Apparatus and method for plasma treatment of containers

1. An apparatus for plasma treating multiple containers, the apparatus comprising:

a manifold comprising a first chamber and a second chamber; and

multiple hollow, electrically-conductive nozzles for at least one of delivering or exhausting plasma-generating gas,

wherein the manifold comprises a first plate having a first face, a second face, and a port extending therethrough, wherein the first chamber comprises:

a first plurality of interconnected grooves formed in the first face of the first plate, wherein interconnections of the first plurality of interconnected grooves are located in the first face of the first plate;

multiple outlet openings in the second face of the first plate; and

multiple passages through the first plate that extend from the first face of the first plate to the second face of the first plate such that the multiple passages connect the first plurality of interconnected grooves to the multiple outlet openings;

wherein the multiple hollow, electrically-conductive nozzles are connected to the multiple outlet openings and protrude from the second face of the first plate, and wherein the first plurality of interconnected grooves provides access to a supply of plasma-generating gas or a vacuum source and provides pathways for connecting the multiple hollow, electrically-conductive nozzles to the supply of plasma-generating gas or the vacuum source, and

wherein the manifold further comprises an insulating block having a first face and a second face, wherein the second chamber comprises:

a second plurality of interconnected grooves formed in the first face of the insulating block, the first face of the insulating block disposed adjacent the second face of the first plate, wherein interconnections of the second plurality of interconnected grooves are located in the first face of the insulating block,

multiple second outlet openings in the second face of the insulating block; and

multiple second passages through the insulating block that extend from the first face of the insulating block to the second face of the insulating block such that the multiple second passages connect the second plurality of interconnected grooves to the multiple second outlet openings, wherein the second plurality of interconnected grooves is in communication with the port in the first plate, wherein the multiple hollow, electrically-conductive nozzles protrude from the multiple second outlet openings in the second face of the insulating block, wherein if the first plurality of interconnected grooves provides access to the supply of plasma-generating gas and provides pathways for connecting the multiple hollow, electrically-conductive nozzles to the supply of plasma-generating gas, then the second plurality of interconnected grooves provides access to the vacuum source and provides pathways for connecting the multiple second passages to the vacuum source, and wherein if the first plurality of interconnected grooves provides access to the vacuum source and provides pathways for connecting the multiple hollow, electrically-conductive nozzles to the vacuum source, then the second plurality of interconnected grooves provides access to the supply of plasma-generating gas and provides pathways for connecting the multiple second passages to the supply of plasma-generating gas.

2. The apparatus according to claim 1 , wherein each of the hollow, electrically-conductive nozzles has an inner diameter in a range from 1.6 millimeters to 12.2 millimeters.

3. The apparatus according to claim 1 , wherein each of the hollow, electrically-conductive nozzles has a surface dielectric coating.

4. The apparatus according to claim 1 , wherein the first plurality of interconnected grooves are configured such that each pathway between one of the hollow, electrically-conductive nozzles and the supply of plasma-generating gas or the vacuum source is substantially the same in volume.

5. The apparatus according to claim 1 , wherein the first plurality of interconnected grooves are configured such that each pathway between one of the hollow, electrically-conductive nozzles and the supply of plasma-generating gas or the vacuum source is substantially the same in length.

6. The apparatus according to claim 1 , wherein the second plurality of interconnected grooves provides access to the vacuum source and provides pathways for connecting the multiple second passages to the vacuum source.

7. The apparatus according to claim 6 , further comprising a second plate comprising:

slots for multiple containers, the slots aligned with the discrete openings in the second face of the insulating block; and

a connection for a radio frequency power source.

8. The apparatus according to claim 7 , wherein the second plate further comprises a coolant entrance port and a coolant exit port with flow paths for coolant extending between the coolant entrance port and the coolant exit port.

9. The apparatus according to claim 1 , wherein the manifold further comprises a coolant entrance port and a coolant exit port with flow paths for coolant extending between the coolant entrance port and the coolant exit port.

10. The apparatus according to claim 1 , further comprising:

an evacuable chamber connected to the manifold, wherein the multiple hollow, electrically-conductive nozzles extend into the evacuable chamber; and

a conductive plate within the evacuable chamber in proximity to the multiple hollow, electrically-conductive nozzles, wherein the conductive plate comprises a connection for a radio frequency power source.

11. A method of plasma treating multiple electrically-conductive containers, the method comprising:

providing a reactor system comprising an apparatus according to claim 1 ;

inserting the multiple hollow, electrically-conductive nozzles into the multiple electrically-conductive containers;

grounding the multiple hollow, electrically-conductive nozzles while applying radio frequency power to the multiple electrically-conductive containers;

evacuating the multiple electrically-conductive containers;

providing a gas inside the multiple electrically-conductive containers; and

generating a plasma to treat an interior surface of the multiple electrically-conductive containers;

wherein at least one of evacuating or providing the gas is carried out through the hollow, electrically-conductive nozzles.

12. The method according to claim 11 , wherein the hollow, electrically-conductive nozzles are centrally disposed in the electrically-conductive containers.

13. The method according to claim 11 , wherein there is a pressure difference among the multiple electrically-conductive containers of up to ten percent.

14. The method according to claim 11 , wherein each of the electrically-conductive containers has a distance between a brim and a bottom, and wherein the hollow, electrically-conductive nozzles penetrate into the electrically-conductive containers in a range from 30 percent to 99 percent of the distance.

15. The method according to claim 11 , wherein exhaust gas from each of the electrically-conductive containers is vented through pathways having substantially the same volume.

16. The method according to claim 11 , further comprising controlling the temperature of at least one of the multiple hollow, electrically-conductive nozzles or the multiple electrically-conductive containers while generating the plasma.

17. The method according to claim 11 , further comprising depositing diamond like glass on the interior surface of the electrically-conductive containers.

18. The method of claim 11 , wherein at least 8 and up to 2500 of the multiple electrically-conductive containers are arranged in rows in a two-dimensional array.

19. The apparatus according to claim 6 , wherein the second plurality of interconnected grooves is configured such that each of the second plurality of interconnected pathways between one of the discrete openings and the port in the first plate has substantially the same volume.