Process for preparing polysaccharide fibers from aqueous alkali metal hydroxide solution
View Patent ↗This invention pertains to a novel processing for preparing fibers from poly(α(1→3)glucan). The fibers prepared according to the invention, have “cotton-like” properties, are useful in textile applications, and can be produced as continuous filaments on a year-round basis. The process comprises solution spinning a 5-20% solids concentration of poly(α(1→3)glucan) in an aqueous alkali metal hydroxide, in particular NaOH at concentration of 2 to 10 weight-%, and coagulating the spun fiber in an acid coagulation liquid.
1. A process for preparing a poly(alpha(1→3)glucan) fiber, comprising forming an isotropic solution by dissolving in an aqueous alkali metal hydroxide, 5 to 20% by weight of the total weight of the resulting solution of poly(alpha(1→3)glucan) comprising a number average molecular weight (M n ) of at least 10,000 Da, wherein the alkali metal hydroxide in the solution has a concentration of 2 to 10%; causing said solution to flow through a spinneret, forming a fiber thereby; and causing the aqueous alkali metal hydroxide to be extracted from the thus formed fiber by contacting said fiber with an acidic liquid coagulant.
2. The process of claim 1 wherein the alkali metal hydroxide is NaOH.
3. The process of claim 2 wherein the concentration of the NaOH in the solution is 4 to 6%.
4. The process of claim 3 wherein the solids concentration of the poly(α(1→3)glucan) is in the range of 7.5 to 16% and the poly(α(1→3)glucan) comprises a number average molecular weight of at least 10,000 Daltons.
5. The process of claim 4 wherein the liquid coagulant is glacial acetic acid.
6. The process of claim 4 wherein the liquid coagulant comprises sulfuric acid.
7. The process of claim 4 further comprising soaking the fiber after coagulation in a neutral to basic liquid.
8. The process of claim 1 wherein the solids concentration of the poly(α(1→3)glucan) is in the range of 7.5 to 16%.
9. The process of claim 1 wherein the poly(α(1→3) glucan) comprises a number average molecular weight of at least 10,000 Daltons.
10. The process of claim 1 wherein the liquid coagulant is glacial acetic acid.
11. The process of claim 1 wherein the liquid coagulant comprises sulfuric acid.
12. The process of claim 1 further comprising soaking the fiber after coagulation in a liquid bath.
13. The process of claim 1 further comprising soaking the fiber after coagulation in a neutral to basic liquid.