Comb polymers and the use thereof in washing and cleaning agents
The invention relates to a comb polymer made of a polymer main chain and polyester side chains linked to said polymer main chain via ester groups, characterized in that (i) the polymer main chain is a polycarbolic acid or a copolymer polycarbolic acid (A), (ii) the polyester side chains comprises the components (B1) C 8 -dicarbolic acids, optionally sulfonated, (B2) dioles and/or polyolethers having 2 OH groups, and (C) non-ionic terminal groups of the formula -0-(AO) x R, where A means ethylene, propylene, or butylene, x is a number from 1 to 100, and R is a hydrocarbon radical having 1 to 30 C atoms; (iii) the total percent by mass of the polyester side chains B1+B2+C is 80 to 99.9%, relative to the total mass of the comb polymer; (iv) the polyester side chains are obtained from an esterification reaction of the components B1, B2, and C at a mass ratio B1+B2/C of 2:1 to 100:1.
1. A comb polymer composed of a main polymer chain and of polyester side chains linked via ester groups to the main polymer chain, wherein
(i) the main polymer chain is a polycarboxylic acid or a copolymer polycarboxylic acid (A),
(ii) the polyester side chains comprise the constituents (B1) C 8 dicarboxylic acids, which are optionally sulfonated, (B2) diols and/or polyol ethers having 2 OH groups, and (C) nonionic end groups of the formula —O-(AO) x R, where A is ethylene, propylene or butylene, x is a number from 1 to 100, and R is a hydrocarbon radical having 1 to 30 carbon atoms;
(iii) the total mass percentage of the polyester side chains B1+B2+C is 80% to 99.9%, based on the total mass of the comb polymer; and
(iv) the polyester side chains are obtained by an esterification reaction of components B1, B2, and C in a B1+B2/C mass ratio of 2:1 to 100:1.
2. A comb polymer as claimed in claim 1 , wherein the polycarboxylic acid (A) is a poly(meth)acrylic acid.
3. A comb polymer as claimed in claim 1 , wherein component (B1) is selected from the group consisting of terephthalic acid, isophthalic acid, cyclohexanedicarboxylic acid, a sulfoisophthalic acid and combinations thereof.
4. A comb polymer as claimed in claim 1 , wherein component (B2) is selected from the group consisting of ethylene glycol, a propanediol, a butanediol, a polyethylene glycol, a polypropylene glycol and combinations thereof.
5. A comb polymer as claimed in claim 1 , wherein component (C) derives from a polyalkoxy compound of the formula HO-(AO) x R, where A is ethylene, propylene or butylene, x is a number from 2 to 100, and R is methyl, ethyl, propyl, butyl or tristyrylphenyl.
6. A comb polymer as claimed in claim 5 , wherein the polyalkoxy compound is selected from the group consisting of triethylene glycol monomethyl ether, triethylene glycol monobutyl ether, tetraethylene glycol monomethyl ether, pentaethylene glycol monomethyl ether, and tristyrylphenol polyethoxylate having 10 to 30 EO units.
7. A comb polymer as claimed in claim 1 , wherein the total mass percentage of the polyester side chains B1+B2+C is 90% to 99.8%, based on the total mass of the comb polymer.
8. A comb polymer as claimed in claim 1 , wherein the polyester side chains are obtained by an esterification reaction of components B1, B2 and C in a B1+B2/C mass ratio of 3:1 to 40:1.
9. A comb polymer as claimed in claim 1 , wherein the comb polymer has a melt viscosity of not more than 50 000 mPas at a temperature of 200° C.
10. A comb polymer as claimed in claim 1 , wherein the comb polymer has an average molar mass Mn of 800 to 25 000 g/mol.
11. A process for preparing a comb polymer as claimed in claim 1 , comprising the step of reacting components (A), (B1), (B2), and (C) with one another in the presence of an esterification catalyst.
12. A process for soil release, comprising the step of contacting a soiled article with a comb polymer as claimed in claim 1 .
13. A detergent composition comprising a comb polymer as claimed in claim 1 .
14. A detergent composition as claimed in claim 13 , containing between 0.1% and 10% by weight of comb polymer, based on the completed composition.