Photocatalyst comprising TiO
View Patent ↗A photocatalyst is provided that comprises activated carbon produced from date pits, impregnated with TiO 2 . The activated carbon can have a porous surface that can attract and trap pollutants flowing in air or water. The photocatalyst can be made by a method that includes preparing activated carbon by calcining date pits to form a precursor material, and then impregnating the precursor material with titanium dioxide.
1. A method consisting essentially of:
contacting date pits with a phosphoric acid solution having a phosphoric acid concentration of from about 1% by weight to about 30% by weight, to form treated date pits;
drying the treated date pits to form treated, dried date pits;
heating the treated, dried date pits under a nitrogen blanket and under conditions to cause the treated, dried date pits to thermally decompose and form activated carbon; and
pulverizing and screening the activated carbon.
2. The method of claim 1 , wherein the phosphoric acid solution has a concentration of phosphoric acid of 5% by weight.
3. The method of claim 1 , wherein the concentration of phosphoric acid in the phosphoric acid solution is from about 5% by weight to about 20% by weight.
4. The method of claim 1 , wherein the treated date pits are treated at a temperature of from about 80° C. to about 150° C., for a period of from about 1 hour to about 12 hours, to dry the treated date pits, prior to the heating.
5. The method of claim 1 , wherein the heating occurs at a temperature of from about 300° C. to about 900° C.
6. The method of claim 1 , wherein the phosphoric acid solution has a concentration of phosphoric acid of 10% by weight.
7. The method of claim 1 , further comprising treating the activated carbon with carbon dioxide gas.
8. A method comprising:
contacting date pits with an acidic aqueous solution, to form treated date pits;
heating the treated date pits under conditions to cause the treated date pits to thermally decompose and form activated carbon; and
impregnating the activated carbon with titanium dioxide, to form an impregnated product, wherein the impregnating comprises impregnating the activated carbon with a solution of titanium dioxide, to form the impregnated product.
9. The method of claim 8 , wherein the impregnating comprises impregnating the activated carbon with a solution comprising from 10% by weight to 50% by weight titanium dioxide, to form the impregnated product.
10. The method of claim 8 , wherein the impregnating comprises impregnating the activated carbon with a solution comprising from about 20% by weight to about 30%, by weight titanium dioxide, to form the impregnated product.
11. A method consisting essentially of:
contacting date pits with a phosphoric acid solution having a phosphoric acid concentration of from about 1% by weight to about 30% by weight, to form treated date pits;
drying the treated date pits to form treated, dried date pits;
heating the treated, dried date pits under conditions to cause the treated, dried date pits to thermally decompose and form activated carbon;
pulverizing and screening the activated carbon; and
impregnating the activated carbon with titanium dioxide, to form an impregnated product.