System And Process For Producing Hydrogen And A Carbon Nanotube Product
A system for producing hydrogen and a carbon nanoproduct includes a hydrocarbon feed gas supply configured to supply a hydrocarbon feed gas at a selected flow rate, a reactor having a hollow reactor cylinder with an enclosed inlet adapted to continuously receive the hydrocarbon feed gas, a reaction chamber in fluid communication with the inlet, and an enclosed outlet in fluid communication with the reaction chamber adapted to discharge a product gas comprised of hydrogen and unreacted hydrocarbon feed gas, along with the carbon nanoproduct. The system also includes a catalyst transport system adapted to move a selected amount of a metal catalyst through the reaction chamber at a rate dependent on the flow rate of the hydrocarbon feed gas to form the product gas. The system also includes a carbon separator adapted to separate the carbon product from the product gas and from the metal catalyst.
1 . A system for producing hydrogen and a carbon nanoproduct comprising:
a hydrocarbon feed gas supply configured to supply a hydrocarbon feed gas at a selected flow rate;
a reactor comprising a hollow reactor cylinder having an enclosed inlet adapted to continuously receive the hydrocarbon feed gas, a reaction chamber in fluid communication with the inlet, and an enclosed outlet in fluid communication with the reaction chamber adapted to discharge a product gas comprised of hydrogen and unreacted hydrocarbon feed gas, along with the carbon nanoproduct;
a catalyst transport system configured to move a metal catalyst through the reaction chamber in contact with the hydrocarbon gas to form the product gas and the carbon nanoproduct, the catalyst transport system configured to provide a selected amount of catalyst in the reaction chamber dependant on the flow rate of the hydrocarbon feed gas and a selected mass ratio of the catalyst to the hydrogen feed gas; and
a carbon separator adapted to separate the carbon nanoproduct from the product gas and from the metal catalyst.
2 . The system of claim 1 wherein the flow rate is between 0.05 and 3.0 liters/minute and the selected amount of the catalyst is one gram/minute.
3 . The system of claim 1 further comprising a container in flow communication with the carbon separator adapted to collect the carbon nanoproduct.
4 . The system of claim 1 wherein the catalyst transport system comprises a chain conveyor system, a rotating auger system, a high velocity pneumatic system or a plunger system.
5 . The system of claim 1 wherein the reactor comprises a tube furnace heated by combustion or electricity to a temperature of from 600 to 900° C.
6 . The system of claim 1 wherein the hydrocarbon feed gas comprises methane, natural gas or a mixture thereof.
7 . The system of claim 1 wherein the mass ratio is from 20:1 to 40:1 carbon to catalyst, and the carbon nanoproduct comprises carbon nanotubes.
8 . The system of claim 1 wherein the mass ratio is from 200:1 to 500:1 carbon to catalyst, and the carbon nanoproduct comprises carbon nanofibers.
9 . The system of claim 1 wherein the product gas comprises 20% to 30% hydrogen by volume and 70% to 80% methane by volume.
10 . A process for producing hydrogen and a carbon nanoproduct comprising:
providing a reactor having a reaction chamber in fluid communication with a hydrocarbon feed gas supply configured to provide a hydrocarbon feed gas at a selected flow rate;
providing a catalyst transport system adapted to move a metal catalyst through the reaction chamber in contact with a hydrocarbon feed gas and to provide a selected amount of the catalyst dependant on the flow rate of the hydrocarbon feed gas;
moving the hydrocarbon feed gas and the metal catalyst through the reaction chamber;
using the catalyst transport system to provide a selected mass ratio of the catalyst to the hydrogen feed gas;
heating the hydrocarbon feed gas and the metal catalyst moving through the reaction chamber;
reacting the hydrocarbon feed gas in the reaction chamber to form a product gas comprised of hydrogen and unreacted hydrocarbon gas and the carbon nanoproduct; and
separating the carbon nanoproduct from the product gas and the metal catalyst.
11 . The process of claim 10 further comprising processing the product gas into pure hydrogen.
12 . The process of claim 10 further comprising using the product gas as an alternative fuel comprised of 20% to 30% hydrogen by volume and 70% to 80% methane by volume.
13 . The process of claim 10 wherein the heating step is performed at a temperature of from about 600 to 900° C.
14 . The process of claim 10 wherein the mass ratio is from 20:1 to 40:1 carbon to catalyst, and the carbon nanoproduct comprises carbon nanotubes.
15 . The process of claim 10 wherein the mass ratio is from 200:1 to 500:1 carbon to catalyst, and the carbon nanoproduct comprises carbon nanofibers.
16 . The process of claim 10 wherein the flow rate of the hydrocarbon feed gas is between 0.05 and 3.0 liters/minute and the selected amount of the catalyst is one gram/minute.
17 . The process of claim 10 further comprising using a portion of the product gas to perform the heating step.