Production of synthesis gas by heating oxidized biomass with a hot gas obtained from oxidation of residual products
A process for producing synthesis gas, or syngas, from biomass. The process comprises contacting biomass with oxygen, or oxygen and steam, in an amount effective to oxidize the biomass and to heat the biomass to a temperature to no greater than 750° C. At least one combustible material also is contacted with oxygen and steam to heat the at least one combustible material to a temperature of at least 1,100° C., to provide a hot gas derived from the oxidized combustible material. The latter maybe residual products derived from the process itself as char, tar, or hydrocarbons. The oxidized biomass then is contacted with the hot flue gas to heat the biomass to a temperature of at least 900° C., thereby producing synthesis gas. The synthesis gas then is recovered. Such process provides a method of providing heat for producing synthesis gas without consuming a portion of the synthesis gas to provide such heat, thereby providing an increased yield of synthesis gas.
1. A process for producing synthesis gas from biomass, comprising:
(a) contacting said biomass with oxygen, in a first vessel containing a gasification zone, in an amount effective to oxidize said biomass and to heat said biomass to a temperature no greater than 750° C.;
(b) contacting at least one combustible material with oxygen, in a second vessel containing an oxidation zone, to oxidize said at least one combustible material and to heat said at least one combustible material to a temperature of at least 1,100° C., thereby providing a hot oxidized gas;
(c) passing said hot oxidized gas produced in step (b) from said second vessel to said first vessel, whereby said oxidized biomass produced in step (a) is contacted with said hot oxidized gas produced in step (b) to heat said biomass to a temperature of at least 900° C., thereby producing a raw synthesis gas, wherein said raw synthesis gas contains at least one combustible material;
(d) separating said at least one combustible material from said raw synthesis gas produced in step (c) to provide a treated synthesis gas;
(e) passing said separated at least one combustible material of step (d) to said second vessel; and
(f) recovering said treated synthesis gas provided in step (d).
2. The process of claim 1 wherein said biomass is a homogenous biomass-rich material.
3. The process of claim 1 wherein said biomass is a non-homogeneous biomass-rich material.
4. The process of claim 1 wherein said biomass is a heterogeneous biomass-rich material.
5. The process of claim 1 wherein said biomass is urban biomass.
6. The process of claim 1 wherein, in step (a), said biomass is heated to a temperature of from about 600° C. to about 750° C.
7. The process of claim 6 wherein, in step (a), said biomass is heated to a temperature of from about 700° C. to about 750° C.
8. The process of claim 1 wherein, in step (b), said at least one combustible material is heated to a temperature of from about 1,100° C. to about 1,850° C.
9. The process of claim 8 wherein, in step (b), said at least one combustible material is heated to a temperature of from about 1,500° C. to about 1,850° C.
10. The process of claim 1 wherein, in step (c), said oxidized biomass is heated to a temperature of from about 900° C. to about 1,200° C.
11. The process of claim 10 wherein, in step (c), said oxidized biomass is heated to a temperature of from about 1,000° C. to about 1,100° C.
12. The process of claim 1 wherein said at least one combustible material from each of step (b), (c), (d), and (e) is selected from the group consisting of methane, ethylene, propylene, propane, methanol, ethanol, methyl acetate, ethyl acetate, acetic acid, dimethyl ester, tar, char, and mixtures thereof.
13. The process of claim 12 wherein said at least one combustible material is methane.
14. The process of claim 12 wherein said at least one combustible material is char.
15. The process of claim 12 wherein said at least one combustible material includes methane and char.
16. A process for producing synthesis gas from biomass, comprising:
(a) contacting said biomass in a gasification zone with oxygen in an amount effective to oxidize said biomass and to heat said biomass to a temperature no greater than 750° C.;
(b) contacting at least one combustible material with oxygen in an oxidation zone to oxidize said at least one combustible material and to heat said at least one combustible material to a temperature of at least 1,100° C., thereby providing a hot oxidized gas, wherein said at least one combustible material comprises a gas selected from the group consisting of methane, ethylene, ethane, propylene, propane, methanol, ethanol, methyl acetate, ethyl acetate, acetic acid, and dimethyl ester;
(c) contacting said oxidized biomass produced in step (a) with said hot oxidized gas produced in step (b) to heat said biomass to a temperature of at least 900° C., thereby producing a raw synthesis gas, wherein said raw synthesis gas contains at least one combustible material, wherein said at least one combustible material comprises a gas selected from the group consisting of methane, ethylene, ethane, propylene, propane, methanol, ethanol, methyl acetate, ethyl acetate, acetic acid, and dimethyl ester;
(d) separating said at least one combustible material from said raw synthesis gas produced in step (c) to provide a treated synthesis gas;
(e) passing said separated at least one combustible material of step (d) to said oxidation zone of step (b); and
(f) recovering said treated synthesis gas provided in step (d).
17. The process of claim 16 wherein said biomass is a homogeneous biomass-rich material.
18. The process of claim 16 wherein said biomass is a non-homogeneous biomass-rich material.
19. The process of claim 16 wherein said biomass is a heterogeneous biomass-rich material.
20. The process of claim 16 wherein said biomass is urban biomass.
21. The process of claim 16 wherein, in step (a), said biomass is heated to a temperature of from about 600° C. to about 750° C.
22. The process of claim 21 wherein, in step (a), said biomass is heated to a temperature of from about 700° C. to about 750° C.
23. The process of claim 16 wherein, in step (b), said at least one combustible material is heated to a temperature of from about 1,100° C. to about 1,850° C.
24. The process of claim 21 wherein, in step (b), said at least one combustible material is heated to a temperature of from about 1,500° C. to about 1,850° C.
25. The process of claim 16 wherein, in step (c), said oxidized biomass is heated to a temperature of from about 900° C. to about 1,200° C.
26. The process of claim 25 wherein, in step (c), said oxidized biomass is heated to a temperature of from about 1,000° C. to about 1,100° C.
27. The process of claim 16 wherein said at least one combustible material is methane.