Polyoxymethylene modified with imidized acrylic resins
View Patent ↗Described herein are compositions comprising (a) 92 to 99 weight percent, of polyoxymethylene with number average molecular weight from 65,000 to 250,000 g/mole; and (b) 1 to 8 weight percent of an imidized acrylic resin obtained by treating an acrylic polymer with a monoalkyl amine, wherein the weight percents of a and b are based on their combined weight, and monoalkyl group has from one to five carbon atoms, the degree of imidization is 20% to 100% and the acid level is from 0 to about 2 weight percent of the imidized acrylic resin. The composition has significantly higher heat deflection temperature than the neat polyoxymethylene. Processes of increasing heat deflection temperature of POM compositions are described herein by blending (a) and (b), wherein the resultant melt-mixed composition has a 200% increase or greater in time to 5% creep strain relative to the same melt-mixed composition lacking (b).
1. A thermoplastic composition comprising:
(a) 92 to 99 weight percent, based on the combined weight of (a) and (b), of polyoxymethylene with number average molecular weight from 20,000 to 250,000 g/mole; and
(b) about 1 to about 8 weight percent, based on the combined weight of (a) and (b), of an imidized acrylic resin obtained by treating an acrylic polymer with a monoalkyl amine wherein the monoalkyl group has from one to five carbon atoms, the degree of imidization is 20% to 100% and the acid level is from 0 to 2 weight percent of the imidized acrylic resin.
2. The composition of claim 1 wherein the imidized acrylic resin comprises cyclic imide units.
3. The composition of claim 1 wherein the imidized acrylic resin is obtained by treating an acrylic polymer with methylamine.
4. The composition of claim 1 wherein the imidized acrylic resin is obtained by treating poly(methyl methacrylate) with methylamine.
5. The composition of claim 1 wherein the imidized acrylic resin is present in the composition in an amount from 1 to 5 weight percent.
6. The composition of claim 1 wherein the polyoxymethylene has a number average molecular weight from 50,000 to 100,000 g/mole.
7. The composition of claim 6 wherein the polyoxymethylene has a number average molecular weight from 50,000 to 80,000 g/mole.
8. The composition of claim 1 wherein the acrylic polymer is poly(methyl methacrylate), poly(methyl acrylate), or a copolymer of methyl methacrylate or methyl acrylate and at least one additional comonomer selected from styrene, acrylonitrile, vinyl acetate, ethylene, butadiene or methyl vinyl ether.
9. The composition of claim 8 wherein the acrylic polymer is poly(methyl methacrylate).
10. The composition of claim 1 wherein the degree of imidization is from 60% to 100%.
11. The composition of claim 10 wherein the degree of imidization is from 80% to 100%.
12. The composition of claim 11 wherein the degree of imidization is from 90% to 100%.
13. An article comprising the composition of claim 1 having a heat deflection temperature determined according to ASTM D-648 that exceeds that of a comparison standard article wherein the shaped article and the comparison standard article have the same shape and structure with the exception that the comparison standard article is prepared from a polyoxymethylene composition that does not comprise an imidized acrylic resin.
14. The article of claim 13 wherein the composition comprises a polyoxymethylene having a number average molecular weight from 50,000 to 100,000 g/mole.
15. The article of claim 13 wherein the imidized acrylic resin is obtained by treating an acrylic polymer with methylamine and the acrylic polymer is poly(methyl methacrylate), poly(methyl acrylate), or a copolymer of methyl methacrylate or methyl acrylate and at least one additional comonomer selected from styrene, acrylonitrile, vinyl acetate, ethylene, butadiene or methyl vinyl ether.
16. The article of claim 15 wherein the imidized acrylic resin is obtained by treating poly(methyl methacrylate) with methylamine.
17. The article of claim 15 wherein the degree of imidization is from 80A % to 100%.
18. The article of claim 13 that is in the form of sheet, profile, rod stock, film, filament, fiber, strapping, tape, tubing, or pipe.
19. The article of claim 13 that is a machine or engine part.
20. A method for preparing a shaped article comprising a composition, the method comprising
(1) melt blending a first polyoxymethylene composition, wherein the first polyoxymethylene has a number average molecular weight from 20,000 to 250,000 g/mole, with an imidized acrylic resin, wherein the imidized acrylic resin is obtained by treating an acrylic polymer with a monoalkyl amine wherein the monoalkyl group has from one to five carbon atoms, the degree of imidization is 20% to 100% and the acid level is from 0 to about 2 weight percent of the imidized acrylic resin to provide a molten thermoplastic composition;
(2) forming the molten composition into a desired shape, and
(3) cooling the molten composition to provide a shaped article;
wherein the shaped article has a heat deflection temperature determined according to ASTM D-648 that exceeds that of a comparison standard article wherein the shaped article and the comparison standard article have the same shape and structure with the exception that the comparison standard article is prepared from the first polyoxymethylene composition that does not comprise an imidized acrylic resin.