Methods of making a reinforced composite and reinforced composite products
View Patent ↗In some embodiments, the instant invention provides methods for making reinforced composites and reinforced composite products. In one embodiment, a method includes adding (a) a carrier including a salt and (b) a plurality of substantially inert sub-micron sized particles into a molten metal to form a mixture; and forming a reinforced composite from the mixture, the reinforced composite including a non-particulate metal portion having the substantially inert sub-micron sized particles therein.
1. A method comprising:
adding (a) a carrier comprising a salt and (b) a plurality of substantially inert sub-micron sized particles into a molten metal, wherein at least some of the plurality of substantially inert sub-micron sized particles include a contaminant on an outermost surface;
forming a mixture comprising the molten metal and the plurality of substantially inert sub-micron sized particles, wherein the salt is configured as a wetting aid to remove at least a portion of the contaminants from the substantially inert sub-micron sized particles to promote incorporation of the submicron sized particles into the melt via wetting; and
producing a reinforced composite from the mixture,
wherein the reinforced composite comprises a non-particulate metal portion having the substantially inert sub-micron sized particles therein;
further wherein, via the forming step, the reinforced composite includes an interface between the substantially inert sub-micron sized particles and the non-particulate metal portion that is substantially contaminant free.
2. The method of claim 1 , wherein, due to the adding step, the reinforced composite comprises an oxide concentration of less than about 100 ppm in the metal portion.
3. The method of claim 1 , wherein the adding step further comprises adding sub-micron sized particles selected from the group consisting of: nanoparticles, carbon nanotubes, magnetic sub-micron sized particles, non-metallic sub-micron sized particles, ceramic particles; and combinations thereof.
4. The method of claim 1 , wherein the forming step comprises forming a reinforced composite product having particles with an average aspect ratio of about 1:5.
5. The method of claim 1 , wherein the forming step comprises forming the reinforced composite having not greater than 25 vol. % of sub-micron sized particles.
6. The method of claim 1 , wherein the forming step comprises forming the reinforced composite having not less than 0.1 vol. % of sub-micron sized particles therein.
7. The method of claim, 1 , wherein the adding step further comprises mixing.
8. The method of claim 7 , wherein the mixing step further comprises:
mixing the salt and at least one of: an alloying element, a grain refiner or combinations thereof.
9. The method of claim 1 , further comprising: producing a metal product from the reinforced composite.
10. The method of claim 9 , further wherein producing comprises:
extruding the reinforced composite.
11. The method of claim 10 , wherein the extruding step comprises: forming at least one of: a rod, a bar, a tube, a wire, or combinations thereof.
12. The method of claim 10 , wherein the producing step comprises: rolling the reinforced composite to form a plate, a sheet, a foil, or combinations thereof.
13. The method of claim 10 , wherein the producing step comprises: casting the reinforced composite into a final shape.
14. The method of claim 1 , further wherein the adding step comprises: adding a carrier substance comprising an inert gas.
15. A method comprising:
adding (a) a carrier comprising a salt and (b) a plurality of substantially inert sub-micron sized particles into a molten metal, wherein at least some of the plurality of substantially inert sub-micron sized particles are selected from the group consisting of: magnesium aluminate, magnesium hydroxide, aluminum nitride, aluminum oxide, aluminum titanate, silica, silicon dioxide, silicon nitride, calcium oxide, calcium phosphate, calcium titanate, calcium zirconate, titanium nitride, titanium silicon oxide, titanium oxide, nickel chromium oxide, nickel oxide, copper aluminum oxide, copper zinc alloy, yttrium oxide, gadolinium oxide, copper oxide, tungsten oxide, molybdenum oxide, zirconium silicate, aluminum cerium oxide, cerium oxide, tungsten, bismuth oxide, nickel, selenide, V 2 O 5 , C—BN, WS 2 , and combinations thereof;
wherein the substantially inert sub-micron sized particles include a contaminant on an outermost surface;
forming a mixture comprising the molten metal and the plurality of substantially inert sub-micron sized particles, wherein the salt is configured to remove at least a portion of the contaminants from the substantially inert sub-micron sized particles to promote incorporation of the submicron sized particles into the melt; and
producing a reinforced composite from the mixture,
wherein the reinforced composite comprises a non-particulate metal portion having the substantially inert sub-micron sized particles therein;
further wherein, via the forming step, the reinforced composite includes an interface between the substantially inert sub-micron sized particles and the non-particulate metal portion that is substantially contaminant free.
16. The method of claim 15 , further wherein the adding step comprises: adding a carrier substance comprising an inert gas.
17. The method of claim 15 , further comprising removing a top layer from the mixture and solidifying the reinforced product.
18. The method of claim 15 , further comprising: producing a metal product from the reinforced composite.
19. The method of claim 18 , further wherein producing comprises:
extruding the reinforced composite to form at least one of: a rod, a bar, a tube, a wire, or combinations thereof.
20. The method of claim 15 , further comprising molding the reinforced composite to form a product.