Enhanced high Q material compositions and methods of preparing same
View Patent ↗A framework for developing high quality factor (Q) material for electronic applications in the radio frequency range is provided. In one implementation, ceramic materials having a tungsten bronze crystal structure is modified by substituting one or more elements at one or more lattice sites on the crystal structure. The substitute elements are selected based on the ionic radius and other factors. In other implementations, the modified ceramic material is prepared in combination with compositions such as rutile or a perovskite to form a orthorhombic hybrid of perovskite and tetragonal tungsten bronze.
1. A ceramic material comprising a tungsten bronze crystal structure modified by substituting one or more lattice sites with one or more elements selected to increase the quality factor (Q) of the material, the ceramic material thereby having a dielectric constant of between 60-100 and a Q greater than 6000 at 1 GHz, the ceramic material further comprising at least one additional phase comprising a perovskite, said perovskite being represented by the general formula Nd 1−1/3x M III 1−x Ti x O 3 , M III being selected from the group consisting of aluminum, gallium, and combinations thereof.
2. The ceramic material of claim 1 wherein the tungsten bronze crystal structure is an orthorhomobic tungsten bronze crystal structure.
3. The ceramic material of claim 1 having a composition represented by the formula Ba 4 M III 2−3x Ln 8+3x Ti 18−3x M III 3x O 54 , x being less than or equal to ⅔; M II being selected from the group consisting of Ca, Sr, and combinations thereof; and Ln being selected from the group consisting of Y, La, Pr, Nd, Sm, Gd, Dy, Ho, Tm, Er, Yb, Lu, and combinations thereof.
4. The ceramic material of claim 1 having a composition represented by the formula Ba 4 (M I 0.5 Ln 0.5 ) 2−3x Ln 8+3x Ti 18−3x M III 3x O 54 , where x being less than or equal to ⅔; M I being selected from the group consisting of Na, K, Cu and combinations thereof; M III being on a C site of the crystal structure; and Ln being on a B site of the crystal structure and being selected from the group consisting of Y, La, Pr, Nd, Sm, Gd, Dy, Ho, Tm, Er, Yb, Lu, and combinations thereof.
5. The ceramic material of claim 1 having a composition represented by the formula Ba 4 (M I 0.5 Ln 0.5 ) 2-3x Ln 8+3x Ti 18−3x M III 3x O 54 , where x being less than or equal to ⅔; M I being selected from the group consisting of Na, K, Cu, and combinations thereof; and Ln being selected from the group consisting of Y, La, Pr, Nd, Sm, Gd, Dy, Ho, Tm, Er, Yb, Lu, and combinations thereof.
6. The ceramic material of claim 1 having a composition represented by the formula Ba 4 M II 2−3x Ln 8+2x+y Ti 18−3x M III 3x O 54 , x being less than or equal to ⅔; y being less than or equal to ⅔; M II being on an A site of the crystal structure and being selected from the group consisting of Ca, Sr, and combinations thereof; M III being on a C site of the crystal structure; and Ln being on an B site of the crystal structure and being selected from the group consisting of Y, La, Pr, Nd, Sm, Gd, Dy, Ho, Tm, Er, Yb, Lu, and combinations thereof.
7. The ceramic material of claim 1 having a composition represented by the formula Ba 4 Ln 8 [Ba 2−3x Ln 2x V x ]Ti 18 O 54 , where x being less than or equal to ⅔; and Ln being selected from the group consisting of Y, La, Pr, Nd, Sm, Gd, Dy, Ho, Tm, Er, Yb, Lu, and combinations thereof.
8. The ceramic material of claim 1 having a composition represented by the formula Ba 4 (M I 0.5+a Ln 5−a ) 2−3x Ln 8+2x+y Ti 18−3y+a M III 3y−a O 54 , x being less than or equal to ⅔ and greater than or equal to 0; y being less than or equal to ⅔ and greater than or equal to 0; a being less than or equal to 0.5 and greater than or equal to −0.5; M I being selected from the group consisting of Na, K, Cu and combinations thereof; and Ln being selected from the group consisting of Y, La, Pr, Nd, Sm, Gd, Dy, Ho, Tm, Er, Yb, Lu, and combinations thereof.
9. The ceramic material of claim 1 having a composition represented by the formula Ba 4 Ln 8 Ln′ 4/3 Ti 18 O 54 , Ln being selected from the group consisting of La, Pr, Nd, Sm, Gd, and combinations thereof; and Ln′ being selected from the group consisting of La, Pr, Nd, Sm, Gd, ho, Y, Er, Yb, In, and combinations thereof.
10. The ceramic material of claim 1 having a composition represented by the formula
Ba 4 Nd 6.16 Sm 3.4 Ti 17.32 Al 0.68 O 54 .
11. The ceramic material of claim 1 having a composition represented by the formula
Ba 4 Nd 8.8 Y 0.8 Ti 17.2 Al 0.8 O 54 .
12. An electronic device comprising:
a ceramic material comprising a tungsten bronze crystal structure modified by substituting one or more lattice sites with one or more elements selected to increase the quality factor (Q) of the material, the ceramic material thereby having a dielectric constant of between 60-100 and a Q greater than 6000 at 1 GHz, the ceramic material further comprising at least one additional phase comprising a perovskite, said perovskite being represented by the general formula Nd 1−1/3x M III 1−x Ti x O 3 , M III being selected from the group consisting of aluminum, gallium, and combinations thereof; and said electronic device adapted to operate in the RF range.
13. A ceramic material comprising an orthorhombic hybrid of perovskite and tetragonal tungsten bronze having a formula represented by
Ba 4 Ln 8 [Ba 2−3x Ln 2x V x ]Ti 18 O 54 , where x is less than or equal to ⅔.
14. The electronic device of claim 12 wherein the ceramic material has a composition represented by the formula Ba 4 M II 2−3x Ln 8+3x Ti 18−3x M III 3x O 54 , x being less than or equal to ⅔; M II being selected from the group consisting of Ca, Sr, and combinations thereof; and Ln being selected from the group consisting of Y, La, Pr, Nd, Sm, Gd, Dy, Ho, Tm, Er, Yb, Lu, and combinations thereof.
15. The electronic device of claim 12 wherein the ceramic material has a composition represented by the formula
Ba 4 Nd 6.16 Sm 3.4 Ti 17.32 Al 0.68 O 54 or Ba 4 Nd 8.8 Y 0.8 Ti 17.2 Al 0.8 O 54 .
16. The electronic device of claim 12 wherein the electronic device comprises a ceramic antenna, a resonator, a cellular phone, a biomedical device, an RFID sensor, or a noise filtration system.
17. The electronic device of claim 16 wherein the ceramic antenna is a helical antenna.
18. The electronic device of claim 16 wherein the noise filtration system is a TE or TM mode filter, or combinations thereof.
19. A ceramic material comprising a tungsten bronze crystal structure modified by substituting one or more lattice sites with one or more elements selected to increase the quality factor (Q) of the material, the ceramic material thereby having a dielectric constant of between 60-100 and a Q greater than 6000 at 1 GHz, the ceramic material being represented by the formula Ba 4 Nd 6.16 Sm 3.4 Ti 17.32 Al 0.68 O 54 or Ba 4 Nd 8.8 Y 0.8 Ti 17.2 Al 0.8 O 54 .
20. An electronic device formed from the ceramic material of claim 19 , said electronic device adapted to operate in the RF range.