CLARIFICATION OF HYDROCARBONS AND SUSPENDED MATTER FROM AN AQUEOUS MEDIUM
A method for removing components from an aqueous medium is described. The method includes dispensing a formulation comprising one or more of zinc chloride, calcium chloride, zirconium acetate and zirconium oxychloride to an aqueous medium. The method includes allowing the formation of floccules in the aqueous medium, wherein the floccules contain the component to be removed. The method includes separating the floccules from the aqueous medium to remove the component.
1 . A method for removing components from an aqueous medium, comprising:
dispensing a formulation comprising one or more of zinc chloride, calcium chloride, zirconium acetate, zirconium oxychloride, or any combination thereof, to an aqueous medium;
allowing the formation of floccules in the aqueous medium, wherein the floccules contain a component to be removed; and
separating the floccules with the component from the aqueous medium.
2 . The method of claim 1 , wherein the aqueous medium is drill water and the formulation comprises zinc chloride.
3 . The method of claim 1 , wherein the aqueous medium is drill water and the formulation comprises zinc chloride and calcium chloride.
4 . The method of claim 1 , wherein the aqueous medium is drill water and the formulation comprises calcium chloride and zirconium acetate, wherein the amount of calcium chloride by weight is equal to or less than the zirconium acetate.
5 . The method of claim 1 , wherein the aqueous medium is drill water and the formulation comprises calcium chloride.
6 . The method of claim 1 , wherein the aqueous medium is drill water and the formulation comprises calcium chloride and zinc chloride.
7 . The method of claim 1 , further comprising dispensing zinc chloride or calcium chloride or both into the aqueous medium, allowing the floccules to form a first time, filtering the floccules from the aqueous medium to result in a filtrate, and dispensing zirconium oxychloride or zirconium acetate or both into the filtrate, and allowing floccules to form a second time in the filtrate.
8 . The method of claim 1 , further comprising dispensing zinc chloride or calcium chloride or both into the aqueous medium, allowing the floccules to form a first time in the aqueous medium, separating the floccules from the aqueous medium to result in a supernatant liquid, and dispensing zirconium oxychloride or zirconium acetate or both into the supernatant liquid, and allowing floccules to form a second time in the supernatant liquid.
9 . The method of claim 1 , wherein the aqueous medium is drill water, produced water, frac water, or flow back water.
10 . The method of claim 1 , wherein the aqueous medium is bilge water.
11 . The method of claim 1 , wherein the aqueous medium is wastewater from a sewage treatment plant.
12 . The method of claim 1 , wherein the aqueous medium is industrial wastewater.
13 . The method of claim 1 , wherein the aqueous medium is food processing wastewater.
14 . The method of claim 1 , wherein the aqueous medium is potable water.
15 . The method of claim 1 , wherein the aqueous medium is recreational water.
16 . The method of claim 1 , wherein the aqueous medium comprises mine tailings.
17 . The method of claim 1 , wherein the formulation further comprises water.
18 . The method of claim 1 , wherein the formulation is a solid.
19 . The method of claim 1 , wherein the formulation is an aqueous solution.
20 . The method of claim 1 , wherein the formulation is an aqueous slurry.
21 . The method of claim 1 , wherein the formulation further comprises a natural polymer or a derivative of a natural polymer.
22 . The method of claim 1 , wherein the formulation further comprises one or more of a polysaccharide, guar gum, xanthan gum, alginate, carboxymethylcellulose, chitosan, a cationic guar, a starch, a cationic starch, an anionic starch, carrageenans, pectin, arabic gum, karaya gum, tragacanth gum, glucomannan, or any combination thereof.
23 . The method of claim 1 , wherein the formulation further comprises magnesium chloride.
24 . The method of claim 1 , wherein the formulation comprises zinc chloride, calcium chloride, ferric chloride, and chitosan.
25 . The method of claim 1 , wherein the formulation comprises calcium chloride, magnesium chloride, and glucomannan.
26 . The method of claim 1 , wherein the formulation comprises zirconium acetate and chitosan.
27 . The method of claim 1 , wherein the formulation comprises zirconium acetate and a polysaccharide.