Electrolyte for electrochemical device, method for preparing the electrolyte and electrochemical device including the electrolyte
View Patent ↗Disclosed is a solid electrolyte for an electrochemical device. The solid electrolyte includes a composite consisting of: a plastic crystal matrix electrolyte doped with an ionic salt; and a network of a non-crosslinked polymer and a crosslinked polymer structure. The electrolyte has high ionic conductivity comparable to that of a liquid electrolyte due to the use of the plastic crystal, and high mechanical strength comparable to that of a solid electrolyte due to the introduction of the non-crosslinked polymer/crosslinked polymer structure network. Particularly, the electrolyte is highly flexible. Further disclosed is a method for preparing the electrolyte. The method does not essentially require the use of a solvent. Therefore, the electrolyte can be prepared in a simple manner. The electrolyte is suitable for use in a cable-type battery whose shape is easy to change due to its high ionic conductivity and high mechanical strength in terms of flexibility.
1. A solid electrolyte for a flexible electrochemical device, consisting of a composite consisting of:
a plastic crystal matrix electrolyte doped with an ionic salt;
a semi-interpenetrating polymer network comprising a non-crosslinked polymer and a crosslinked polymer;
optionally residual solvent; and
optionally a photoinitiator;
wherein the semi-interpenetrating polymer network is formed in the plastic crystal matrix electrolyte,
wherein the non-crosslinked polymer is selected from: polyethylene oxide, polyvinylidene fluoride-co-hexafluoropropylene and polyacrylonitrile as linear polymers;
poly(methoxy polyethylene glycol methacrylate) and poly(2-methoxy ethyl glycidyl ether) as branched polymers; and mixtures thereof,
wherein the crosslinked polymer structure is obtained by polymerization of a monomer having two or more functional groups selected from trimethylolpropane ethoxylate triacrylate, polyethylene glycol dimethacrylate, trimethylolpropane trimethacrylate, ethoxylated bisphenol A dimethacrylate, and mixtures thereof, and
wherein said solid electrolyte is suitable for use in a flexible electrochemical device.
2. The solid electrolyte according to claim 1 , wherein the ionic salt-doped plastic crystal matrix electrolyte and the non-crosslinked polymer/crosslinked polymer network are present in a weight ratio of 30:70 to 90:10.
3. The solid electrolyte according to claim 1 , wherein the non-crosslinked polymer and the crosslinked polymer are present in a weight ratio of 10:90 to 70:30.
4. The solid electrolyte according to claim 1 , wherein the plastic crystal matrix electrolyte comprises succinonitrile.
5. The solid electrolyte according to claim 1 , wherein the ionic salt is a lithium salt.
6. The solid electrolyte according to claim 5 , wherein the lithium salt is selected from lithium bis-trifluoromethanesulfonylimide, lithium bis-perfluoroethylsulfonylimide, lithium tetrafluoroborate, and mixtures thereof.
7. A method for preparing the solid electrolyte according to claim 1 , the method comprising:
preparing a solution consisting of a plastic crystal matrix electrolyte doped with an ionic salt, a non-crosslinked polymer, a monomer having two or more functional groups, optionally solvent and optionally a photoinitiator; and
polymerizing the monomer having two or more functional groups in the solution;
wherein the non-crosslinked polymer is selected from: polyethylene oxide, polyvinylidene fluoride-co-hexafluoropropylene and polyacrylonitrile as linear polymers;
poly(methoxy polyethylene glycol methacrylate) and poly(2-methoxy ethyl glycidyl ether) as branched polymers; and mixtures thereof, and
wherein the monomer having two or more functional groups is selected from trimethylolpropane ethoxylate triacrylate, polyethylene glycol dimethacrylate, trimethylolpropane trimethacrylate, ethoxylated bisphenol A dimethacrylate, and mixtures thereof.
8. The method according to claim 7 , wherein the non-crosslinked polymer and the monomer having two or more functional groups are present in a weight ratio of 10:90 to 70:30.
9. The method according to claim 7 , wherein the plastic crystal matrix electrolyte comprises succinonitrile.
10. The method according to claim 7 , wherein the ionic salt is used in an amount of 0.1 to 3 moles per mole of the plastic crystal matrix electrolyte.
11. The method according to claim 7 , wherein the ionic salt is a lithium salt.
12. The method according to claim 11 , wherein the lithium salt is selected from lithium bis-trifluoromethanesulfonylimide, lithium bis-perfluoroethylsulfonylimide, lithium tetrafluoroborate, and mixtures thereof.
13. A flexible electrochemical device comprising a cathode, an anode and the solid electrolyte according to claim 1 .
14. The flexible electrochemical device according to claim 13 , wherein the electrochemical device is a lithium secondary battery.
15. The solid electrolyte according to claim 1 , wherein the composite is prepared by mixing the plastic crystal matrix electrolyte doped with an ionic salt, the non-crosslinked polymer and a monomer having two or more functional groups to prepare a solution; and polymerizing the monomer having two or more functional groups in the solution.
16. The flexible electrochemical device according to claim 14 , wherein the battery is a cable-type battery.