Spherical rubber chemicals and the method for preparing the same
The present invention provides spherical rubber chemicals and the method for preparing the same. The spherical rubber chemicals of the present invention include spherical antioxidants, spherical vulcanization agents, spherical processing aids, spherical reinforcing agents, or spherical adhesive agents. With the spherical rubber chemicals of the present invention, the shortcomings of powdery or semi-spherical rubber chemicals are overcome, including eliminating the dust pollution during granulation procedure and avoiding the raw material loss and the environmental pollution, while solving the quality problem of lower melting point of product caused by the presence of fine powder crystal. Furthermore, the resultant rubber chemicals has an improved smoothness of surface, which is helpful to improve the flowing and mixing behaviors of the rubber chemicals in mixing or open milling process with rubbers.
1. A method for preparing spherical rubber chemicals, comprising an overhead granulation step, a step of cooling and forming in a cooling liquid and a cooling liquid-removing step, wherein,
said method further comprising a pre-crystallizing step prior to the over head granulation step, and;
in the overhead granulation step, a material tank and a distribution plate are detached from each other and are separated by a thermal insulating layer,
and;
in the overhead granulation step, a heating and/or cooling medium is provided for the distribution plate, small holes and intermediate holes are disposed from top to bottom in the distribution plate, the small holes have a diameter of 0.1-5 mm and the intermediate hole nozzles have a diameter of 0.2-10 mm.
2. The method according to claim 1 , wherein large holes are disposed below the intermediate holes with a distance of 0.5-5 mm between the inner wall of a large hole and the outer wall of a intermediate hole nozzle.
3. The method according to claim 1 , wherein, in the overhead granulation step, a chamfer angle is disposed at the lower end of the nozzle.
4. The method according to claim 1 , wherein, in the overhead granulation step, the material drips naturally by gravity, under pressure by a reciprocating motion or under a constant pressure by a high viscosity feeding pump.
5. The method according to claim 2 , wherein dripping under pressure by a reciprocating motion is adopted in the overhead granulation step.
6. The method according to claim 1 , wherein, in the overhead granulation step, the dripping rate from a nozzle is 1-4 drops/second.
7. The method according to claim 1 , wherein, in the cooling and forming step, a surfactant is added into the cooling liquid in a cooling tower and/or ultrasonic wave is applied to the cooling liquid.
8. The method according to claim 5 , wherein the cooling liquid is at least one selected from the group consisting of water, aqueous ammonia, an aqueous solution of a salt and an organic substance.
9. The method according to claim 6 , wherein the cooling liquid is selected from the group consisting of water, aqueous ammonia, an aqueous solution of methanol, an aqueous solution of sodium chloride, gasoline or acetone.
10. The method according to claim 7 , wherein the surfactant is at least one selected from the group consisting of polyethylene glycol ether, polypropylene glycol ether, fatty alcohol polyoxyethylene ether, alkyl benzene sulfonate compound, quaternary ammonium salt compound, alkyl alcohol ammonium type surfactant and betaine type surfactant.
11. The method according to claim 10 , wherein the fatty alcohol in the fatty alcohol polyoxyethylene ether has 6-18 carbon atoms and the polymerization degree of polyoxyethylene is 3-25.
12. The method according to claim 10 , wherein the betaine type surfactant is selected from a group consisting of cocoamidopropyl betaine, dimethylalkyl betaine and N,N-dimethyl-N-alkoxymethylene betaine.