Azeotrope and azeotrope-like compositions useful for the production of haloolefins
View Patent ↗The present invention pertains to ternary azeotrope and azeotrope-like composition including 2-chloro-3,3,3-trifluoropropene (HCFO-1233xf), HF, and either 1,1,2,3-tetrachloropropene (TCP) or 1,1,1,2,2-pentafluoropropane (HFC-245cb). The present invention also relates to binary azeotropes of 2,3,3,3-tetrachloropropene and HF. Such azeotropic and azeotrope-like compositions are useful as intermediates in the production of 2,3,3,3-tetrafluoropropene (HFO-1234yf).
1. A ternary azeotrope or azeotrope-like composition consisting essentially of hydrogen fluoride, 2-chloro-3,3,3-trifluoropropene, and a third component selected from the group consisting of 1,1,2,3-tetrachloropropene and 1,1,1,2,2-pentafluoropropane, wherein
when the third component is 1,1,2,3-tetrachloropropene, hydrogen fluoride is present in an amount from about 3.0 to about 28.0 weight percent, 2-chloro-3,3,3-trifluoropropene is present in an amount from about 68.0 to about 93.0 weight percent, and 1,1,2,3-tetrachloropropene is present in an amount from about 2.5 to about 4.3 weight percent, and
when the third component is 1,1,1,2,2-pentafluoropropane, hydrogen fluoride is present in an amount, from about 3.0 to about 22.0 weight percent, 2-chloro-3,3,3-trifluoropropene is present in an amount from about 65.0 to about 83.5 weight percent, and 1,1,1,2,2-pentafluoropropane is present in an amount from about 11.1 to about 15.5 weight percent.
2. The ternary azeotropic or azeotrope-like composition of claim 1 wherein the third component is 1,1,2,3-tetrachloropropene.
3. The ternary azeotropic or azeotrope-like composition of claim 2 wherein hydrogen fluoride is present in an amount from about 5.9 to about 25 weight percent; 2-chloro-3,3,3-trifluoropropene is present in an amount from about 72 to about 90.3 weight percent, and 1,1,2,3-tetrachloropropene is present in an amount from about 3.0 to about 3.8 weight percent.
4. The ternary azeotropic or azeotrope-like composition of claim 2 having a boiling point between about 0 to about 61° C. at a pressure between about 15 to about 110 psia.
5. The ternary azeotropic or azeotrope-like composition of claim 2 having a boiling point of about 0° C. at a pressure of about 16.2 psia.
6. The ternary azeotropic or azeotrope-like composition of claim 2 having a boiling point of about 24.9° C. at a pressure of about 39.9 psia.
7. The ternary azeotropic or azeotrope-like composition of claim 2 having a boiling point of about 59.8° C. at a pressure of about 109.7 psia.
8. The ternary azeotropic or azeotrope-like composition of claim 1 wherein the third component is 1,1,1,2,2-pentafluoropropane.
9. The ternary azeotropic or azeotrope-like composition of claim 8 wherein hydrogen fluoride is present in an amount from about 4.5 to about 20.5 weight percent; 2-chloro-3,3,3-trifluoropropene is present in an amount from about 67.4 to about 81 weight percent, and 1,1,1,2,2-pentafluoropropane is present in an amount from about 12.1 to about 14.5 weight percent.
10. The ternary azeotropic or azeotrope-like composition of claim 8 having a boiling point between about 0 to about 61° C. at a pressure between about 15 to about 110 psia.
11. The ternary azeotropic or azeotrope-like composition of claim 8 having a boiling point of about 0° C. at a pressure of about 18.0 psia.
12. The ternary azeotropic or azeotrope-like composition of claim 8 having a boiling point of about 24.9° C. at a pressure of about 44.8 psia.
13. The ternary azeotropic or azeotrope-like composition of claim 8 having a boiling point of about 59.7° C. at a pressure of about 120.0 psia.