Systems and methods for oxidation of synthesis gas tar
View Patent ↗A process of gasification and the production of synthesis gas. A process of biomass gasification and the reduction or elimination of tars from the hydrocarbon-rich product gas derived from biomass gasification. Systems and methods for the reduction of tar from a synthesis gas derived from biomass gasification are provided.
1. A method for removing tar from a gas, the method comprising: contacting a first gas comprising tar with a second gas comprising oxygen for time period sufficient to effect oxidation of at least a portion of the tar in the first gas, thus producing an oxidized product gas that comprises less tar than the first gas; and
adjusting the rate of oxidation to a rate at which substantially complete mixing of the first gas with the second gas is achieved before the oxygen in the second gas is completely consumed.
2. The method of claim 1 , wherein the second gas is selected from the group consisting of substantially pure oxygen, air, and oxygen-enriched air.
3. The method of claim 1 , wherein the first gas comprises synthesis gas.
4. The method of claim 3 , wherein the molar ratio of H 2 /CO in the oxidized product gas is greater than the molar ratio of H 2 /CO in the first gas.
5. The method of claim 3 , wherein the molar ratio of H 2 /CO in the oxidized product gas is at least twice as large as the molar ratio of H 2 /CO in the first gas.
6. The method of claim 1 , wherein contacting the first gas with the second gas is performed in the presence of a fluidized medium.
7. The method of claim 6 , wherein the fluidized medium is selected from the group consisting of calcined dolomite, limestone, olivine sand, calcium containing materials, and combinations thereof.
8. The method of claim 1 , wherein the rate of oxidation is adjusted by cooling the second gas prior to contacting thereof with the first gas.
9. The method of claim 8 further comprising producing at least a portion of the first gas by introducing a biomass feedstock to a gasifier, wherein heat from a fluidized particulate material causes the gasification of at least a portion of the biomass feedstock to form a tar-containing product gas, and wherein the at least a portion of the first gas is cooled to a temperature less than the gasification temperature and greater than the temperature at which at least a portion of the tar condenses prior to contacting thereof with the second gas.
10. The method of claim 1 , wherein the rate of oxidation is adjusted by utilizing a second gas comprising a diluent in addition to oxygen.
11. A method for removing tar from a gas, the method comprising:
producing a first gas, comprising tar by introducing a biomass feedstock to a gasifier, wherein heat from a fluidized particulate material therein causes the gasification of at least a portion of the biomass feedstock to form a tar-containing product gas; and
contacting at least a portion of the first gas with a second gas comprising oxygen for time period sufficient to effect oxidation of at least a portion of the tar in the first gas, thus producing an oxidized product gas that comprises less tar than the first gas.
12. The method of claim 11 further comprising:
heating a fluidized particulate material in a combustor; and
transferring the heated fluidized particulate material to the gasifier.
13. The method of claim 12 , wherein at least a portion of the biomass feedstock is converted to char in the gasifier and wherein the method further comprises transferring at least a portion of the char out of the gasifier.
14. The method of claim 13 , further comprising (a) separating fluidized particulate material and optionally char produced in the gasifier from the tar-containing product gas, (b) transferring at least a portion of the char to the combustor and combusting the transferred char to heat the fluidized particulate material, or both (a) and (b).
15. The method of claim 11 further comprising cooling the at least a portion of the tar-containing product gas in the first gas prior to contacting the first gas with the second gas.
16. The method of claim 11 further comprising operating the gasifier at a temperature in the range of from about 1200° F. to about 1500° F.
17. The method of claim 16 , wherein the rate of heat transfer between the heated fluidized particulate material and the biomass feedstock is sufficient to convert at least about 70% of the carbon in the biomass feedstock into the tar-containing product gas.
18. The method of claim 11 , further comprising carrying out the contacting of the first gas with the second gas in a fluidized bed reactor selected from the group consisting of conventional bubbling bed reactors, circulating fluid bed reactors, multi-solid fluid bed reactors, and combinations thereof.
19. The method of claim 11 , wherein the oxidized product gas has a total combustion energy that is greater than the total combustion energy of the first gas, comprises substantially no tar, or both.