Systems and methods for separating condensable vapors from gases by direct-contact heat exchange
Condensable vapors such as carbon dioxide are separated from light gases in a process stream. The systems and methods employ a direct exchange heat exchanger to desublimate the condensable vapors from the process stream. The condensable vapors are condensed by directly contacting a heat exchange liquid in the direct contact heat exchanger while the uncondensed light gases from the process stream form a separated light-gas stream. The separated light-gas stream can be used in a recuperative heat exchanger to cool the process stream.
1. A system for separating condensable vapors from light gases by desublimating the condensable vapors, comprising:
a heat exchanger configured to precool a condensable-vapor-containing process stream;
a direct contact heat exchanger (DCHE) vessel downstream from the heat exchanger, the DCHE vessel including a non-volatile heat exchange liquid (NVHEL) within a vessel, the vessel having a process stream inlet, a light gas outlet, and a desublimated solids outlet, the process stream inlet configured to cause a precooled condensable-vapor-containing process stream received from the heat exchanger to directly contact the NVHEL within the DCHE vessel,
wherein the system is configured to cool the NVHEL to a temperature and pressure such that direct contact of the NVHEL with the process stream causes the condensable vapors to desublimate and form separated cool gases and a slurry comprising desublimated solids and the NVHEL,
the separated light-gas stream exiting the DCHE vessel through the light gas outlet,
the desublimated solids exiting the DCHE vessel through the desublimated solids outlet; and
a solids separator that separates at least a portion of the desublimated solids from the NVHEL.
2. A system as in claim 1 , wherein the solids separator is downstream from the desublimated solids outlet of the DCHE vessel.
3. A system as in claim 1 , further comprising a fluid recirculation loop that provides a fluid path from the desublimated solids outlet to the NVHEL inlet of the DCHE vessel and comprising a recirculation heat exchanger.
4. A system as in claim 3 , wherein the light gas outlet is coupled to the recirculation heat exchanger to cool the NVHEL.
5. A system as in claim 1 , wherein the process stream inlet is in fluid communication with a flue gas source.
6. A system as in claim 1 , configured to operate at a pressure within a range from about 5 psi pressure to about 500 psi.
7. A system as in claim 1 , configured to operate at a pressure within a range from about atmospheric pressure to about 5 psi.
8. A system as in claim 1 , the heat exchanger comprising a recuperative upstream heat exchanger configured to cool the process stream upstream from the DCHE vessel using the separated light gases downstream from the light gas outlet of the DCHE vessel.
9. A system as in claim 1 , the heat exchanger comprising a recuperative upstream heat exchanger configured to cool the process stream upstream from the DCHE vessel using the separated solids downstream from the solids outlet of the DCHE vessel.
10. A system as in claim 1 , wherein the DCHE vessel includes a plurality of porous dividers configured to cause contact between the NVHEL and the process stream.
11. A system for separating condensable vapors, comprising a plurality of staged subsystems, wherein each subsystem includes the system as in claim 1 , wherein the DCHE vessels of the staged subsystems are staged to provide solids removal over a range of temperatures and conditions and wherein the staging preserves counter-current heat exchange in the heat exchangers of the staged subsystems or provides cross current or co-current heat exchange, or a combination thereof.
12. A system as in claim 1 , wherein the NVHEL inlet is in fluid communication with an interior sprayer that produces NVHEL droplets in the DCHE vessel.
13. A system as in claim 1 , wherein the DCHE vessel includes a distribution apparatus in fluid communication with the process stream inlet that injects the process stream into the NVHEL.
14. A system as in claim 1 , further comprising at least one of a valve, pump or auger for removing a slurry containing the NVHEL and desublimated solids from the DCHE vessel.
15. A method for separating condensable vapors from gases by sublimating the condensable vapors, comprising:
providing a process stream that includes condensable vapors and light gases;
cooling the process stream using one or more up-stream heat exchangers;
contacting the process stream with a non-volatile heat exchange liquid (NVHEL);
desublimating the condensable vapors within the NVHEL to form cooled light gases and a slurry comprising desublimated solids and the NVHEL;
separating the slurry from the cooled light gases to produce a separated light-gas stream; and
separating at least a portion of the desublimated solids from the NVHEL.
16. A method as in claim 15 , wherein the NVHEL is selected from the group consisting of methyl cyclopentane, methyl cyclohexane, a fluorinated or chlorinated hydrocarbons, or a combination thereof.
17. A method as in claim 15 , wherein the desublimated solids are separated from the NVHEL either before or after pressurizing the slurry.
18. A method as in claim 15 , wherein the NVHEL separated from the desumblimated solids is reused in the contacting step.
19. A method as in claim 18 , wherein the separated light-gas stream is used in a recirculation heat exchanger to cool the recirculating NVHEL.
20. A method as in claim 19 , further comprising cooling the process stream to a temperature within a range from the desublimation temperature of carbon dioxide to approximately two degrees Celsius above the desublimation temperature before contacting the process stream with the NVHEL.
21. A method as in claim 15 , further comprising desublimating or condensing one or more process stream impurities.
22. A system for separating condensable vapors from light gases by desublimating the condensable vapors, comprising:
a direct contact heat exchanger (DCHE) vessel including a non-volatile heat exchange liquid (NVHEL) within a vessel, the vessel having a process stream inlet, a light gas outlet, and a desublimated solids outlet, the process stream inlet configured to cause a condensable-vapor-containing process stream to directly contact the NVHEL within the DCHE vessel,
wherein the system is configured to cool the NVHEL to a temperature and pressure such that direct contact of the NVHEL with the process stream causes the condensable vapors to desublimate and form separated cool gases and a slurry comprising desublimated solids and the NVHEL,
the separated light-gas stream exiting the DCHE vessel through the light gas outlet,
the desublimated solids exiting the DCHE vessel through the desublimated solids outlet;
a solids separator that separates at least a portion of the desublimated solids from the NVHEL; and
a fluid recirculation loop that provides a fluid path from the desublimated solids outlet to the NVHEL inlet of the DCHE and comprises a recirculation heat exchanger, wherein the light gas outlet is coupled to the recirculation heat exchanger to cool the NVHEL.
23. A system for separating condensable vapors from light gases by desublimating the condensable vapors, comprising:
a direct contact heat exchanger (DCHE) vessel including a non-volatile heat exchange liquid (NVHEL) within a vessel, the vessel having a process stream inlet, a light gas outlet, and a desublimated solids outlet, the process stream inlet configured to cause a condensable-vapor-containing process stream to directly contact the NVHEL within the DCHE vessel,
wherein the system is configured to cool the NVHEL to a temperature and pressure such that direct contact of the NVHEL with the process stream causes the condensable vapors to desublimate and form separated cool gases and a slurry comprising desublimated solids and the NVHEL,
the separated light-gas stream exiting the DCHE vessel through the light gas outlet,
the desublimated solids exiting the DCHE vessel through the desublimated solids outlet;
a solids separator that separates at least a portion of the desublimated solids from the NVHEL; and
a recuperative upstream heat exchanger configured to cool the process stream upstream from the DCHE vessel using at least one of (i) the separated light gases downstream from the light gas outlet of the DCHE vessel or (ii) the separated solids downstream from the solids outlet of the DCHE vessel.
24. A system for separating condensable vapors from light gases by desublimating the condensable vapors, comprising:
a direct contact heat exchanger (DCHE) vessel including a non-volatile heat exchange liquid (NVHEL) within a vessel, the vessel having a process stream inlet, a light gas outlet, and a desublimated solids outlet, the process stream inlet configured to cause a condensable-vapor-containing process stream to directly contact the NVHEL within the DCHE vessel,
wherein the system is configured to cool the NVHEL to a temperature and pressure such that direct contact of the NVHEL with the process stream causes the condensable vapors to desublimate and form separated cool gases and a slurry comprising desublimated solids and the NVHEL,
the separated light-gas stream exiting the DCHE vessel through the light gas outlet,
the desublimated solids exiting the DCHE vessel through the desublimated solids outlet,
wherein the DCHE vessel includes a plurality of porous dividers configured to cause contact between the NVHEL and the process stream; and
a solids separator that separates at least a portion of the desublimated solids from the NVHEL.
25. A system for separating condensable vapors from light gases by desublimating the condensable vapors, comprising:
a direct contact heat exchanger (DCHE) vessel including a non-volatile heat exchange liquid (NVHEL) within a vessel, the vessel having a process stream inlet, a light gas outlet, and a desublimated solids outlet, the process stream inlet configured to cause a condensable-vapor-containing process stream to directly contact the NVHEL within the DCHE vessel,
wherein the system is configured to cool the NVHEL to a temperature and pressure such that direct contact of the NVHEL with the process stream causes the condensable vapors to desublimate and form separated cool gases and a slurry comprising desublimated solids and the NVHEL,
the separated light-gas stream exiting the DCHE vessel through the light gas outlet,
the desublimated solids exiting the DCHE vessel through the desublimated solids outlet,
wherein the DCHE vessel includes a distribution apparatus in fluid communication with the process stream inlet that injects the process stream into the NVHEL; and
a solids separator that separates at least a portion of the desublimated solids from the NVHEL.
26. A system for separating condensable vapors from light gases by desublimating the condensable vapors, comprising:
a plurality of staged subsystems, wherein each subsystem includes:
a direct contact heat exchanger (DCHE) vessel including a non-volatile heat exchange liquid (NVHEL) within a vessel, the vessel having a process stream inlet, a light gas outlet, and a desublimated solids outlet, the process stream inlet configured to cause a condensable-vapor-containing process stream to directly contact the NVHEL within the DCHE vessel,
wherein the system is configured to cool the NVHEL to a temperature and pressure such that direct contact of the NVHEL with the process stream causes the condensable vapors to desublimate and form separated cool gases and a slurry comprising desublimated solids and the NVHEL,
the separated light-gas stream exiting the DCHE vessel through the light gas outlet,
the desublimated solids exiting the DCHE vessel through the desublimated solids outlet; and
a solids separator that separates at least a portion of the desublimated solids from the NVHEL,
wherein the DCHE vessels of the staged subsystems are staged to provide solids removal over a range of temperatures and conditions and wherein the staging preserves counter-current heat exchange in the heat exchangers of the staged subsystems or provides cross current or co-current heat exchange, or a combination thereof.
27. A method for separating condensable vapors from gases by sublimating the condensable vapors, comprising:
providing a process stream that includes condensable vapors and light gases;
cooling the process stream using one or more up-stream heat exchangers to a temperature within a range from the desublimation temperature of carbon dioxide to approximately two degrees Celsius above the desublimation temperature;
providing a direct contact heat exchanger (DCHE) including a non-volatile heat exchange liquid (NVHEL) within a vessel;
introducing the cooled process stream from the one or more up-stream heat exchangers into the DCHE and desublimating the condensable vapors within the NVHEL to form cooled light gases and a slurry comprising desublimated solids and the NVHEL;
separating the slurry from the cooled light gases to produce a separated light-gas stream;
separating at least a portion of the desublimated solids from the NVHEL;
recirculating the NVHEL to the DCHE after separation from the desublimated solids;
using the separated light-gas stream in a recirculation heat exchanger to cool the recirculating NVHEL.