Doped aluminum oxides
View Patent ↗A process of preparing a doped aluminum oxide, includes providing a solution comprising 8-hydroxyquinoline; an aluminum precursor; a dopant precursor, and a reaction solvent; isolating a precipitate from the solution; and calcining the precipitate to form the doped aluminum oxide. Compositions may be prepared which include tris(8-hydroxyquinolinato) aluminum and (8-hydroxyquinolinato) z M, wherein M is a metal ion and the value of z is equivalent to the oxidation state of the metal ion.
1. A process of preparing a doped aluminate, the process comprising:
providing a solution comprising 8-hydroxyquinoline; an aluminum precursor; a dopant precursor, and a reaction solvent;
isolating a precipitate from the solution; and
calcining the precipitate to form the doped aluminate.
2. The process of claim 1 , wherein the dopant precursor is a metal salt or metal alkoxide.
3. The process of claim 1 , wherein the dopant precursor is a metal salt or metal alkoxide of chromium, manganese, iron cobalt, nickel, lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, lutetium, yttrium, calcium, magnesium, barium, or strontium.
4. The process of claim 1 , wherein the aluminum precursor is an aluminum salt, an aluminum alkoxide, or a mixture of any two or more thereof.
5. The process of claim 1 , wherein the aluminum precursor is aluminum chloride, aluminum bromide, aluminum methoxide, aluminum ethoxide, aluminum acetate, aluminum isopropoxide, aluminum nitrate, or a mixture of any two or more thereof.
6. The process of claim 1 , wherein the aluminum precursor is a compound of formula Al(OR) 3 , where R is a C 1 -C 10 alkyl, or an aryl group.
7. The process of claim 6 , wherein R is methyl, ethyl, n-propyl, or isopropyl.
8. The process of claim 1 , wherein the reaction solvent is an alcohol, an ether, a glycol ether, a ketone, an amide, a nitrile, a halogenated hydrocarbon, or a mixture of any two or more thereof.
9. The process of claim 1 , further comprising heating the solution at a temperature, and for a time period, sufficient to produce the precipitate, prior to the isolating step.
10. The process of claim 9 , wherein the temperature is the refluxing temperature of the reaction solvent.
11. The process of claim 9 , wherein the time period is about 10 minutes to about 10 hours.
12. The process of claim 1 , further comprising washing the precipitate with a wash solvent before the calcining step and after the isolating step.
13. The process of claim 12 , wherein the wash solvent is an alcohol or an ether.
14. The process of claim 1 , wherein the doped aluminate is LaAlO 3 (perovskite), Y 3 Al 5 O 12 (yttrium aluminum garnet), Cr:Al 2 O 3 , CoAl 2 O 4 , or SrAl 2 O 4 .
15. The process of claim 1 further comprising combining the precipitate with a polymer after the isolating step and before the calcining step to form a polymer composite.
16. The process of claim 15 , wherein the polymer is polyvinylpyrrolidone or polyvinyl alcohol.
17. The process of claim 15 further comprising preparing a nanofiber of the polymer composite before the calcining step.
18. The process of claim 15 , further comprising preparing a nanofiber of the polymer composite before the calcining step by electrospinning the polymer composite into nanofibers.