Rare earth magnet and method for manufacturing same
View Patent ↗A rare-earth element including a magnet body containing a rare-earth element, and a protective layer formed on a surface of the magnet body. The protective layer may include a first layer covering the magnet body and containing a rare-earth element, and a second layer covering the first layer and containing substantially no rare-earth element. Another protective layer in accordance may include an inner protective layer and an outer protective layer successively from the magnet body side. The outer protective layer is any of an oxide layer, a resin layer, a metal salt layer, and a layer containing an organic-inorganic hybrid compound.
1. A rare-earth magnet comprising:
a magnet body having a constituent material based on R-TB, and
a protective layer formed on a surface of the magnet body by heat-treating the magnet body in an oxidizing atmosphere containing an oxidizing gas;
wherein:
R is a rare-earth element and T is a transition element selected from the group consisting of Fe and a mixture of Fe and Co;
the protective layer comprises:
(i) a first oxide layer consisting of a single layer covering the magnet body and containing the rare-earth element, the transition element, and oxygen, and
(ii) a second oxide layer covering the first oxide layer and containing the transition element, oxygen, and from substantially none of the rare-earth element to an amount of the rare-earth element that is smaller than an amount of the rare-earth element in the first oxide layer;
the first and second oxide layers do not contain any metal elements that are not contained in the magnet body; and
the first oxide layer is directly adhered to the magnet body and the second oxide layer is directly adhered to the first oxide layer.
2. The rare-earth magnet according to claim 1 , wherein the protective layer is formed by heat-treating the magnet body in an oxidizing atmosphere containing an oxidizing gas while adjusting at least one condition of a partial pressure of the oxidizing gas, a treatment temperature, and a treatment time such as to have the first oxide layer covering the magnet body and containing the rare-earth element, and the second oxide layer covering the first oxide layer and containing the rare-earth element by an amount smaller than that in the first layer.
3. The rare-earth magnet according to claim 1 , wherein the protective layer contains oxygen and an element derived from the magnet body.
4. The rare-earth magnet according to claim 1 , wherein the rare-earth element is neodymium.
5. The rare-earth magnet according to claim 1 , wherein the first and second oxide layers have a total thickness of 0.1 to 20 μm.
6. The rare-earth magnet according to claim 5 , wherein the first oxide layer has a thickness greater than a thickness of the second oxide layer, and the thickness of the second oxide layer is greater than 5 nm.
7. The rare-earth magnet according to claim 1 , wherein:
the first and second oxide layers have a total thickness ranging from 0.1 μm to 5 μm,
the first oxide layer has a thickness greater than a thickness of the second oxide layer, and
the thickness of the second oxide layer is greater than 5 nm.
8. The rare-earth magnet according to claim 1 , wherein the second oxide layer contains substantially none of the rare-earth element.