IP Library Granted Patent US 9,512,387
Granted Patent B2
US 9,512,387 · App. 13/323,160 · Granted Dec 6, 2016

Cleaning compositions for removing polymeric contaminants from papermaking surfaces

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Quick Facts
Patent No.
US 9,512,387
App. No.
13/323,160
Granted
Dec 6, 2016
Kind
B2
Abstract

Embodiments of cleaning compositions for removing polymeric soils comprise at least one surfactant, at least one amine, and a solvent blend comprising at least one aromatic alcohol, at least one dibasic ester, and at least one terpene solvent.

Claims (40)

1. A cleaning composition for removing polymeric soils comprising:

at least one surfactant;

at least one amine; and

a solvent blend comprising at least one aromatic alcohol, at least one dibasic ester, and at least one terpene solvent.

2. The composition of claim 1 wherein the amine comprises monoisopropanolamine.

3. The composition of claim 1 wherein the cleaning composition comprises from about 0.01 to about 5 weight % of the amine.

4. The composition of claim 1 wherein the cleaning composition comprises from about 1.5 to about 2.5 weight % of the amine.

5. The composition of claim 1 wherein the surfactant is a nonionic surfactant.

6. The composition of claim 1 wherein the at least one surfactant is selected from the group consisting of dodecylbenzene sulfonate, sodium-1-octane sulfonate, sodium caprylyl sulfonate, alcohol ethoxylates, and mixtures thereof.

7. The composition of claim 1 wherein the cleaning composition comprises from about 1 to about 20 weight % of the surfactant.

8. The composition of claim 1 wherein the cleaning composition comprises from about 6 to about 18 weight % of the surfactant.

9. The composition of claim 1 wherein the solvent blend comprises a weight ratio of aromatic alcohol:dibasic ester:terpene solvent, wherein the ratio is 2:2:1.

10. The composition of claim 1 wherein the solvent blend comprises a weight ratio of aromatic alcohol:dibasic ester of from about 0.7:1 to about 1:0.7.

11. The composition of claim 1 wherein the solvent blend comprises a weight ratio of aromatic alcohol:terpene solvent of from about 1.5:1 to about 2.5:1.

12. The composition of claim 1 wherein the solvent blend comprises a weight ratio of dibasic ester:terpene solvent of from about 1.5:1 to about 2.5:1.

13. The composition of claim 1 wherein the cleaning composition comprises about 10 to about 40 weight percent of the solvent blend.

14. The composition of claim 1 wherein the solvent blend comprises about 35 to about 45% by weight dibasic ester, about 35 to about 45% by weight aromatic alcohol, and about 15 to about 25% by weight terpene solvent.

15. The composition of claim 1 wherein the terpene solvent is d-limonene.

16. The composition of claim 1 wherein the dibasic ester is selected from the group consisting of dialkyl adipate, dialkyl methylglutarate and dialkyl ethylsuccinate, wherein the alkyl groups individually comprise a C 1 -C 12 hydrocarbon group.

17. The composition of claim 1 wherein the dibasic ester is dimethyl-2 methyl glutarate.

18. The composition of claim 1 wherein the aromatic alcohol is an alkyl aromatic alcohol.

19. The composition of claim 1 wherein the aromatic alcohol is benzyl alcohol.

20. A combination cleanser comprising:

the cleaning composition of claim 1 ; and

a second alkaline cleanser.

21. The combination cleanser of claim 20 wherein the combination cleanser comprises a pH of about 10 to about 13.8.

22. A combination cleanser according to claim 20 further comprising one or more components selected from the group consisting of potassium hydroxide, sodium hydroxide, sodium hypochlorite, peroxides, triethanolamine, ethylenediaminetetraacetic acid, nitrilotriacetic acid, sodium silicate, tetrasodium pyrophosphate, sodium tripolyphosphate, 1-(2,5-dimethoxy-4-methylphenyl)propan-2-amine, and combinations thereof.

23. A combination cleanser according to claim 20 further comprising builders, surfactants and/or other formulation components.

24. A cleaning composition for removing polymeric soils comprising:

at least one surfactant;

at least one amine; and

a solvent blend having a Hansen Solubility Factor for polymeric soils of below 4.

25. The cleaning composition of claim 24 wherein the solvent blend comprises an aromatic alcohol.

26. The cleaning composition of claim 24 wherein the solvent blend comprises dibasic ester.

27. The cleaning composition of claim 24 wherein the solvent blend comprises terpene solvent.

28. A combination cleanser comprising:

the cleaning composition of claim 24 ; and

a second alkaline cleanser.

29. The cleaning composition of claim 1 wherein the solvent blend has a Hansen Solubility Factor for polymeric soils of below 4.

30. The cleaning composition of claim 24 wherein the solvent blend comprises about 35 to about 45% by weight dibasic ester, about 35 to about 45% by weight aromatic alcohol, and about 15 to about 25% by weight terpene solvent.

Assignments (15)
PATENT SECURITY AGREEMENT Recorded Jun 18, 2024
From: DUBOIS CHEMICALS, INC.
To: ANTARES CAPITAL LP, AS COLLATERAL AGENT
Reel/Frame 067774/0852 →
SECURITY INTEREST Recorded Jul 22, 2022
From: DUBOIS CHEMICALS, INC.
To: ANTARES CAPITAL LP, AS COLLATERAL AGENT
Reel/Frame 060588/0838 →
RELEASE OF SECURITY INTEREST Recorded Apr 4, 2021
From: WILMINGTON TRUST, NATIONAL ASSOCIATION
To: DUBOIS CHEMICALS, INC.
Reel/Frame 055814/0512 →
SECURITY INTEREST Recorded Jun 30, 2020
From: DUBOIS CHEMICALS, INC., AS GRANTOR
To: WILMINGTON TRUST, NATIONAL ASSOCIATION, AS COLLATERAL AGENT
Reel/Frame 053085/0382 →
CORRECTIVE ASSIGNMENT TO CORRECT THE TITLE TO READ RELEASE OF SECURITY INTEREST RECORDED AT REEL/FRAME 042038/0101 PREVIOUSLY RECORDED ON REEL 050598 FRAME 0028. ASSIGNOR(S) HEREBY CONFIRMS THE RELEASE OF SECURITY INTEREST. Recorded Oct 10, 2019
From: ANTARES CAPITAL LP
To: DUBOIS CHEMICALS, INC.
Reel/Frame 052091/0032 →
RELEASE OF SECURITY INTEREST RECORDED AT REEL/FRAME 04238/0101 Recorded Oct 1, 2019
From: ANTARES CAPITAL LP
To: DUBOIS CHEMICALS, INC.
Reel/Frame 050598/0028 →
SECURITY INTEREST Recorded Oct 1, 2019
From: DUBOIS CHEMICALS, INC.
To: JPMORGAN CHASE BANK, N.A., AS COLLATERAL AGENT
Reel/Frame 050573/0202 →
SECURITY INTEREST Recorded Oct 1, 2019
From: DUBOIS CHEMICALS, INC.
To: ANTARES CAPITAL LP, AS COLLATERAL AGENT
Reel/Frame 050573/0867 →
RELEASE OF SECURITY INTEREST RECORDED AT REEL/FRAME 042038/0153 Recorded Oct 1, 2019
From: ANTARES CAPITAL LP
To: DUBOIS CHEMICALS, INC.
Reel/Frame 050597/0851 →
FIRST LIEN INTELLECTUAL PROPERTY SECURITY AGREEMENT Recorded Mar 17, 2017
From: DUBOIS CHEMICALS, INC.
To: ANTARES CAPITAL LP
Reel/Frame 042038/0101 →
SECOND LIEN INTELLECTUAL PROPERTY SECURITY AGREEMENT Recorded Mar 17, 2017
From: DUBOIS CHEMICALS, INC.
To: ANTARES CAPITAL LP
Reel/Frame 042038/0153 →
RELEASE OF SECURITY INTEREST IN INTELLECTUAL PROPERTY COLLATERAL RECORDED AT REEL 029549/FRAME 0142 Recorded Mar 15, 2017
From: ANTARES CAPITAL LP, SUCCESSOR AGENT TO GENERAL ELECTRIC CAPITAL CORPORATION
To: DUBOIS CHEMICALS, INC.
Reel/Frame 042020/0826 →
ASSIGNMENT OF INTELLECTUAL PROPERTY SECURITY AGREEMENTS Recorded Oct 9, 2015
From: GENERAL ELECTRIC CAPITAL CORPORATION, AS RETIRING AGENT
To: ANTARES CAPITAL LP, AS SUCCESSOR AGENT
Reel/Frame 036826/0621 →
SECURITY AGREEMENT Recorded Dec 28, 2012
From: DUBOIS CHEMICALS, INC.
To: GENERAL ELECTRIC CAPITAL CORPORATION, AS AGENT
Reel/Frame 029549/0142 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 12, 2011
From: LASER, HAROLD; MAHLER, BRANDON E.; EBBELER, ROBERT E.
To: DUBOIS CHEMICALS, INC.
Reel/Frame 027363/0569 →