Inkjet-printed flexible electronic components from graphene oxide
An electrical component includes an inkjet-printed graphene electrode. Graphene oxide flakes are deposited on a substrate in a graphene oxide ink using an inkjet printer. The deposited graphene oxide is thermally reduced to graphene. The electrical properties of the electrode are comparable to those of electrodes made using activated carbon, carbon nanotubes or graphene made by other methods. The electrical properties of the graphene electrodes may be tailored by adding nanoparticles of other materials to the ink to serve as conductivity enhancers, spacers, or to confer pseudocapacitance. Inkjet-printing can be used to make graphene electrodes of a desired thickness in preselected patterns. Inkjet printing can be used to make highly-transparent graphene electrodes. Inkjet-printed graphene electrodes may be used to fabricate double-layer capacitors that store energy by nanoscale charge separation at the electrode-electrolyte interface (i.e., “supercapacitors”).
1. An electrical component, comprising an inkjet-printed electrode on a flexible substrate, said electrode including a plurality of overlapping dot-like structures which include graphene flakes, wherein said plurality of dot-like structures is distributed in said electrode such that said electrode has a transparency of at least about 80 percent.
2. An electrical component, comprising an inkjet-printed electrode on a flexible substrate, said electrode including a plurality of overlapping dot-like structures which include graphene flakes, wherein said electrode is a first electrode, said electrical component further comprising a second inkjet-printed electrode on a second flexible substrate, said second electrode including a plurality of overlapping dot-like structures which include graphene flakes, said first and second electrodes being separated from each other by an electrically-insulating membrane.
3. An electrical component, comprising an inkjet-printed electrode on a flexible substrate, said electrode including a plurality of overlapping dot-like structures which include graphene flakes, further comprising a second inkjet-printed electrode on said substrate, said second electrode including a plurality of overlapping dot-like structures which include graphene flakes, said substrate being an electrically-insulating substrate and said first and second electrodes being spaced apart by a distance from each other.
4. An electrical component, comprising an inkjet-printed electrode on a flexible substrate, said electrode including a plurality of overlapping dot-like structures which include graphene flakes, wherein said electrode is fabricated by a process including the steps of depositing graphene oxide flakes onto said flexible substrate, and then reducing at least some of said deposited graphene oxide to graphene.
5. The electrical component of claim 4 , wherein said graphene oxide flakes are deposited onto said flexible substrate in droplets of a water-based graphene oxide ink so as to form said overlapping dot-like structures in a predetermined pattern, said dot-like structures including said graphene oxide flakes.
6. The electrical component of claim 4 , wherein said depositing step is performed so as to build said electrode to a desired thickness.
7. The electrical component of claim 4 , wherein said reducing step is performed at a temperature in the range of about 140° C. to about 800° C. under an inert atmosphere for a period of time in the range of about 4 hours to about 12 hours.
8. The electrical component of claim 4 , wherein said reducing step is performed by means of a source of infrared radiation.
9. A double-layer capacitor, comprising
a first inkjet-printed electrode including a first plurality of overlapping dot-like structures which include graphene flakes;
a second inkjet-printed electrode including a second plurality of overlapping dot-like structures which include graphene flakes; and
an electrically-insulating, ionically conducting material separating said first and second electrodes.