IP Library Granted Patent US 8,629,402
Granted Patent B2
US 8,629,402 · App. 13/300,925 · Granted Jan 14, 2014

X-ray imaging panel with thermally-sensitive adhesive and methods of making thereof

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Quick Facts
Patent No.
US 8,629,402
App. No.
13/300,925
Granted
Jan 14, 2014
Kind
B2
Abstract

Provided herein are scintillator screens comprising a substrate; a scintillation layer disposed over the substrate, the scintillation layer comprising a scintillator material; and an adhesive layer disposed by solvent coating over the scintillation layer, the adhesive layer comprising solvent-coatable thermally-sensitive elastomer, wherein the adhesive layer has a dust adhesion of ≦1 dust particles/sq.in.

Claims (31)

1. A scintillator screen comprising:

a substrate;

a scintillation layer disposed over the substrate, the scintillation layer comprising a scintillator material; and

an adhesive layer disposed by solvent coating over the scintillation layer, the adhesive layer comprising solvent-coatable thermally-sensitive elastomers, wherein the adhesive layer has a dust adhesion of ≦1 dust particles/sq.in.

2. The scintillator screen of claim 1 , wherein the thermally-sensitive elastomer is selected from the group consisting of thermoset polymers, thermoplastic polymers, and combinations thereof.

3. The scintillator screen of claim 2 , wherein the solvent-coatable thermoset polymers are selected from the group consisting of polyesters, epoxies, urea/formaldehyde, melamine, cyanate esters, polyurethane, and combinations thereof.

4. The scintillator screen of claim 2 , wherein the thermoplastic polymers are selected from the group consisting of acrylic, polyethylene, polypropylene, cellulose acetate, polystyrene, polyurethane, and combinations thereof.

5. The scintillator screen of claim 1 , wherein the solvent-coatable thermally-sensitive elastomer is a thermoplastic polyurethane.

6. The scintillator screen of claim 1 , wherein the adhesive layer has an adhesive strength greater than about 8 lbf/in.

7. The scintillator screen of claim 1 , wherein the adhesive layer has an adhesive strength greater than about 12 lbf/in.

8. The scintillator screen of claim 1 , wherein the solvent-coatable thermally-sensitive elastomer is present in the adhesive layer in an amount ranging from about 10% to about 100%.

9. The scintillator screen of claim 1 , wherein the scintillator material comprises at least one phosphor selected from the group consisting of Y 2 SiO 5 :Ce; Y 2 Si 2 O 7 :Ce; LuAlO 3 :Ce; Lu 2 SiO 5 :Ce; Gd 2 SiO 5 :Ce; YAlO 3 :Ce; ZnO:Ga; CdWO 4 ; LuPO 4 :Ce; PbWO 4 ; Bi 4 Ge 3 O 12 ; CaWO 4 ; GdO 2 S:Tb, GdO 2 S:Pr; RE 3 Al5O 12 :Ce, and combinations thereof, wherein RE is at least one rare earth metal.

10. The scintillator screen of claim 1 , wherein the scintillator material is present in the scintillation layer in an amount ranging from about 50% by volume to about 99% by volume, relative to the total volume of the scintillation layer.

11. The scintillator screen of claim 1 , further comprising a fiber optic plate coupled to the scintillator screen by an adhesive layer comprising thermally-sensitive elastomers to form an X-ray imaging element.

12. A method of making a scintillator screen, comprising:

solvent coating an adhesive solution on a scintillation screen comprising a scintillator material to form a coated surface, the adhesive solution comprising a solvent and a solvent-coatable thermally-sensitive elastomer; and

drying the coated surface of the scintillation screen to create an adhesive layer.

13. The method of claim 12 , further comprising:

contacting the adhesive layer on the scintillation screen with a fiber optic glass plate; and

laminating the fiber optic glass plate and the scintillation screen to produce a laminated X-ray imaging element.

14. The method of claim 12 , wherein the thermally-sensitive elastomer is selected from the group consisting of thermoset polymers, thermoplastic polymers, and combinations thereof.

15. The method of claim 12 , wherein the thermally-sensitive elastomer is a thermoplastic polyurethane.

16. The method of claim 12 , wherein the thermally-sensitive elastomer is present in the adhesive solution in an amount ranging from about 0.1% to about 50%.

17. A method of making an X-ray imaging panel comprising:

solvent coating an adhesive solution on an X-ray imaging element to form a coated surface, wherein the X-ray imaging element comprises a scintillation screen coupled to a fiber optic glass plate, and wherein the adhesive solution comprises thermally-sensitive elastomers;

drying the coated surface of the X-ray imaging element to create an adhesive layer;

contacting the adhesive layer on the X-ray imaging element with at least one photodetector; and

laminating the X-ray imaging element to the at least one photodetector.

18. The method of claim 17 , wherein the thermally-sensitive elastomer is selected from the group consisting of thermoset polymers, thermoplastic polymers, and combinations thereof.

19. The method of claim 17 , wherein the thermally-sensitive elastomer is a thermoplastic polyurethane.

20. The method of claim 17 , wherein the thermally-sensitive elastomer is present in the adhesive solution in an amount ranging from about 0.1% to about 50%.

Assignments (8)
RELEASE OF SECURITY INTEREST IN INTELLECTUAL PROPERTY (SECOND LIEN) Recorded Oct 14, 2022
From: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH
To: CARESTREAM HEALTH, INC.; CARESTREAM DENTAL LLC; QUANTUM MEDICAL IMAGING, L.L.C.; TROPHY DENTAL INC.
Reel/Frame 061683/0601 →
RELEASE OF SECURITY INTEREST IN INTELLECTUAL PROPERTY (FIRST LIEN) Recorded Oct 14, 2022
From: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH
To: CARESTREAM HEALTH, INC.; CARESTREAM DENTAL LLC; QUANTUM MEDICAL IMAGING, L.L.C.; TROPHY DENTAL INC.
Reel/Frame 061683/0441 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 14, 2017
From: CARESTREAM HEALTH, INC.
To: CARESTREAM DENTAL TECHNOLOGY TOPCO LIMITED
Reel/Frame 044873/0520 →
RELEASE OF SECURITY INTEREST Recorded Sep 1, 2017
From: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH
To: CARESTREAM DENTAL LLC; CARESTREAM HEALTH, INC.; CARESTREAM HEALTH LTD.; RAYCO (SHANGHAI) MEDICAL PRODUCTS CO., LTD.; CARESTREAM HEALTH FRANCE
Reel/Frame 043749/0243 →
RELEASE OF SECURITY INTEREST Recorded Sep 1, 2017
From: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH
To: CARESTREAM DENTAL LLC; CARESTREAM HEALTH, INC.; CARESTREAM HEALTH LTD.; RAYCO (SHANGHAI) MEDICAL PRODUCTS CO., LTD.; CARESTREAM HEALTH FRANCE
Reel/Frame 043749/0133 →
SECOND LIEN INTELLECTUAL PROPERTY SECURITY AGREEMENT Recorded Jul 1, 2013
From: CARESTREAM HEALTH, INC.; CARESTREAM DENTAL LLC; QUANTUM MEDICAL IMAGING, L.L.C.; TROPHY DENTAL INC.
To: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH
Reel/Frame 030724/0154 →
AMENDED AND RESTATED INTELLECTUAL PROPERTY SECURITY AGREEMENT (FIRST LIEN) Recorded Jun 28, 2013
From: CARESTREAM HEALTH, INC.; CARESTREAM DENTAL LLC; QUANTUM MEDICAL IMAGING, L.L.C.; TROPHY DENTAL INC.
To: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH
Reel/Frame 030711/0648 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 22, 2012
From: AYLWARD, BRIAN P.; JAGANNATHAN, SESHADRI; BISHOP, KEVIN L.; LOMBARDO, RICHARD A.
To: CARESTREAM HEALTH, INC.
Reel/Frame 027740/0059 →