Organic electroluminescence display device and manufacturing method thereof
View Patent ↗An organic electroluminescence display includes a first electrode and an auxiliary wire each either on or in a substrate. A luminescent layer is over the first electrode, and a hole transport layer is between the luminescent layer and the first electrode. The hole transport layer extends from over the first electrode to over the auxiliary wire. A second electrode is over the luminescent layer and extends from over the first electrode to over the auxiliary wire. A metal layer is over the auxiliary wire between the hole transport layer and the second electrode. The second electrode and the auxiliary wire are electrically connected via the hole transport layer and the metal layer. The metal layer comprises a metal, wherein a difference of a work function value of the metal minus an absolute value of an energy level of a lowest unoccupied molecular orbit of the hole transport layer is at most approximately 0.5 eV.
1. An organic electroluminescence display, comprising:
a substrate;
a first electrode one of on and in the substrate;
an auxiliary wire one of on and in the substrate;
a luminescent layer over the first electrode, the luminescent layer comprising a luminescent substance;
an organic layer between the luminescent layer and the first electrode and extending over the first electrode and the auxiliary wire, the organic layer comprising an organic material;
a second electrode over the luminescent layer and extending over the first electrode and the auxiliary wire; and
a metal layer contacting the organic layer over the auxiliary wire and between the organic layer and the second electrode,
wherein the second electrode and the auxiliary wire are electrically connected via the organic layer and the metal layer
the second electrode and the auxiliary wire are electrically connected via the organic layer and the metal layer, and
metallic atoms of the metal layer are configured to diffuse for causing the organic layer over the auxiliary wire to be conductive.
2. The organic electroluminescence display according to claim 1 ,
wherein the metal layer comprises a metal,
a difference of a work function value of the metal minus an absolute value of an energy level of a lowest unoccupied molecular orbit of the organic layer is at most approximately 0.5 eV,
the organic layer over the first electrode and the auxiliary wire comprises a non-n-doped organic material, and
the organic layer contacts the metal layer over the auxiliary wire and is n-doped.
3. The organic electroluminescence display according to claim 1 ,
wherein the difference of the work function value of the metal minus the absolute value of the energy level of the lowest unoccupied molecular orbit of the organic layer is at least approximately −0.5 eV.
4. The organic electroluminescence display according to claim 1 ,
wherein an n-dope concentration of the organic layer over the auxiliary wire is greater than an n-dope concentration of the organic layer over the first electrode.
5. The organic electroluminescence display according to claim 1 ,
wherein the metal layer is a single layer that extends from over the auxiliary wire to over the first electrode.
6. The organic electroluminescence display according to claim 5 ,
wherein the metal layer is an electron injection layer for injecting an electron into the luminescent layer over the first electrode.
7. The organic electroluminescence display according to claim 1 ,
wherein metal atoms of the metal layer diffuse, over the auxiliary wire, to a vicinity of a second principal surface of the organic layer, the second principal surface being opposite a first principal surface of the organic layer that is an interface between the organic layer and the metal layer.
8. The organic electroluminescence display according to claim 7 ,
wherein the vicinity of the second principal surface is at most approximately 5 nm from the second principal surface.
9. The organic electroluminescence display according to claim 1 ,
wherein the metal layer comprises at least one of an alkali metal and an alkali earth metal.
10. The organic electroluminescence display according to claim 1 ,
wherein the organic layer over the auxiliary wire has a thickness from greater than 0 nm to approximately 50 nm.
11. The organic electroluminescence display according to claim 1 ,
wherein the organic layer comprises an aromatic amine.
12. A method of manufacturing an organic electroluminescence display having a luminescent pixel, the method comprising:
providing a first electrode one of on and in a substrate;
providing an auxiliary wire one of on and in the substrate;
providing an organic layer over the first electrode and over the auxiliary wire, the organic layer comprising a non-n-doped organic material;
providing a luminescent layer over the first electrode, the organic layer between the luminescent layer and the first electrode for transporting holes to the luminescent layer, the luminescent layer comprising a luminescent substance;
providing a metal layer over the auxiliary wire and over the organic layer;
providing a second electrode over the luminescent layer and extending from over the first electrode to over the auxiliary wire, the metal layer between the second electrode and the organic layer, the second electrode and the auxiliary wire being electrically connected via the metal layer and the organic layer,
wherein metallic atoms of the metal layer are configured to diffuse for causing the organic layer over the auxiliary wire to be conductive.
13. The method according to claim 12 ,
wherein the metal layer comprises a metal, and a difference of a work function value of the metal minus an absolute value of an energy level of a lowest unoccupied molecular orbit of the organic layer is at most approximately 0.5 eV, and
the organic layer contacts the metal layer over the auxiliary wire and is n-doped.