Non-tacky wetness indicator composition for application on a polymeric substrate
View Patent ↗The invention describes a color-developing composition that contains at least three major components: (1) a leuco dye or a combination of leuco dyes, (2) an color-developer or a combination of color-developers that can form colored complexes with the leuco dyes, and (3) a desensitizer to temporarily remove the effect of the developer so the leuco dye appears in its colorless form. An optional binder may be included so that the composition may be applied to a substrate as an ink. The ink composition may be applied to synthetic polymeric substrates and other substrates that are incorporated into absorbent articles or personal care products.
1. A color-developing composition comprising:
a color-appearing leuco dye;
a color-developer; and
a desensitizer;
wherein the desensitizer is a zwitterionic small molecule having a molecular weight of 100 to 800.
2. The color-developing composition of claim 1 wherein the desensitizer comprises betaine.
3. The color-developing composition of claim 1 wherein the desensitizer is selected from the group consisting of poly sugar betaine C, Betaine ester-menthol and Betaine hydrochloride.
4. The color-developing composition of claim 1 wherein the desensitizer is soluble in a volatile organic solvent and water.
5. The color-developing composition of claim 4 wherein the volatile organic solvent comprises ethanol.
6. The color-developing composition of claim 1 wherein the leuco dye and color developer are water insoluble.
7. The color-developing composition of claim 1 wherein the desensitizer comprises Girard's reagent.
8. The color-developing composition of claim 1 wherein the molecular weight is 100 to 500.
9. The color-developing composition of claim 1 wherein the molecular weight is 200 to 400.
10. The color-developing composition of claim 1 wherein the zwitterionic molecules comprises 2-(methacryloyloxy)ethyl 3-sulfopropyl)ammonium hydroxide.
11. The color-developing composition of claim 1 further comprising a binder.
12. The color-developing composition of claim 11 wherein the binder is water soluble.
13. The color-developing composition of claim 1 wherein the color-developer comprises bisphenol A, zinc chloride, zinc salicylate, and/or phenol resins.
14. The color-developing composition of claim 1 wherein the leuco dye comprises phthalide leuco dye, triarylmethane leuco dye, and/or fluoran leuco dye.
15. A color changing material comprising:
a substrate having an ink deposited thereon;
wherein the ink comprises a color-appearing leuco dye; a color-developer; and
a desensitizer; and
wherein the desensitizer is selected from the group consisting of betaine and/or Girard's reagent.
16. The color changing material of claim 15 wherein the substrate is a porous material.
17. The color changing material of claim 15 comprises a synthetic polymer.
18. An absorbent article with a color-changing feature, the absorbent article comprising:
a topsheet;
a backsheet having a garment-facing surface and an opposite body-facing surface;
an absorbent core disposed between the topsheet and the back sheet; and
a color-changing composition comprising a leuco-dye and a developer, the color-changing composition deposited onto the body-facing surface of the backsheet; the color-changing composition further comprising a zwitterionic small molecule desensitizer having a molecular weight between 100 and 500.
19. The absorbent article of claim 18 wherein the color-changing composition comprises betaine.
20. The absorbent article of claim 18 wherein the color-changing composition forms indicia.