Method for forming a thermoplastic composition that contains a plasticized starch polymer
View Patent ↗A method and system for melt processing a thermoplastic composition that contains a starch and plasticizer is provided. The composition is melt blended and extruded through a die to form an extrudate, which is thereafter cooled using a multi-stage system of the present invention that includes at least one water-cooling stage and at least one air-cooling stage. More particularly, the extrudate is initially contacted with water for a certain period time so that it becomes partially cooled and solidified on its surface. After the water-cooling stage(s), the extrudate is also subjected to at least one air-cooling stage in which a stream of air is placed into contact with the extrudate.
1. A method for forming a thermoplastic starch-based composition, the method comprising:
melt extruding a thermoplastic composition through a die to form an extrudate, wherein the thermoplastic composition comprises a starch polymer and a plasticizer, wherein the plasticizer is a polyhydric alcohol or a sugar alcohol;
subjecting the extrudate to at least one water-cooling stage in which the extrudate is contacted with water for a first period of time; and
thereafter, subjecting the water-cooled extrudate to at least one air-cooling stage in which the extrudate is contacted with air for a second period of time, wherein the air-cooled extrudate has a moisture content of from about 1,000 to about 10,000 parts per million, wherein a film formed from the thermoplastic starch-based composition exhibits a percent strain at break in the cross-machine direction of about 550% or more.
2. The method of claim 1 , wherein the first period of time is from about 1 to about 50 seconds.
3. The method of claim 1 , wherein the temperature of the water is from about 10° C. to about 60° C.
4. The method of claim 1 , wherein the extrudate is immersed within a water cooling device during the water-cooling stage.
5. The method of claim 1 , wherein the second period of time is from about 1 to about 50 seconds.
6. The method of claim 1 , wherein the temperature of the stream of air is from about 0° C. to about 40° C.
7. The method of claim 1 , wherein the stream of air is provided by an air knife.
8. The method of claim 1 , further comprising pelletizing the air-cooled extrudate.
9. The method of claim 1 , wherein the starch polymer is a corn starch.
10. The method of claim 1 , wherein the weight ratio of starch polymers to plasticizers in the thermoplastic composition is from about 1 to about 10.
11. The method of claim 1 , further comprising melt-extruding the air-cooled extrudate onto a surface to form a substrate.
12. A method for forming a thermoplastic starch-based composition, the method comprising:
melt extruding a thermoplastic composition through a die to form an extrudate, wherein the thermoplastic composition comprises a starch polymer, a plasticizer, wherein the plasticizer is a polyhydric alcohol or sugar alcohol, a biodegradable polymer, a polyolefin, and a compatibilizer;
subjecting the extrudate to at least one water-cooling stage in which the extrudate is contacted with water for a first period of time; and
thereafter, subjecting the water-cooled extrudate to at least one air-cooling stage in which the extrudate is contacted with air for a second period of time, wherein the air-cooled extrudate has a moisture content of from about 1,000 to about 10,000 parts per million, wherein a film formed from the thermoplastic starch-based composition exhibits a percent strain at break in the cross-machine direction of about 550% or more.
13. The method of claim 12 , wherein the polyolefin is a copolymer of an ethylene and an α-olefin; and the biodegradable polymer is an aliphatic-aromatic copolyester.
14. The method of claim 13 , wherein the compatibilizer has a polar component and a non-polar component, the non-polar component being provided by an olefin.