.002 to 0.26.
2. The method according to claim 1 , wherein the reduced palladium-containing catalyst comprises from 0.002 to 0.30 mole of tellurium per mole of palladium.
3. The method according to claim 1 , further comprising:
reducing a compound containing palladium with a reducing agent to form the reduced palladium-containing catalyst.
4. The method according to claim 1 , further comprising:
reducing a compound containing tellurium to form the reduced palladium-containing catalyst.
5. The method according to claim 1 , further comprising:
simultaneously reducing a compound containing palladium and a compound containing tellurium to form the reduced palladium-containing catalyst.
6. The method according to claim 1 , further comprising:
reducing a compound comprising palladium to form the reduced palladium-containing catalyst after impregnating a carrier with the compound containing palladium.
7. The method according to claim 1 , wherein the reduced palladium-containing catalyst comprises from 0.003 to 0.25 mole of tellurium per mole of palladium.
8. The method according to claim 1 , further comprising:
mixing a compound containing palladium and a compound containing tellurium, wherein each of the compound containing palladium and the compound containing tellurium are in an oxidized state, to form a mixture, then
reducing the mixture to form the reduced palladium-containing catalyst.
9. The method according to claim 1 , wherein the oxidizing is carried out on at least one olefin selected from the group consisting of propylene and isobutylene.
10. The method according to claim 1 , wherein the oxidizing is carried out on an α,β-unsaturated aldehyde selected from the group consisting of acrolein, methacrolein, crotonaldehyde, cinnamaldehyde and mixtures thereof.
11. The method according to claim 1 , wherein the molar ratio of bismuth element to palladium element, Bi/Pd, is from 0.003 to 0.10.
12. The method according to claim 1 , wherein the palladium-containing catalyst is present on a carrier during the oxidizing.
13. The method according to claim 12 , wherein the carrier is silica.