Nanotube-based insulators
View Patent ↗A nanotube-based insulator is provided having thermal insulating properties. The insulator can include a plurality of nanotube sheets stacked on top of one another. Each nanotube sheet can be defined by a plurality of carbon nanotubes. The plurality of carbon nanotubes can be configured so as to decrease normal-to-plane thermal conductivity while permitting in-plane thermal conductivity. A plurality of spacers can be situated between adjacent nanotube sheets so as to reduce interlayer contact between the nanotubes in each sheet. The plurality of spacers can be ceramic or alumina dots or provided by texturing the nanotube sheets.
1. An insulator comprising:
a plurality of nanotube sheets positioned on top of one another,
each sheet is wound about its central axis to form multiple distinct layers with a plurality of nanotubes in each distinct layer, the nanotubes being substantially contained within each distinct layer as to minimize normal-to-plane thermal conductivity between distinct layers; and
a plurality of spacers situated between adjacent nanotube sheets in order to reduce intersheet contact, so as to further minimize normal-to-plane thermal conductivity between the sheets.
2. The insulator of claim 1 , wherein the nanotube sheets are defined by non-woven nanotubes.
3. The insulator of claim 1 , wherein each nanotube sheet includes a dopant to decrease normal-to-plane thermal conductivity.
4. The insulator of claim 3 , wherein the dopant is boron, carbon 13, an irradiated CNT material, or a combination thereof.
5. The insulator of claim 4 , wherein the dopant is about 0.5 to about 5% weight percent boron.
6. The insulator of claim 4 , wherein the dopant is about 2% weight percent boron.
7. The insulator of claim 1 , wherein the plurality of nanotubes are substantially aligned in-plane to maintain the in-plane thermal conductivity.
8. The insulator of claim 1 , wherein the plurality of spacers are alumina or ceramic dots situated between adjacent nanotube sheets.
9. The insulator of claim 1 , wherein the plurality of spacers are a plurality of holes in each nanotube sheet.
10. The insulator of claim 1 , wherein the plurality of spacers are provided by a porous layer of non-metal material having poor thermal conductivity and positioned between adjacent nanotube sheets.
11. The insulator of claim 1 , wherein the plurality of spacers are provided by a texture in each nanotube sheet to define a rough surface having peaks and valleys thereon, so as to minimize surface contact between adjacent nanotube sheets.