Production of polycrystalline silicon in substantially closed-loop systems that involve disproportionation operations
View Patent ↗Production of polycrystalline silicon in substantially closed-loop processes and systems is disclosed. The processes and systems generally involve disproportionation of trichlorosilane to produce silane or dichlorosilane and thermal decomposition of silane or dichlorosilane to produce polycrystalline silicon.
1. A system for producing polycrystalline silicon, the system being substantially closed-loop with respect to hydrogen and chlorine-containing compounds, the system comprising:
a chlorination reactor in which hydrogen chloride is contacted with silicon to produce trichlorosilane and silicon tetrachloride;
a disproportionation system in which trichlorosilane is converted to silane or dichlorosilane;
a fluidized bed reactor in which silane or dichlorosilane is decomposed to produce polycrystalline silicon; and
a hydrogenation reactor in which silicon tetrachloride and hydrogen are introduced to produce trichlorosilane.
2. The system as set forth in claim 1 wherein the disproportionation system comprises a system in which trichlorosilane is converted to silane and wherein the fluidized bed reactor comprises a reactor in which silane is decomposed to produce polycrystalline silicon.
3. The system as set forth in claim 2 further comprising:
a conveying apparatus for conveying trichlorosilane from the hydrogenation reactor to the disproportionation system;
a conveying apparatus for conveying silane from the disproportionation system to the fluidized bed reactor;
a conveying apparatus for conveying trichlorosilane from the chlorination reactor to the disproportionation system; and
a conveying apparatus for conveying silicon tetrachloride from the disproportionation system to the hydrogenation reactor.
4. The system as set forth in claim 1 further comprising a separation system to which hydrogen, hydrogen chloride, silicon tetrachloride and trichlorosilane are introduced to separate hydrogen, hydrogen chloride and the chlorosilanes.
5. The system as set forth in claim 4 further comprising:
a conveying apparatus for conveying trichlorosilane and silicon tetrachloride from the separation system to the disproportionation system;
a conveying apparatus for conveying hydrogen chloride from the separation system to the chlorination reactor;
a conveying apparatus for conveying hydrogen from the separation system to the hydrogenation reactor;
a conveying apparatus for conveying hydrogenated gas from the hydrogenation reactor to the separation system; and
a conveying apparatus for conveying chlorinated gas from the chlorination reactor to the separation system.
6. The system as set forth in claim 2 wherein the disproportionation system comprises:
a first distillation column for separating silicon tetrachloride into a bottoms fraction and to separate dichlorosilane and trichlorosilane into an overhead fraction;
a second distillation column for separating trichlorosilane into a bottoms fraction and dichlorosilane into an overhead fraction;
a first disproportionation reactor for producing a first disproportionation reactor product gas comprising dichlorosilane and silicon tetrachloride; and
a second disproportionation reactor for producing a second disproportionation reactor product gas comprising silane and trichlorosilane; and
a third distillation column for separating silane into an overhead fraction and trichlorosilane into a bottoms fraction.
7. The system as set forth in claim 4 wherein the separation system comprises:
a chlorosilane separator for separating trichlorosilane and silicon tetrachloride from hydrogen and hydrogen chloride; and
a hydrogen separator for separating hydrogen from hydrogen chloride.
8. The system as set forth in claim 7 wherein the chlorosilane separator is a vapor-liquid separator.
9. The system as set forth in claim 7 wherein the hydrogen separator is a vapor-liquid separator.
10. The system as set forth in claim 7 wherein the hydrogen separator is a bubbler.
11. The system as set forth in claim 1 further comprising a stripper column to remove light end impurities prior to introduction of silicon tetrachloride and trichlorosilane into the disproportionation system.