Polymer composition having heat-absorbing properties and high stability to weathering
View Patent ↗The present invention relates to a polymer composition including a transparent thermoplastic plastic, an inorganic infrared absorber, also referred to as IR absorber hereinbelow, optionally an inorganic nano-scale pigment, and the combination of at least one organic coloring agent of a specific structure, and to the preparation and use of the polymer compositions according to the invention and to products produced therefrom.
1. A polymer composition comprising
a. at least one transparent polycarbonate or copolycarbonate;
b. at least one inorganic IR absorber selected from the group consisting of boride compounds, tungstates, and mixtures thereof,
c. optionally an inorganic, nano-scale pigment,
d. a colouring agent or a colouring agent combination having structures selected from:
III. (1a) and/or (1b), (7)
IV. (1a) and/or (1b), (4), (7)
V. (1a) and/or (1b), (5), (7)
X. (3), (4)
XL (3), (5)
XIV. (3), (4), (7)
XV. (3), (5), (7)
XX. (1a) and/or (1b), (8b)
XXI. (7), (4)
XXII. (7), (5),
wherein the structures are as follows:
wherein
Ra and Rb, independently of one another, represent a linear or branched alkyl radical, or halogen;
n, independently of the respective R, represents a natural number from 0 to 3, the radical for n=0 being H;
wherein
R represents H or a p-methylphenylamine radical;
wherein
R3 represents a halogen;
n=4;
wherein
R1 and R2, independently of one another, represent a linear or branched alkyl radical, or halogen;
n represents a natural number from 0 to 4;
8b:
wherein
the radicals R(5-20), independently of one another, represents hydrogen, methyl, ethyl, propyl, isopropyl, butyl, isobutyl, tert-butyl, pentyl, neopentyl, hexyl, thexyl, fluorine, chlorine, bromine, sulfone or CN, and
M represents aluminium, nickel, cobalt, iron, zinc, copper or manganese
wherein the colouring agent of structure (7) has a bulk volume of from 2 to 10 l/kg, a specific surface area of from 5 to 60 m2/g, and a pH value of from 4 to 9, and
wherein the nano-scale pigment is carbon black and the IR absorber is lanthanum hexaboride.
2. The composition according to claim 1 , wherein the composition comprises the colouring agents of structures (1a) and (1b) in a 1:1 isomer mixture.
3. The composition according to claim 1 , wherein the composition comprises the colouring agents of structures (1a) and (1b) in each case only in the form of a pure isomer.
4. The composition according to claim 1 , wherein the composition comprises at least one colouring agent of structures (1a), (1b) or (7).
5. The composition according to claim 1 , wherein the colouring agents of component d) and the colouring agents of component e) are present in a ratio of from 1:3 to 3:1.
6. The composition according to claim 1 , wherein the thermoplastic plastic is a polycarbonate.
7. The composition according to claim 6 , wherein the IR absorber is present in an amount of from 0.0015 wt. % to 0.015 wt. %, calculated as solids content of metal boride in the polymer composition as a whole, and the carbon black is present in an amount of from 0 wt. % to 0.00135 wt. %, based on the polymer composition as a whole.
8. The composition according to claim 1 , wherein the colouring agents of component d) can be used in amounts of from 0.00001 wt. % to 0.3 wt. %, based on the individual component in question.
9. The composition according to claim 1 , wherein the composition further comprises additives selected from the group of the UV absorbers, demoulding agents, heat stabilisers and processing stabilisers.