Polyester resin composition
A polyester resin composition comprises (A) about 100 parts by weight of polyester resin with a melting point greater than about 200° C. and including repeat units of Formula 1; (B) about 0.1 to about 80 parts by weight of white pigment; and (C) about 0.01 to about 80 parts by weight of filler. The polyester resin composition of the present invention does not exhibit deteriorated reflectance and impact strength and also has good heat resistance, non-yellowing property and humidity resistance and can be used in a light emitting diode (LED) reflector.
1. A polyester resin composition comprising:
(A) about 100 parts by weight of polyester resin with a melting point greater than about 200° C. including units derived from a diol component including 1,4-cyclohexanedimethanol and including repeat units of the following Formula 1, wherein the diol component of the polyester resin (A) further includes greater than 0% and up to about 85% by weight of ethylene glycol, based on 100% by weight of the diol component;
(B) about 0.1 to about 80 parts by weight of white pigment; and
(C) about 0.01 to about 80 parts by weight of filler,
wherein the polyester resin composition has an initial reflectance value of more than about 90 at a wavelength of 440 nm measured using a color-difference meter, a decline of reflectance value of less than about 10 which is measured again after maintaining the polyester resin composition under conditions of 85° C. and 85% relative humidity for 144 hours, and a change of initial yellow index (YI) of less than about 5 measured using a color-difference meter after maintaining the polyester resin composition under conditions of 85° C. and 85% relative humidity for 144 hours.
2. The polyester resin composition of claim 1 , wherein the (A) polyester resin has an intrinsic viscosity of about 0.4 to about 1.5 dl/g.
3. The polyester resin composition of claim 1 , wherein the (B) white pigment comprises titanium dioxide, zinc oxide, zinc sulfide, white lead, zinc sulfate, barium sulfate, calcium carbonate, aluminum oxide, or a combination thereof.
4. The polyester resin composition of claim 1 , wherein the (B) white pigment is treated with an inorganic surface treatment agent, organic surface treatment agent, or a combination thereof.
5. The polyester resin composition of claim 1 , wherein the (B) white pigment has an average particle size of about 0.05 to about 20 μm.
6. The polyester resin composition of claim 1 , further including an additive selected from the group consisting of fluorescence brightening agents, lubricants, release agents, nucleating agents, antistic agents, UV stabilizers, stabilizers, reinforcement materials, inorganic additives, colorants and combinations thereof.
7. The polyester resin composition of claim 1 , wherein the polyester resin composition has a water uptake of less than about 2% for 20 minutes measured using a moisture analyzer after maintaining the polyester resin composition under conditions of 85° C. and 85% relative humidity for 48 hours.
8. The polyester resin composition of claim 1 , wherein the diol component of the polyester resin (A) includes about 30 to about 80% by weight of 1,4-cyclohexanedimethanol and about 20 to about 70% by weight of ethylene glycol.
9. The polyester resin composition of claim 1 , wherein the diol component of the (A) polyester resin further includes C 6 -C 21 aromatic diol, C 3 -C 8 aliphatic diol, or a combination thereof.
10. The polyester resin composition of claim 9 , wherein the C 6 -C 21 aromatic diol or C 3 -C 8 aliphatic diol include propane-1,3-diol, butane-1,4-diol, pentane-1,5-diol, hexane-1,6-diol, 3-methylpentane-2,4-diol, 2-methylpentane-1,4-diol, 2,2,4-trimethylpentan-1,3-diol, 2-ethylhexane-1,3-diol, 2,2-diethylpropane-1,3-diol, 1,4-cyclobutanedimethanol, 2,2-bis-(hydroxyethoxyphenyl)-propane, 2,2-bis-(4-hydroxypropoxyphenyl)-propane or a combination thereof.
11. The polyester resin composition of claim 1 , wherein the (C) filler comprises carbon fibers, glass fibers, boron fibers, glass bids, glass flakes, carbon black, diatom earth, clay, kaolin, talc, mica, calcium carbonate, wollastonite, potassium titanate whiskers, aluminum boric acid whiskers, zinc oxide whiskers, calcium whiskers or a combination thereof.
12. The polyester resin composition of claim 11 , wherein the glass fiber has an average length of about 0.1 to about 20 mm and an aspect ratio of about 10 to about 2000.
13. An article prepared from the polyester resin composition of claim 1 .
14. The article of claim 13 , wherein the article is a reflector for a light emitting diode (LED).