IP Library Granted Patent US 8,298,331
Granted Patent B2
US 8,298,331 · App. 13/349,778 · Granted Oct 30, 2012

Zeolite and water slurries for asphalt concrete pavement

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Quick Facts
Patent No.
US 8,298,331
App. No.
13/349,778
Granted
Oct 30, 2012
Kind
B2
Abstract

Embodiments provide slurries of water and zeolite. These slurries have beneficial properties when mixed with asphalt. These beneficial properties may include extension of the asphalt as well as a decrease in the temperature used to process the cement. In some embodiments additional additives are included, such as anti-strip amines. Methods of making and using the slurries, as well as cement mixtures incorporating the slurries are also included herein.

Claims (29)

1. A slurry for reducing the mix temperature of asphalt cement, comprising:

water in an amount between 30-99% of the slurry by weight;

zeolite in an amount between 1-70% by weight; and

a cationic polyamine.

2. The slurry of claim 1 , wherein said water is present between 40-50% by weight and zeolite is present between 50-60% by weight.

3. The slurry of claim 1 , wherein said zeolite is at least one member of the group consisting of amicite, analcime, barrerite, bellbergite, bikitaite, boggsite, brewsterite, chabazite, clinoptilolite, cowlesite, dachiardite, edingtonite, epistilbite, erionite, faujasite, ferrierite, garronite, gismondine, gmelinite, gobbinsite, gonnardite, goosecreekite, harmotome, herschelite, heulandite, laumontite, levyne, maricopaite, mazzite, merlinoite, mesolite, montesommaite, mordenite, natrolite, offretite, paranatrolite, paulingite, pentasil (also known as zsm-5), perlialite, phillipsite, pollucite, scolecite, sodium dachiardite, stellerite, stilbite, tetranatrolite, thomsonite, tschernichite, wairakite, wellsite, willhendersonite, yugawaralite, zeolite A, zeolite P, zeolite X, and zeolite Y.

4. The slurry of claim 1 , wherein the zeolite is hydrated zeolite sodium A.

5. The slurry of claim 1 , wherein the zeolite is a hydrated zeolite.

6. The slurry of claim 1 , further comprising a liquid anti-strip composition.

7. The slurry of claim 6 , wherein said liquid anti-strip composition is selected from the group consisting of a polyamine, bishexamethylenetriamine (BHMT), a tallow amine, an amidoamine, and a phosphate ester.

8. The slurry of claim 6 , wherein said water is present in an amount between 29%-59% by weight, said zeolite is present in an amount between 1%-70% by weight, and said liquid anti-strip composition is present in an amount between 1%-40% by weight.

9. The slurry of claim 8 , wherein said water is present in an amount between 25%-35% by weight, said zeolite is present in an amount between 35%-45% by weight, and said liquid anti-strip composition is present in an amount between 25-30% by weight.

10. The slurry of claim 1 , further comprising lime in an amount between 40%-60% by weight, water in an amount between 25%-50% by weight, and zeolite in an amount between 10%-15% by weight.

11. The slurry of claim 10 , wherein said lime is present in an amount between 40%-48% by weight, water in an amount between 40%-50% by weight, and zeolite in an amount between 10%-12% by weight.

12. The slurry of claim 1 , further comprising 0.5%-5.0% surfactant by weight, and wherein said water is present in 25%-98.5% by weight and zeolite present in 1-70% by weight.

13. The slurry of claim 12 , wherein said surfactant is present in an amount between 1%-2% by weight, zeolite present between 50%-60% by weight, and water present between 38%-49% by weight.

14. The slurry of claim 1 , wherein said cationic polyamine is present in an amount between 0.1%-0.5% by weight.

15. The slurry of claim 10 , wherein said lime is present in an amount between 40%-48% by weight, water in an amount between 40%-50% by weight, and zeolite in an amount between 10%-12% by weight.

16. A slurry for reducing the mix temperature of asphalt cement, comprising:

water in an amount between 30-99% of the slurry by weight;

zeolite in an amount between 1-70% by weight; and

a liquid anti-strip composition.

17. The slurry of claim 16 , wherein said liquid anti-strip composition is selected from the group consisting of a polyamine, bishexamethylenetriamine (BHMT), a tallow amine, an amidoamine, and a phosphate ester.

18. The slurry of claim 16 , wherein said water is present in an amount between 29%-59% by weight, said zeolite is present in an amount between 1%-70% by weight, and said liquid anti-strip composition is present in an amount between 1%-40% by weight.

19. The slurry of claim 18 , wherein said water is present in an amount between 25%-35% by weight, said zeolite is present in an amount between 35%-45% by weight, and said liquid anti-strip composition is present in an amount between 25-30% by weight.

20. A slurry for reducing the mix temperature of asphalt cement, comprising:

water in an amount between 25%-50% of the slurry by weight;

zeolite in an amount between 10-15% by weight; and

lime in an amount between 40%-60% by weight.

Assignments (21)
CHANGE OF NAME Recorded Dec 2, 2021
From: PQ CORPORATION
To: PQ LLC
Reel/Frame 058295/0836 →
CORRECTIVE ASSIGNMENT TO CORRECT THE CONVEYING PARTY NAME PREVIOUSLY RECORDED AT REEL: 057089 FRAME: 0345. ASSIGNOR(S) HEREBY CONFIRMS THE RELEASE OF SECURITY INTEREST. Recorded Aug 6, 2021
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: PQ CORPORATION
Reel/Frame 057109/0688 →
PARTIAL RELEASE OF SECURITY INTEREST IN PATENTS RECORDED AT R/F 056539/0903 Recorded Aug 5, 2021
From: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH, AS ADMINISTRATIVE AGENT
To: PQ CORPORATION
Reel/Frame 057089/0255 →
PARTIAL RELEASE OF SECURITY INTEREST IN PATENTS RECORDED AT R/F 038861/0071 Recorded Aug 5, 2021
From: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH, AS COLLATERAL AGENT
To: PQ CORPORATION
Reel/Frame 057089/0345 →
RELEASE OF SECURITY INTEREST IN PATENTS RECORDED AT R/F 038860/0900 Recorded Aug 5, 2021
From: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH, AS ADMINISTRATIVE AGENT
To: PQ CORPORATION
Reel/Frame 057089/0382 →
TERM LOAN PATENT SECURITY AGREEMENT Recorded Jun 10, 2021
From: PQ CORPORATION
To: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH, AS AGENT
Reel/Frame 056539/0903 →
RELEASE OF SECURITY INTEREST IN PATENTS AT R/F 053281/0474 Recorded Jun 10, 2021
From: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH, AS COLLATERAL AGENT
To: PQ CORPORATION
Reel/Frame 056539/0782 →
SECURITY INTEREST Recorded Jul 22, 2020
From: PQ CORPORATION
To: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH, AS COLLATERAL AGENT
Reel/Frame 053281/0474 →
RELEASE OF SECURITY INTEREST AT R/F 38860/0012 Recorded Jul 22, 2020
From: WELLS FARGO BANK, N.A., AS COLLATERAL AGENT
To: PQ CORPORATION
Reel/Frame 053281/0616 →
PATENT SECURITY AGREEMENT (NOTES) Recorded Jun 1, 2016
From: PQ CORPORATION
To: WELLS FARGO BANK, NATIONAL ASSOCIATION, AS COLLATERAL AGENT
Reel/Frame 038860/0012 →
PATENT SECURITY AGREEMENT (ABL) Recorded Jun 1, 2016
From: PQ CORPORATION
To: CITIBANK, N.A., AS COLLATERAL AGENT
Reel/Frame 038861/0071 →
PATENT SECURITY AGREEMENT (TERM) Recorded Jun 1, 2016
From: PQ CORPORATION
To: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH, AS COLLATERAL AGENT
Reel/Frame 038860/0900 →
RELEASE OF SECURITY INTEREST Recorded May 5, 2016
From: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH, AS ADMINISTRATIVE AGENT
To: PQ CORPORATION; POTTERS INDUSTRIES, LLC
Reel/Frame 038612/0222 →
RELEASE OF SECURITY INTEREST Recorded May 4, 2016
From: WILMINGTON TRUST, NATIONAL ASSOCIATION, AS ADMINISTRATIVE AGENT
To: PQ CORPORATION; POTTERS INDUSTRIES, LLC
Reel/Frame 038611/0927 →
SECURITY AGREEMENT Recorded Nov 30, 2012
From: PQ CORPORATION; POTTERS INDUSTRIES, LLC
To: WILMINGTON TRUST, NATIONAL ASSOCIATION, AS ADMINISTRATIVE AGENT
Reel/Frame 029377/0878 →
SECURITY AGREEMENT Recorded Nov 29, 2012
From: PQ CORPORATION; POTTERS INDUSTRIES, LLC
To: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH, AS ADMINISTRATIVE AGENT
Reel/Frame 029370/0103 →
RELEASE OF SECURITY INTEREST IN PATENTS Recorded Nov 26, 2012
From: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH
To: PQ CORPORATION
Reel/Frame 029349/0592 →
RELEASE OF SECURITY INTEREST IN PATENTS Recorded Nov 26, 2012
From: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH
To: PQ CORPORATION
Reel/Frame 029349/0556 →
FIRST LIEN GRANT OF SECURITY INTEREST IN PATENTS AMENDMENT NO. 1 Recorded Apr 3, 2012
From: PQ CORPORATION
To: CREDIT SUISSE AG, AS SUCCESSOR AGENT
Reel/Frame 027980/0194 →
SECOND LIEN GRANT OF SECURITY INTEREST IN PATENTS AMENDMENT NO. 1 Recorded Apr 3, 2012
From: PQ CORPORATION
To: CREDIT SUISSE AG, AS SUCCESSOR AGENT
Reel/Frame 027980/0219 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 20, 2012
From: RIBEIRO, FLAVIO ERNESTO
To: PQ CORPORATION
Reel/Frame 027892/0505 →