Electrolyte for electrochemical device, method for preparing the electrolyte and electrochemical device including the electrolyte
View Patent ↗Disclosed is an electrolyte for an electrochemical device. The electrolyte includes a composite of a plastic crystal matrix electrolyte doped with an ionic salt and a crosslinked polymer structure. The electrolyte has high ionic conductivity comparable to that of a liquid electrolyte due to the use of the plastic crystal, and high mechanical strength comparable to that of a solid electrolyte due to the introduction of the crosslinked polymer structure. Further disclosed is a method for preparing the electrolyte. The method does not essentially require the use of a solvent. Therefore, the electrolyte can be prepared in a simple manner by the method. The electrolyte is suitable for use in a cable-type battery whose shape is easy to change due to its high ionic conductivity and high mechanical strength.
1. A solid electrolyte for an electrochemical device comprising a composite of a plastic crystal matrix electrolyte doped with an ionic salt and a crosslinked polymer structure, wherein the crosslinked polymer structure is obtained by polymerization of only a monomer having two or more crosslinkable functional groups in the presence of the plastic crystal matrix electrolyte.
2. The solid electrolyte according to claim 1 , wherein the ionic salt-doped plastic crystal matrix electrolyte and the crosslinked polymer structure are present in a weight ratio of 30:70 to 90:10.
3. The solid electrolyte according to claim 1 , wherein the plastic crystal matrix electrolyte comprises succinonitrile.
4. The solid electrolyte according to claim 1 , wherein the ionic salt is a lithium salt.
5. The solid electrolyte according to claim 4 , wherein the lithium salt is selected from lithium bis-trifluoromethanesulfonylimide, lithium bis-perfluoroethylsulfonylimide, lithium tetrafluoroborate, and mixtures thereof.
6. The solid electrolyte according to claim 1 , wherein the monomer having two or more crosslinkable functional groups is selected from trimethylolpropane ethoxylate triacrylate, ethylene glycol dimethacrylate, trimethylolpropane trimethacrylate, ethoxylated bisphenol A dimethacrylate, ethylene glycol diacrylate, and mixtures thereof.
7. An electrochemical device comprising a cathode, an anode and the solid electrolyte according to claim 1 .
8. The electrochemical device according to claim 7 , wherein the electrochemical device is a lithium secondary battery.