Ultraviolet light emitting devices having compressively strained light emitting layer for enhanced light extraction
View Patent ↗Light emitting devices having an enhanced degree of polarization, P D , and methods for fabricating such devices are described. A light emitting device may include a light emitting region that is configured to emit light having a central wavelength, λ, and a degree of polarization, P D , where P D >0.006λ−b for 200 nm≦λ≦400 nm, wherein b≦1.5.
1. A light emitting device, comprising:
a bulk crystalline AlN substrate; and
a light emitting region, disposed above the bulk crystalline AlN substrate and comprising:
at least one compressively strained Al x Ga 1-x N layer; and
two Al y Ga 1-y N layers, the at least one compressively strained Al x Ga 1-x N layer disposed between the two Al y Ga 1-y N layers, wherein the compressively strained Al x Ga 1-x N layer is configured to emit light having a central wavelength, λ, and a degree of polarization, P D , wherein P D is greater than 0 and 231 nm<λ<250 nm, and the compressively strained Al x Ga 1-x N layer has a strain, ε α , wherein y≧0.9 and ε α <−0.0065.
2. A light emitting device, comprising:
a bulk crystalline AlN substrate; and
a light emitting region, disposed above the bulk crystalline AlN substrate and comprising:
at least one compressively strained Al x Ga 1-x N layer; and
two Al y Ga 1-y N layers, the at least one compressively strained Al x Ga 1-x N layer disposed between the two Al y Ga 1-y N layers, wherein the at least one compressively strained Al x Ga 1-x N layer is configured to emit light having a central wavelength, λ, and a degree of polarization, P D , wherein P D is greater than 0 and 231 nm<λ<250 nm, and the Al x Ga 1-x N layer has a strain, ε α , wherein
y>0.9, and ε α <−0.0065, if 250 nm>λ>240 nm; or
y>0.95, and ε α <−0.0075, if 240 nm>λ>231 nm.
3. A nitride-semiconductor light emitting device comprising:
a bulk crystalline AlN substrate;
a light emitting region disposed over the bulk crystalline AlN substrate and comprising:
at least one III-nitride quantum well layer; and
III-nitride barrier layers comprising Al y Ga 1-y N, where y≧0.9, the at least one III-nitride quantum well layer disposed between the III-nitride barrier layers, the at least one III-nitride quantum well layer being compressively strained and configured to emit light having a central wavelength, λ, and a degree of polarization, P D , where P D >0.006λ−b and 231 nm≦λ≦250 nm, wherein b≦1.5;
a base layer proximate the bulk crystalline AlN substrate;
a contact layer; and
a transition region between the base layer and the contact layer, the transition having an aluminum content.
4. The device of claim 3 , wherein b is about 1.
5. The device of claim 3 , wherein the light emitting region comprises at least one of GaN, InAlN, AlGaN, InGaN and InAlGaN.
6. The device of claim 3 , wherein:
the bulk crystalline AlN substrate has a lattice constant, a bulk-AlN ;
the at least one III-nitride quantum well layer comprises at least one Al x Ga 1-x N layer; and
the at least one Al x Ga 1-x N layer has an in-plane lattice constant a strained and a strained −a bulk-Aln ≦(λ (nm)−230)*0.0012 Å.
7. The device of claim 3 , wherein the at least one III-nitride quantum well layer comprises at least one Al x Ga 1-x N layer and wherein strain ε a in the Al x Ga 1-x N layer satisfies the inequality ε a <−0.0079+0.00022*(λ (nm)−240 nm).
8. The device of claim 3 , wherein the transition region comprises at least one of:
an AlGaN/AlGaN superlattice; and
an AlGaN layer having a first surface near the bulk crystalline AlN substrate and a second surface near the light emitting region, the AlGaN layer graded in Al content between the first surface and the second surface.
9. The device of claim 3 , wherein the base layer comprises Al zbase Ga 1-zbase N, where zbase is between 0 and 1.
10. A nitride-semiconductor light emitting device comprising:
a bulk crystalline AlN substrate;
a light emitting region disposed over the bulk crystalline AlN substrate and comprising:
at least one III-nitride quantum well layer; and
III-nitride barrier layers comprising Al y Ga 1-y N, where y≧0.9, the at least one III-nitride quantum well layer disposed between the III-nitride barrier layers, the at least one III-nitride quantum well layer being compressively strained and configured to emit light having a central wavelength, λ, and a degree of polarization, P D , where P D >0.006λ−b and 231 nm≦λ≦250 nm, wherein b≦1.5;
a base layer proximate the bulk crystalline AlN substrate;
a contact layer; and
a transition region between the base layer and the contact layer, the transition having an aluminum content that varies between the base layer and the contact layer.
11. The device of claim 10 , wherein b is about 1.
12. The device of claim 10 , wherein the at least one III-nitride quantum well layer comprises at least one of GaN, InAlN, AlGaN, InGaN and InAlGaN.
13. The device of claim 10 , wherein:
the bulk crystalline AlN substrate has a lattice constant, a bulk-AlN ;
the at least one III-nitride quantum well layer comprises at least one Al x Ga 1-x N layer; and
the at least one Al x Ga 1-x N layer has an in-plane lattice constant a strained and a strained −a bulk-Aln ≦(λ (nm)−230)*0.0012 Å.
14. The device of claim 10 , wherein the at least one quantum well layer comprises at least one Al x Ga 1-x N layer and wherein strain ε a in the Al x Ga 1-x N layer satisfies the inequality ε a <−0.0079+0.00022*(λ (nm)−240 nm).
15. The device of claim 10 , wherein the transition region comprises at least one of:
an AlGaN/AlGaN superlattice; and
an AlGaN layer having a first surface near the bulk crystalline AlN substrate and a second surface near the light emitting region, the AlGaN layer graded in Al content between the first surface and the second surface.
16. The device of claim 10 , wherein the base layer comprises Al zbase Ga 1-zbase N, where zbase is between 0 and 1.
17. A method of forming a light emitting device, comprising:
growing a light emitting region over a bulk crystalline AlN substrate wherein growing the light emitting region comprises growing at least one compressively-strained Al x Ga 1-x N quantum well layer between two Al y Ga 1-y N layers, the at least one compressively strained Al x Ga 1-x N quantum well layer having compressive strain ε α , and configured to emit light having a central wavelength, λ, where 231 nm<λ<250 nm, and with a degree of polarization, P D greater than 0, wherein:
y>0.9, and ε α <−0.0065, if 250 nm>λ>240 nm; or
y>0.95, and ε α <−0.0075, if 240 nm>λ>231 nm.
18. The method of claim 17 , wherein:
growing the light emitting region comprises growing the light emitting region so that a variation in reciprocal lattice values of the bulk crystalline AlN substrate and the at least one quantum well layer is less than about 1.5%.
19. The method of claim 17 , wherein:
the bulk crystalline AlN substrate has a lattice constant a bulk-AlN ; and
the at least one Al x Ga 1-x N quantum well layer has a lattice constant, a strained , where a strained −a bulk-AlN ≦(λ (nm)−230)*0.0012 Å.
20. The method of claim 19 , further comprising:
homoepitaxially growing an AlN layer above the bulk crystalline AlN substrate so that the homoepitaxially grown AlN layer is disposed between the light emitting region and the bulk crystalline AlN substrate; and
removing at least some of the bulk crystalline Al substrate.
21. The method of claim 20 , further comprising removing at least some of the homoepitaxially grown AlN layer.
22. The method of claim 19 , further comprising:
epitaxially growing an AlGaN or AlGaInN layer above the bulk crystalline AlN substrate so that the epitaxially grown AlGaN or AlGaInN layer is disposed between the light emitting region and the bulk crystalline AlN substrate; and
removing some or all of the bulk crystalline AlN substrate.
23. The method of claim 22 , further comprising removing at least some of the epitaxially grown AlGaN or AlGaInN layer.