Small pore molecular sieve supported copper catalysts durable against lean/rich aging for the reduction of nitrogen oxides
View Patent ↗A method of using a catalyst comprises exposing a catalyst to at least one reactant in a chemical process. The catalyst comprises copper and a small pore molecular sieve having a maximum ring size of eight tetrahedral atoms. The chemical process undergoes at least one period of exposure to a reducing atmosphere. The catalyst has an initial activity and the catalyst has a final activity after the at least one period of exposure to the reducing atmosphere. The final activity is within 30% of the initial activity at a temperature between 200 and 500° C.
1. A method for using a catalyst comprising exposing a catalyst to at least one reactant in a chemical process, wherein the catalyst comprises copper and a small pore molecular sieve having a maximum ring size of eight tetrahedral atoms, the chemical process undergoes at least one period of exposure to a reducing atmosphere, the catalyst has an initial activity and the catalyst has a final activity after the at least one period of exposure to the reducing atmosphere, wherein the final activity is within 30% of the initial activity at a temperature between 200 and 500° C.
2. The method according to claim 1 , wherein the catalyst has a final activity that is within 10% of the initial activity at a temperature between 200 and 500° C.
3. The method according to claim 1 , wherein the catalyst has a final activity that is within 3% of the initial activity at a temperature between 250 and 350° C.
4. A method according to claim 1 , wherein the chemical process is selected from the group consisting of selective catalytic reduction, catalyzed soot filter regeneration, and NO X trap regeneration.
5. The method according to claim 1 , wherein the small pore molecular sieve is selected from the group consisting of aluminosilicate molecular sieves, metal-substituted aluminosilicate molecular sieves, and aluminophosphate molecular sieves.
6. The method according to claim 1 , wherein the small pore molecular sieves is selected from the group of Framework Type consisting of: ACO, AEI, AEN, AFN, AFT, AFX, ANA, APC, APD, ATT, CDO, DDR, DFT, EAB, EDI, EPI, ERI, GIS, GOO, IHW, ITE, ITW, LEV, KFI, MER, MON, NSI, OWE, PAU, PHI, RHO, RTH, SAT, SAV, SIV, THO, TSC, UEI, UFI, VNI, YUG AND ZON.
7. A method according to claim 1 , wherein the small pore molecular sieves containing a maximum ring size of eight tetrahedral atoms is selected from the group Framework Type consisting of LEV, ERI and DRR.