Making ductility-enhanced magnesium alloy sheet materials
View Patent ↗A method of enhancing the ductility of magnesium alloy sheets containing 85% or more by weight of magnesium is described. An annealed, substantially strain free, sheet of generally uniform grain size is locally deformed in local regions to develop strained ‘islands’ of a predetermined strain embedded in a substantially strain-free matrix and then annealed. The deformed regions undergo recrystallization and grain growth while the remainder of the sheet suffers only minor change in grain size, leading to sheet with grains having a bimodal size distribution. The ductility of alloys processed in this way is significantly greater than the ductility of the unprocessed, uniform grain size alloy without compromise to the tensile strength of the alloy.
1. A method of improving the room temperature tensile elongation of a magnesium-based alloy sheet with a thickness, the sheet having an initial annealed microstructure comprising strain-free grains of substantially uniform size, by forming in the sheet a microstructure comprising grains of two distinguishable size ranges, the method comprising:
deforming the sheet, in a single rolling operation at a temperature no higher than about 160° C. to distribute, the deformation producing a substantially uniform distribution of closely-spaced, strained, portions of the sheet embedded in substantially undeformed sheet portions; and
annealing the sheet at a temperature and for a time suitable for producing, in the strained, closely-spaced, embedded portions, grains larger than the grains in the substantially undeformed sheet portions to develop a microstructure in which the grain sizes comprise a bimodal distribution in which a majority of the grains have sizes which lie within one of two size ranges of between about 10 and 25 micrometers and between about 70 and 100 micrometers, the regions with grains of between about 70 and 100 micrometers developing in the previously-strained portions.
2. The method of claim 1 in which the magnesium sheet is deformed by rolling between roughened rolls, the roughened rolls comprising protrusions extending outwardly from the roll surface, the protrusions having a length of less than 10% of the sheet thickness, the rolling being conducted at a temperature below about 160° C. to reduce the sheet thickness by about 1%.
3. The method of claim 1 in which the magnesium sheet is deformed by rolling between substantially smooth rolls without heating the sheet to reduce its thickness by between about 2% and 5%.
4. The method of claim 1 in which annealing temperature is about 350° C. and the annealing time ranges from about 15 minutes to about 30 minutes.
5. The method of claim 1 in which the annealing temperature ranges from about 350° C. to about 500° C.
6. The method of claim 1 in which the closely-spaced strained portions of the sheet are spaced apart by about 500 micrometers.
7. The method of claim 1 in which about 75% of the volume of the sheet contains grains which lie in the size ranges of the bimodal distribution.
8. The method of claim 1 in which a first volume of the sheet comprises grains ranging in size from about 10 to 25 micrometers and a second volume of the sheet comprises grains ranging in size from about 70 to 100 micrometers and the ratio of the first volume to the second volume is about 2:1.
9. The method of claim 1 in which the magnesium alloy is AZ31.
10. A magnesium alloy sheet with a microstructure comprising closely-spaced, and substantially uniformly distributed clusters of grains of a first size range of between about 70 and 100 micrometers embedded within a plurality of grains of a second, smaller size range of between about 10 and 25 micrometers, the sheet having greater tensile ductility and comparable tensile strength than a sheet of the same alloy with a microstructure comprising grains of substantially similar size.
11. The magnesium alloy sheet of claim 10 in which the clusters of grains ranging from 70 to 100 micrometers in size are spaced apart by about 500 micrometers.
12. The magnesium alloy sheet of claim 10 in which a first volume of the sheet comprises grains ranging in size from about 10 to 25 micrometers and a second volume of the sheet comprises grains ranging in size from about 70 to 100 micrometers and the ratio of the first volume to the second volume is about 2:1.
13. The magnesium alloy sheet of claim 10 in which the magnesium alloy is AZ31.
14. A method of improving the room temperature tensile elongation of a magnesium-based alloy sheet with a thickness and an initial microstructure comprising annealed strain-free grains of substantially uniform size, by forming in the sheet a microstructure comprising grains of two differing size ranges, the method comprising:
deforming the sheet by rolling the sheet between roughened rolls comprising protrusions extending outwardly from the roll surface, the protrusions having a length of less than 10% of the sheet thickness, the rolling being conducted in a single pass at a temperature of about 25° C. to reduce the sheet thickness by about 1% to thereby distribute, substantially uniformly, strained portions of the sheet embedded in substantially undeformed sheet portions; and
annealing the sheet at a temperature and for a time suitable for producing, in the strained, closely-spaced, embedded portions, grains larger than the grains in the substantially undeformed sheet portions to develop a microstructure in which the grain sizes comprise a bimodal distribution in which a majority of the grains have sizes which lie within size ranges of about from 10 to 25 micrometers and about from 70 to 100 micrometers, the regions with grains of between about 70 and 100 micrometers developing in the previously-strained portions.
15. The method of claim 14 in which the magnesium sheet is deformed by rolling, in a single pass, between substantially smooth rolls to reduce its thickness by between about 2% and 5%.
16. The method of claim 14 in which annealing temperature is about 350° C. and the annealing time ranges from about 15 minutes to about 30 minutes.
17. The method of claim 14 in which the annealing temperature ranges from about 350° C. to about 500° C.
18. The method of claim 14 in which the length of the protrusions ranges from 2% to 5% of the sheet thickness.