IP Library Granted Patent US 8,575,830
Granted Patent B2
US 8,575,830 · App. 13/355,891 · Granted Nov 5, 2013

Electrode material for a spark plug

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Quick Facts
Patent No.
US 8,575,830
App. No.
13/355,891
Granted
Nov 5, 2013
Kind
B2
Abstract

An electrode material that may be used in spark plugs and other ignition devices including industrial plugs, aviation igniters, glow plugs, or any other device that is used to ignite an air/fuel mixture in an engine. The electrode material is a metal composite and includes a particulate component embedded or dispersed within a matrix component such that the metal composite has a multi-phase microstructure. In one embodiment, the metal composite includes a matrix component that includes a precious metal and makes up about 2-80% wt of the overall composite and a particulate component that includes a ruthenium-based material and makes up about 20-98% wt of the overall composite.

Claims (35)

1. A spark plug, comprising:

a metallic shell having an axial bore;

an insulator having an axial bore and being at least partially disposed within the axial bore of the metallic shell;

a center electrode being at least partially disposed within the axial bore of the insulator; and

a ground electrode being attached to a free end of the metallic shell;

wherein the center electrode, the ground electrode or both includes an electrode material having a particulate component embedded within a matrix component in the form of a metal composite;

the particulate component includes a ruthenium-based material having at least one precious metal, where ruthenium (Ru) is the single largest constituent of the particulate component on a wt % basis; and

the matrix component includes a precious metal, where the precious metal is the single largest constituent of the matrix component on a wt % basis.

2. The spark plug of claim 1 , wherein the particulate component includes a ruthenium-based material having a precious metal that is the second largest constituent of the particulate component on a wt % basis, and the precious metal is present in the particulate component from about 0.1 wt % to about 49.9 wt %, inclusive.

3. The spark plug of claim 2 , wherein the precious metal is selected from the group consisting of: rhodium (Rh), platinum (Pt), palladium (Pd), iridium (Ir) or gold (Au).

4. The spark plug of claim 2 , wherein the particulate component includes rhodium (Rh) from about 0.1 to 15 wt % and ruthenium (Ru) as the balance.

5. The spark plug of claim 1 , wherein the particulate component further includes at least one refractory metal selected from the group consisting of: tungsten (W), rhenium (Re), tantalum (Ta), molybdenum (Mo) or niobium (Nb).

6. The spark plug of claim 1 , wherein the particulate component further includes at least one rare earth metal selected from the group consisting of: yttrium (Y), hafnium (Hf), scandium (Sc), zirconium (Zr) or lanthanum (La).

7. The spark plug of claim 1 , wherein the matrix component includes a platinum-based material where platinum (Pt) is the single largest constituent of the matrix component on a wt % basis.

8. The spark plug of claim 7 , wherein the platinum-based material is made from pure platinum (Pt).

9. The spark plug of claim 1 , wherein about 2-20 wt % of the metal composite is in the form of the matrix component and about 80-98 wt % of the metal composite is in the form of the particulate component.

10. The spark plug of claim 1 , wherein the metal composite has an average particulate component spacing of about 1-20 μm, inclusive.

11. The spark plug of claim 1 , wherein the metal composite has an average density that is less than or equal to 14.0 g/cm 3 .

12. The spark plug of claim 1 , wherein the metal composite, after extrusion, has a microstructure with grains of the matrix component that are more elongated or more fiber-like than grains of the particulate component.

13. The spark plug of claim 1 , wherein the matrix component makes up about 2-20 wt % of the overall metal composite and includes a platinum-based material made from pure platinum (Pt), and the particulate component makes up about 80-98 wt % of the overall metal composite and includes a ruthenium-based alloy with rhodium (Rh) from about 0.1 to 5 wt % and ruthenium (Ru) as the balance.

14. The spark plug of claim 1 , wherein the metal composite is at least partially surrounded by a thin cladding material that includes platinum (Pt).

15. The spark plug of claim 1 , wherein the center electrode, the ground electrode or both includes an attached firing tip that is at least partially made from the electrode material.

16. The spark plug of claim 15 , wherein the firing tip is a multi-piece rivet that includes a second component attached to the center electrode or the ground electrode, and a first component that is attached to the second component and is at least partially made from the electrode material.

17. The spark plug of claim 1 , wherein the center electrode, the ground electrode or both is at least partially made from the electrode material and does not include an attached firing tip.

18. A spark plug electrode, comprising:

an electrode material having a particulate component embedded within a matrix component in the form of a metal composite;

the particulate component includes a ruthenium-based material, where ruthenium (Ru) is the single largest constituent of the particulate component on a wt % basis; and

the matrix component includes a precious metal, where the precious metal is the single largest constituent of the matrix component on a wt % basis.

19. A method of forming a spark plug electrode, comprising the steps of:

(a) providing a matrix component and a particulate component in powder form, wherein the matrix component includes at least one precious metal and the particulate component includes ruthenium (Ru);

(b) blending the matrix component and particulate component powders together to form a powder mixture;

(c) sintering the powder mixture to form an electrode material, where the electrode material is in the form of a metal composite with the particulate component embedded or dispersed in the matrix component; and

(d) forming the electrode material into a spark plug electrode.

20. The method of claim 19 , further comprising the step of:

inserting the electrode material from step (c) into a cladding structure, and co-extruding the electrode material and the cladding structure together.

Assignments (18)
PATENT SECURITY AGREEMENT (ABL) Recorded Apr 7, 2023
From: TENNECO INC.; DRIV AUTOMOTIVE INC.; FEDERAL-MOGUL CHASSIS LLC; FEDERAL-MOGUL IGNITION LLC; FEDERAL-MOGUL MOTORPARTS LLC; FEDERAL-MOGUL POWERTRAIN LLC; FEDERAL-MOGUL WORLD WIDE LLC; TENNECO AUTOMOTIVE OPERATING COMPANY INC.; THE PULLMAN COMPANY
To: CITIBANK, N.A., AS COLLATERAL AGENT
Reel/Frame 063268/0506 →
NOTICE OF GRANT OF SECURITY INTEREST IN PATENTS (FIRST LIEN) Recorded Nov 22, 2022
From: DRIV AUTOMOTIVE INC.; FEDERAL-MOGUL CHASSIS LLC; FEDERAL-MOGUL IGNITION LLC; FEDERAL-MOGUL MOTORPARTS LLC; FEDERAL-MOGUL POWERTRAIN LLC; FEDERAL-MOGUL WORLD WIDE LLC; TENNECO AUTOMOTIVE OPERATING COMPANY INC.; TENNECO INC.; THE PULLMAN COMPANY
To: CITIBANK, N.A., AS COLLATERAL AGENT
Reel/Frame 061989/0689 →
RELEASE OF SECURITY INTEREST Recorded Nov 19, 2022
From: WILMINGTON TRUST, NATIONAL ASSOCIATION
To: TENNECO INC.; TENNECO AUTOMOTIVE OPERATING COMPANY INC.; TENNECO INTERNATIONAL HOLDING CORP.; THE PULLMAN COMPANY; TENNECO GLOBAL HOLDINGS INC.; CLEVITE INDUSTRIES INC.; TMC TEXAS INC.; CARTER AUTOMOTIVE COMPANY LLC; FEDERAL-MOGUL WORLD WIDE LLC; FELT PRODUCTS MFG. CO. LLC; MUZZY-LYON AUTO PARTS LLC; FEDERAL-MOGUL POWERTRAIN LLC; FEDERAL-MOGUL POWERTRAIN IP LLC; FEDERAL-MOGUL PISTON RINGS, LLC; FEDERAL-MOGUL IGNITION LLC; FEDERAL-MOGUL MOTORPARTS LLC; FEDERAL-MOGUL CHASSIS LLC; F-M MOTORPARTS TSC LLC; F-M TSC REAL ESTATE HOLDINGS LLC; FEDERAL-MOGUL VALVE TRAIN INTERNATIONAL LLC; FEDERAL-MOGUL SEVIERVILLE, LLC; BECK ARNLEY HOLDINGS LLC; FEDERAL-MOGUL FILTRATION LLC; FEDERAL-MOGUL FINANCING CORPORATION; FEDERAL-MOGUL PRODUCTS US LLC
Reel/Frame 061975/0218 →
RELEASE OF SECURITY INTEREST Recorded Nov 19, 2022
From: WILMINGTON TRUST, NATIONAL ASSOCIATION
To: TENNECO INC.; TENNECO AUTOMOTIVE OPERATING COMPANY INC.; THE PULLMAN COMPANY; FEDERAL-MOGUL IGNITION LLC; FEDERAL-MOGUL POWERTRAIN LLC; FEDERAL-MOGUL PRODUCTS US LLC; FEDERAL-MOGUL MOTORPARTS LLC; FEDERAL-MOGUL WORLD WIDE LLC; FEDERAL-MOGUL CHASSIS LLC; DRIV AUTOMOTIVE INC.
Reel/Frame 061971/0156 →
RELEASE OF SECURITY INTEREST Recorded Nov 19, 2022
From: WILMINGTON TRUST, NATIONAL ASSOCIATION
To: TENNECO INC.; TENNECO AUTOMOTIVE OPERATING COMPANY INC.; THE PULLMAN COMPANY; FEDERAL-MOGUL IGNITION LLC; FEDERAL-MOGUL POWERTRAIN LLC; FEDERAL-MOGUL PRODUCTS US LLC; FEDERAL-MOGUL WORLD WIDE LLC; FEDERAL-MOGUL CHASSIS LLC; DRIV AUTOMOTIVE INC.
Reel/Frame 061975/0031 →
RELEASE OF SECURITY INTEREST Recorded Mar 18, 2021
From: WILMINGTON TRUST, NATIONAL ASSOCIATION
To: FEDERAL-MOGUL PRODUCTS US, LLC, AS SUCCESSOR TO FEDERAL-MOGUL PRODUCTS, INC.; FEDERAL-MOGUL WORLD WIDE, INC., AS SUCCESSOR TO FEDERAL-MOGUL WORLD WIDE LLC; FEDERAL-MOGUL MOTORPARTS LLC, AS SUCCESSOR TO FEDERAL-MOGUL MOTORPARTS CORPORATION; FEDERAL-MOGUL IGNITION, LLC, AS SUCCESSOR TO FEDERAL-MOGUL IGNITION COMPANY; TENNECO INC., AS SUCCESSOR TO FEDERAL-MOGUL LLC; FEDERAL-MOGUL CHASSIS LLC; FEDERAL-MOGUL POWERTRAIN LLC; DRIV AUTOMOTIVE INC.
Reel/Frame 058392/0274 →
RELEASE OF SECURITY INTEREST Recorded Mar 18, 2021
From: WILMINGTON TRUST, NATIONAL ASSOCIATION
To: FEDERAL-MOGUL PRODUCTS US, LLC, AS SUCCESSOR TO FEDERAL-MOGUL PRODUCTS, INC.; FEDERAL-MOGUL WORLD WIDE, INC., AS SUCCESSOR TO FEDERAL-MOGUL WORLD WIDE LLC; FEDERAL-MOGUL MOTORPARTS LLC, AS SUCCESSOR TO FEDERAL-MOGUL MOTORPARTS CORPORATION; FEDERAL-MOGUL IGNITION, LLC, AS SUCCESSOR TO FEDERAL-MOGUL IGNITION COMPANY; TENNECO INC., AS SUCCESSOR TO FEDERAL-MOGUL LLC; FEDERAL-MOGUL CHASSIS LLC; FEDERAL-MOGUL POWERTRAIN LLC; DRIV AUTOMOTIVE INC.
Reel/Frame 056886/0455 →
SECURITY AGREEMENT Recorded Mar 17, 2021
From: TENNECO INC.; TENNECO AUTOMOTIVE OPERATING COMPANY INC.; THE PULLMAN COMPANY; FEDERAL-MOGUL IGNITION LLC; FEDERAL-MOGUL POWERTRAIN LLC; FEDERAL-MOGUL PRODUCTS US LLC; FEDERAL-MOGUL WORLD WIDE LLC; FEDERAL-MOGUL CHASSIS LLC; DRIV AUTOMOTIVE INC.
To: WILMINGTON TRUST, NATIONAL ASSOCIATION
Reel/Frame 055626/0065 →
SECURITY AGREEMENT Recorded Dec 1, 2020
From: TENNECO INC.; THE PULLMAN COMPANY; FEDERAL-MOGUL IGNITION LLC; FEDERAL-MOGUL POWERTRAIN LLC; FEDERAL-MOGUL PRODUCTS US LLC; FEDERAL-MOGUL MOTORPARTS LLC; FEDERAL-MOGUL WORLD WIDE LLC; FEDERAL-MOGUL CHASSIS LLC; DRIV AUTOMOTIVE INC.; TENNECO AUTOMOTIVE OPERATING COMPANY INC.
To: WILMINGTON TRUST, NATIONAL ASSOCIATION
Reel/Frame 054555/0592 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 22, 2019
From: FEDERAL-MOGUL IGNITION COMPANY
To: FEDERAL-MOGUL IGNITION LLC
Reel/Frame 049821/0536 →
COLLATERAL TRUSTEE RESIGNATION AND APPOINTMENT, JOINDER, ASSUMPTION AND DESIGNATION AGREEMENT Recorded Oct 26, 2018
From: BANK OF AMERICA, N.A., AS CO-COLLATERAL TRUSTEE AND RESIGNING COLLATERAL TRUSTEE
To: WILMINGTON TRUST, NATIONAL ASSOCIATION, AS CO-COLLATERAL TRUSTEE, SUCCESSOR COLLATERAL TRUSTEE
Reel/Frame 047630/0661 →
RELEASE OF SECURITY INTEREST Recorded Oct 22, 2018
From: BANK OF AMERICA, N.A., AS COLLATERAL TRUSTEE
To: FEDERAL-MOGUL LLC; FEDERAL-MOGUL WORLD WIDE LLC; FEDERAL-MOGUL MOTORPARTS LLC; FEDERAL-MOGUL IGNITION COMPANY; FEDERAL-MOGUL CHASSIS LLC; FEDERAL MOGUL POWERTRAIN LLC; FEDERAL-MOGUL PRODUCTS, INC.
Reel/Frame 047276/0554 →
RELEASE OF SECURITY INTEREST Recorded Oct 22, 2018
From: BANK OF AMERICA, N.A., AS COLLATERAL TRUSTEE
To: FEDERAL-MOGUL LLC; FEDERAL-MOGUL WORLD WIDE LLC; FEDERAL-MOGUL MOTORPARTS LLC; FEDERAL-MOGUL IGNITION COMPANY; FEDERAL-MOGUL CHASSIS LLC; FEDERAL MOGUL POWERTRAIN LLC; FEDERAL-MOGUL PRODUCTS, INC.
Reel/Frame 047276/0771 →
CONFIRMATORY GRANT OF SECURITY INTERESTS IN UNITED STATES PATENTS Recorded Oct 9, 2018
From: TENNECO INC.; TENNECO AUTOMOTIVE OPERATING COMPANY INC.; TENNECO INTERNATIONAL HOLDING CORP.; THE PULLMAN COMPANY; TENNECO GLOBAL HOLDINGS INC.; CLEVITE INDUSTRIES INC.; TMC TEXAS INC.; CARTER AUTOMOTIVE COMPANY LLC; FEDERAL-MOGUL WORLD WIDE LLC; FELT PRODUCTS MFG. CO. LLC; MUZZY-LYON AUTO PARTS LLC; FEDERAL-MOGUL POWERTRAIN LLC; FEDERAL-MOGUL POWERTRAIN IP LLC; FEDERAL-MOGUL PISTON RINGS, LLC; FEDERAL-MOGUL IGNITION LLC; FEDERAL-MOGUL MOTORPARTS LLC; FEDERAL-MOGUL CHASSIS LLC; F-M MOTORPARTS TSC LLC; F-M TSC REAL ESTATE HOLDINGS LLC; FEDERAL-MOGUL VALVETRAIN INTERNATIONAL LLC; FEDERAL-MOGUL SEVIERVILLE, LLC; BECK ARNLEY HOLDINGS LLC; FEDERAL-MOGUL FILTRATION LLC; FEDERAL-MOGUL FINANCING CORPORATION; FEDERAL-MOGUL PRODUCTS US LLC
To: WILMINGTON TRUST, NATIONAL ASSOCIATION, AS COLLATERAL TRUSTEE
Reel/Frame 047223/0001 →
COLLATERAL TRUSTEE RESIGNATION AND APPOINTMENT AGREEMENT Recorded Apr 3, 2018
From: CITIBANK, N.A., AS COLLATERAL TRUSTEE
To: BANK OF AMERICA, N.A., AS COLLATERAL TRUSTEE
Reel/Frame 045822/0765 →
GRANT OF SECURITY INTEREST IN UNITED STATES PATENTS Recorded Sep 26, 2017
From: FEDERAL-MOGUL LLC; FEDERAL-MOGUL PRODUCTS, INC.; FEDERAL-MOGUL MOTORPARTS LLC; FEDERAL-MOGUL CHASSIS LLC; FEDERAL-MOGUL POWERTRAIN LLC; FEDERAL-MOGUL IGNITION COMPANY; FEDERAL-MOGUL WORLD WIDE, LLC
To: CITIBANK, N.A., AS COLLATERAL TRUSTEE
Reel/Frame 044013/0419 →
GRANT OF SECURITY INTEREST IN UNITED STATES PATENTS Recorded Jun 23, 2017
From: FEDERAL-MOGUL LLC; FEDERAL-MOGUL PRODUCTS, INC.; FEDERAL-MOGUL MOTORPARTS CORPORATION; FEDERAL-MOGUL CHASSIS LLC; FEDERAL-MOGUL POWERTRAIN LLC; FEDERAL-MOGUL IGNITION COMPANY; FEDERAL-MOGUL WORLD WIDE, INC.
To: CITIBANK, N.A., AS COLLATERAL TRUSTEE
Reel/Frame 042963/0662 →
SECURITY INTEREST Recorded Jun 20, 2014
From: FEDERAL-MOGUL CORPORATION, A DELAWARE CORPORATION; FEDERAL-MOGUL WORLD WIDE, INC., A MICHIGAN CORPORATION; FEDERAL-MOGUL IGNITION COMPANY, A DELAWARE CORPORATION; FEDERAL-MOGUL POWERTRAIN, INC., A MICHIGAN CORPORATION; FEDERAL-MOGUL PRODUCTS, INC. , A MISSORI CORPORATION; FEDERAL-MOGUL CHASSIS LLC, A DELAWARE LIMITED LIABILITY COMPANY
To: CITIBANK, N.A., AS COLLATERAL TRUSTEE
Reel/Frame 033204/0707 →