Compositions of polyamide and ionomer
View Patent ↗Disclosed is a shaped article comprising a composition comprising polyamide and ionomer wherein the ionomer comprises a mixture of Zn and alkali metal (M2) cations wherein the Zn/M2 equivalent ratio is from about 0.6 to about 6. The articles prepared from the compositions with mixed ion ionomers exhibit high stiffness, hardness and toughness, good scratch resistance, desirable low melt viscosity and high processability.
1. A shaped article comprising a polyamide/ionomer blend composition comprising
(1) a polyamide having a melt viscosity from 400 Pa·sec to 4000 Pa·sec, measured at 250° C. and a shear rate of 12 sec −1 , in an amount in the range of about 35 to about 70 weight % of the combination of (1) and (2); and
(2) an ionomer composition in an amount in the range of about 30 to about 65 weight % of the combination of (1) and (2), wherein the ionomer composition comprises at least one neutralized acid copolymer, wherein the acid copolymer comprises copolymerized units of ethylene with
(a) copolymerized units of an alpha-beta unsaturated monocarboxylic acid wherein the monocarboxylic acid is methacrylic acid or acrylic acid or a combination thereof;
(b) optionally copolymerized units of an alpha-beta unsaturated dicarboxylic acid derivative selected from maleic anhydride and alkyl monoesters of maleic acid or fumaric acid, in the amount of 0 to about 7 weight % of the copolymer; wherein the combination of (a) and (b) is from about 7 to about 21 weight % of the copolymer;
(c) optionally copolymerized units of an alkyl acrylate or alkyl methacrylate comonomer, in the amount of 0 to about 25 weight % of the copolymer; and
wherein 60 mol % to about 95 mole % of the total carboxylic acid groups in the copolymer are neutralized to salts comprising cations of zinc (Zn) and cations of sodium, wherein Zn cations comprise about 10 to about 90% mole equivalents and sodium cations comprise about 90 to 10% mole equivalents.
2. The article according to claim 1 wherein the polyamide has a melt viscosity from 400 Pa·sec to about 3000 Pa·sec, measured at 250° C. and a shear rate of 12 sec −1 .
3. The article according to claim 1 wherein Zn cations comprise about 30 to about 70% mole equivalents.
4. The article according to claim 3 wherein the polyamide is nylon-6, nylon-66, nylon-610, nylon-612, nylon-1010, nylon-11, nylon-12, or a combination thereof.
5. The article according to claim 1 wherein the polyamide is nylon-6, nylon-66, nylon-610, nylon-612, nylon-6/66, nylon-6/610, nylon-6/66/610, nylon-6/6t, nylon-1010, nylon-11, nylon-12, or a combination thereof.
6. The article according to claim 5 wherein the polyamide is nylon-6 with relative viscosity from 2.7 to 4.0, as measured using 1% of polymer in 96% sulfuric acid according to ISO Test Method 307.
7. The article according to claim 1 wherein the polyamide has a melting point in the range of 170 to 290 C.°, as measured according to differential scanning calorimetry by ASTM D789.
8. The article according to claim 7 wherein the polyamide has a melting point in the range of 170 to about 230° C., and comprises an aliphatic or semiaromatic polyamide.
9. The article according to claim 7 wherein the polyamide comprises an aliphatic polyamide.
10. The article according to claim 1 wherein the shape of the article is nonplanar and comprises a surface or outside layer comprising the polyamide/ionomer blend composition.
11. The article according to claim 10 wherein the article consists essentially of the blend composition.
12. The article according to claim 10 wherein the article is multilayer, comprising a surface layer consisting essentially of the blend composition and at least one additional layer comprising a composition other than the blend composition.
13. The article according to claim 10 wherein the article is a container, molded automotive part, bottle, jar, tub, tank, tray, cup, rod stock, casing element for a portable communication device, can, bucket, box, bowl, vial, tube, bottle preform, or cap.
14. The article according to claim 1 having greater scratch resistance measured according to ISO 1518 than a comparison article comprising a comparison blend of the polyamide and an ionomer comprising cations of zinc that does not contain cations of sodium.
15. The article according to claim 1 wherein the polyamide comprises nylon-6 with relative viscosity from 3.1 to 4.0, as measured using 1% of polymer in 96% sulfuric acid according to ISO Test Method 307, and wherein the ionomer composition comprises at least one neutralized acid copolymer, wherein the acid copolymer comprises copolymerized units of ethylene with copolymerized units of an alpha-beta unsaturated monocarboxylic acid wherein the monocarboxylic acid is methacrylic acid or acrylic acid or a combination thereof; and wherein 75 mol % to about 85 mole % of the total carboxylic acid groups in the copolymer are neutralized to salts comprising cations of zinc (Zn) and cations of sodium, wherein the equivalent ratio of zinc to sodium is from 0.7 to 1.7.