This invention pertains to a golf ball which includes a core, optionally one or more intermediate layers; and an outer cover layer. The outer cover layer and/or one or more intermediate layers includes a blend of a) about 2 to about 40 wt % (based on the total weight of the blend composition) of an aramid polymer and b) about 60 to about 98 wt % (based on the total weight of the blend composition) of one or more additional polymer components. The blend composition has a melt flow index (MFI) from about 1 to about 80 g/10 min., a material hardness of about 30 to about 90 Shore D, and a flex modulus of about 10 to about 120 kpsi.
1. A golf ball comprising;
I a core;
II one or more intermediate layers; and
III an outer cover layer, and
wherein said one or more intermediate layers comprises a blend composition comprising;
A from about 5 to about 30 wt % (based on the total weight of the blend composition) of an aramid polymer having the general formula
—NH—Ar 1 —NH—C(O)—Ar 2 —C(O)—
wherein Ar 1 and Ar 2 independently represent p-phenylene, m-phenylene, halogen-substituted p-phenylene, halogen-substituted m-phenylene, 4,4-substituted diphenyl methane, or mixtures thereof; and
B from about 70 to about 95 wt % (based on the total weight of the blend composition) of one of more additional blend component which is selected from the group consisting of a block copolymer, a unimodal ethylene/(meth)acrylic acid copolymer, a unimodal ethylene/(meth)acrylic acid/alkyl (meth)acrylate terpolymer, a bimodal ethylene/(meth)acrylic acid copolymer, a bimodal ethylene/(meth)acrylic acid/alkyl (meth)acrylate terpolymer, a unimodal ionomer, a bimodal ionomer, a modified unimodal ionomer, a modified bimodal ionomer, a polyalkenamer, a polyamide, a thermoplastic or thermoset polyurethane or thermoplastic or thermoset polyurea, or a multicomponent blend composition (“MCBC”), the MCBC comprising (A) a block copolymer; and (B) one or more acidic polymers; and (C) one or more basic metal salts present in an amount to neutralize at greater than or equal to about 30 percent of the acid groups of Component (B), and any and all combinations thereof; and
wherein said blend composition has;
i a melt flow index (MFI) of from about 3 to about 40 g/10 min.;
ii a material hardness of from about 36 to about 75 Shore D; and
iii a flex modulus of from about 40 to about 90 kpsi.
2. The golf ball of claim 1 wherein said blend composition comprises;
A from about 8 to about 20 wt % (based on the total weight of the blend composition) of said aramid polymer is selected from the group consisting of poly(para-phenyleneterephthalamide), poly(meta-phenyleneisophthalamide), and any and all copolymers and combinations thereof; and
B from about 80 to about 92 wt % (based on the total weight of the blend composition) of said additional blend component which is selected from the group consisting of a block copolymer, a unimodal ionomer, a bimodal ionomer, a modified unimodal ionomer, a modified bimodal ionomer, a polyalkenamer, a multicomponent blend composition (“MCBC”) comprising (A) a block copolymer; and (B) one or more acidic polymers; and (C) one or more basic metal salts present in an amount to neutralize at greater than or equal to about 30 percent of the acid groups of Component (B) and any and all combinations thereof; and
wherein said blend composition has;
i a melt flow index (MFI) of from about 4 to about 30 g/10 min.;
ii a material hardness of from about 40 to about 72 Shore D; and
iii a flex modulus of from about 50 to about 80 kpsi.
3. The golf ball of claim 1 wherein said core;
a has a diameter of from about 0.5 to about 1.62 inches;
b has a PGA compression of less than about 100; and
c comprises a peptizer selected from the group consisting of an organic sulfur compound, a metal salt of an organic sulfur compound, a non-metal salt of an organic sulfur compound, and any and all combinations thereof.
4. The golf ball of claim 1 wherein said core;
a has a diameter of from about 0.9 to about 1.58 inches;
b has a PGA compression of less than about 90; and
c further comprises one or more core layers each exhibiting a different hardness wherein the difference in hardness between each core layer is greater than 5 units of Shore D.
5. A three piece golf ball consisting essentially of;
I a core;
II an outer cover layer having a thickness of from about 0.020 to about 0.080 inches and a Shore D hardness as measured on the ball of from about 38 to about 68, and
III an intermediate layer having a thickness of from about 0.02 to about 0.200 inches and a Shore D hardness as measured on the ball of greater than about 40; and
wherein said intermediate layer comprises a blend composition comprising;
A from about 5 to about 30 wt % (based on the total weight of the blend composition) of said aramid polymer having the general formula
—NH—Ar 1 —NH—C(O)—Ar 2 —C(O)—
wherein Ar 1 and Ar 2 independently represent p-phenylene, m-phenylene, halogen-substituted p-phenylene, halogen-substituted m-phenylene, 4,4-substituted diphenyl methane, or mixtures thereof; and
B from about 70 to about 95 wt % (based on the total weight of the blend composition) of said additional blend component which is selected from the group consisting of a block copolymer, a unimodal ethylene/(meth)acrylic acid copolymer, a unimodal ethylene/(meth)acrylic acid/alkyl (meth)acrylate terpolymer, a bimodal ethylene/(meth)acrylic acid copolymer, a bimodal ethylene/(meth)acrylic acid/alkyl (meth)acrylate terpolymer, a unimodal ionomer, a bimodal ionomer, a modified unimodal ionomer, a modified bimodal ionomer, a polyalkenamer, a polyamide, a thermoplastic or thermoset polyurethane or thermoplastic or thermoset polyurea, or a multicomponent blend composition (“MCBC”), the MCBC comprising (A) a block copolymer; and (B) one or more acidic polymers; and (C) one or more basic metal salts present in an amount to neutralize at greater than or equal to about 30 percent of the acid groups of Component (B), and any and all combinations thereof; and
wherein said blend composition has;
i a melt flow index (MFI) of from about 3 to about 40 g/10 min.;
ii a material hardness of from about 36 to about 75 Shore D; and
iii a flex modulus of from about 40 to about 90 kpsi.
6. The three piece golf ball of claim 5 wherein said core;
a has a diameter greater than or equal to 1.41 inch;
b has a PGA compression of less than about 140; and
c comprises a peptizer selected from the group consisting of an organic sulfur compound, a metal salt of an organic sulfur compound, a non-metal salt of an organic sulfur compound, and any and all combinations thereof.